Equipe LC₃: Ligands Chiraux, Complexes et Catalyse

Intérêts de recherche

My activities are oriented towards the syntheses of new organometallic compounds with attractive chemical or physical properties, and the use of X-ray diffraction studies as a tool to characterize new compounds.

            Up to the end of 1993, I have been interested in the field of cluster-assisted ligand transformation in the Laboratoire de Chimie des Métaux de Transition (LCMT, URA419). In 1994, I moved to the Laboratoire de Chimie de Coordination du CNRS (LCC, UPR8241, Toulouse), where I was the manager of the SAIM team (Synthèse Asymétrique et Interactions Moleculaires) until December 2002. Since 2003, I share the management of a new group LC3 (Ligands Chiraux, Complexes et  Catalyse) which results from the merging of 3 groups. In this new team, my main interest is devoted to stereochemistry and syntheses of new ligands or complexes with two principal aims, asymmetric catalysis and the building of new materials.:

- Building of chiral polysubstituted ferrocenes which can be used in many fields such as organic synthesis, asymmetric catalysis, and materials chemistry (Non-Linear Optics, Dendrimers…).

- Syntheses of new chiral phospholes and 2,2'-biphospholes ligands to build enantiomerically pure metal complexes and their use in asymmetric catalysis.

Over the years, I gained experience in the field of X-ray structural determination for small molecules and a good knowledge in computing. Until 2005, I was the manager of the X-ray department ( Two diffractometers : Oxford-Diffraction XCALIBUR, Stoe IPDS) of the Laboratoire de Chimie de Coordination.

Publications et Communications

Publications récentes:

2004

New Dihidroxy Bis(oxazoline) Ligands for the Palladium-Catalyzed Asymmetric Allylic Alkylation: Experimental Investigations of the Origin of the Reversal of the Enantioselectivity. H. Aït-Haddou, O. Hoarau, D. Cramailère, F. Pezet, J.-C. Daran, G.G.A. Balavoine. Chem. Eur. J. (2004), 10, 699-707.

A one-pot method to prepare the carbene complex [TpMe2,ClRhCl2(CHNiPr2)] from [TpMe2,ClRh(CO)2], CHCl3 and NHiPr2. E. Teuma, F. Malbosc, M. Etienne, J.-C. Daran, P. Kalck. J. Organomet. Chem. (2004), 689, 1763-1765.

From calcium interaction to calcium electrochemical detection by [(C5H5)Fe(C5H4COCH=CH C6H4NEt2)] and its two novel structurally characterized derivatives. J. Maynadier, B. Delavaux-Nicot, D. Lavabre, B. Donnadieu, J.-C. Daran, A. Sournia-Saquet. Inorg. Chem. (2004), 43, 2064-2077.

Enantiomerically pure disulfides: key compounds in kinetic resolution of chiral PIII-derivatives with stereogenic phosphorus. W. Perlikowska, M. Gouygou, M. Mikolajczyk, J.-C. Daran. (2004), Tetrahedron: Asymmetry, 3519-3521.

One Pot Diastereoselective Synthesis of New Chiral Spiro-1,3,4-thiadiazoles and 1,4,2-Oxathiazoles from (1R)-Thiocamphor. A. Feddouli, M.Y. Ait Itto, A. Hasnaoui, D. Villemin, P.A. Jaffrès, I Sopkova-De Oliveira Santos, A. Riahi, F. Huet, J.-C. Daran. J. Heterocyclic Chem. (2004), 41, 731-735.

A New Synthetic Method and Solution Equilibria for the Chlorotitanate(IV) Anions- Evidence for the Existence of a New Species: [Ti2Cl11]3-. E. Robé, J.-C. Daran, S. Vincendeau, R. Poli. Eur. J. Inorg. Chem. (2004), 4108-4114.


2005

The radical trap in atom transfer radical polymerization need not be thermodynamically stable. A study of the MoX3(PMe3)3(X= Cl, Br, I) catalysts. S. Maria, F. Stoffelbach, J. Mata, J.-C. Daran, P. Richard, R. Poli. J. Am. Chem. Soc. (2005), 127, 5946-5956.

Lanthanide Complexes Coordinated by N-Substituted ®-1,1’-Binaphtyl-2,2’-diamido Ligands in the Catalysis of Enantioselective Intramolecular Hydroamination. J. Collin, J.-C. Daran, O. Jacquet, E. Schulz, A. Trifonov. Chem. Eur. J. (2005), 11, 3455-3462.

New Ferrocenyl P,S and S,S ligands for Asymmetric Catalysis. L. Routaboul, S. Vincendeau, J.-C. Daran, E. Manoury. Tetrahedron : Asymmetry, (2005), 2685-2690.

Stereochemically Dynamic 2,2’-Biphosphole Ligands for Asymmetric Catalysis. E. Robé, C. Ortéga, M. Mikina, M. Mikolajczyk, J.-C. Daran, M. Gouygou. Organometallics, (2005), 24, 5549-5559.

2,3-Diphenyl-2,3-dihydrospiro[1,3-oxazole-5(4H), 1’(3’H)-2-benzofuran]-3’-one. J.-C. Daran, R. Fihi, C. Roussel, N. Laghrib, M. Azrour, K. Ciamala, J. Vebreld. Acta. Cryst., Section E. (2005), E61, O329-O331.

2006

Ni(II) complexes with bifunctional phosphine-imidazolium ligands and their catalytic activity in the Kumada-Corriu coupling reaction. J. Wolf, A. Labande, J.-C. Daran, R. Poli. J. Organomet. Chem. (2006), 691, 433-443.

New, Multi-Dimensional Cu(tn)-[M(CN)6]n- Cyano-Bridged, Bimetallic Coordination Materials (M= FeII, CoIII, CrIII and tn= 1,3-Diaminopropane). S. Triki, J. Sala-Pala, F. Thétiot, C. J. Gomez-Garcia, J.-C. Daran. Eur. J. Inorg . Chem. (2006). 185-199.

Aryl Grignard Cross-Coupling of Aryl Chlorides Catalysed by New, Highly Active Phosphine/Imidazolium Nickel(II) Complexes J. Wolf, A. Labande, M. Natella, J.-C. Daran, R. Poli, J. Mol. Catal. A, (2006), 259, 205-212.

Three new enantiomerically pure ferrocenylphosphole compounds ; j ;g ; Lopez Cortés, S. Vincendeau, J.-C. Daran, E. Manoury, M. Gouygou, Acta. Cryst., Section C, 62, m188-m191.

A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN= 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane. A.D. Phillips, Sandra Bolãno, S. S. Bosquain, J.-C. Daran, R. Malacea, M. Peruzzini, R. Poli, L. Gonsalvi. Organometallics. 2006

Interplay between lead carboxylate and Ti or Zr isopropoxides in solution routes to perovskites: synthesis, molecular structures and reactivity of single source non-oxo Pb-Zr and Pb-Ti carboxylatoalkoxides supported by 2-ethylhexanoate ligands. Brethon, A.; Hubert-Pfalzgraf, L. G.; Daran, J. C., Dalton Transactions 2006, (1), 250.

Ziyat, H.; Itto, M. Y. A.; Ali, M. A.; Riahi, A.; Karim, A.; Daran, J. C., Convenient synthesis of new functionalized cyclopropanes from monoterpenic olefines. Arkivoc 2006, 152.

Synthesis and catalytic applications of new chiral ferrocenyl P,O ligands. Mateus, N.; Routaboul, L.; Daran, J. C.; Manoury, E., Journal Of Organometallic Chemistry 2006, 691, (10), 2297.

Synthesis and characterization of MoOI2(PMe3)(3) and use of MoOX2(PMe3)(3) (X = Cl, I) in controlled radical polymerization. Mata, J. A.; Maria, S.; Daran, J. C.; Poli, R., Synthesis and characterization of MoOI2(PMe3)(3) and use of MoOX2(PMe3)(3) (X = Cl, I) in controlled radical polymerization. European Journal Of Inorganic Chemistry 2006, (13), 2624.

Coordination chemistry and diphenylacetylene hydrogenation catalysis of planar chiral ferrocenylphosphane-thioether ligands with cyclooctadieneiridium(I). Malacea, R.; Manoury, E.; Routaboul, L.; Daran, J. C.; Poli, R.; Dunne, J. P.; Withwood, A. C.; Godard, C.; Duckett, S. B., European Journal Of Inorganic Chemistry 2006, (9), 1803.

Parahydrogen studies of H-2 addition to Ir(I) complexes containing chiral phosphine-thioether ligands: implications for catalysis. Malacea, R.; Daran, J. C.; Duckett, S. B.; Dunne, J. P.; Godard, C.; Manoury, E.; Poli, R.; Whitwood, A. C., Dalton Transactions 2006, (27), 3350.

Dichloro(2,5-diphenyl-3,4-di-2-pyridylcyclopenta-2,4-dienone)cobalt(II). Khalaji, A. D.; Amirnasr, M.; Daran, J. C., Acta Crystallographica Section E-Structure Reports Online 2006, 62, M687.

Poly[[(2-amino-5-bromopyridine-kappa N)copper(I)]mu(3)-iodo] Khalaji, A. D.; Amirnasr, M.; Daran, J. C.,. Acta Crystallographica Section E-Structure Reports Online 2006, 62, M3222.

Bis[N,N '-bis(3,3-diphenylprop-2-enylidene)-ethane-1,2-diamine-kappa N-2,N ']copper(I) triiodide. Khalaji, A. D.; Amirnasr, M.; Daran, J. C., Acta Crystallographica Section E-Structure Reports Online 2006, 62, M3183.

Promoting role of [PtI2(CO)](2) in the iridium-catalyzed methanol carbonylation to acetic acid and its interaction with involved iridium species. Gautron, S.; Lassauque, N.; Le Berre, C.; Azam, L.; Giordano, R.; Serp, P.; Laurenczy, G.; Daran, J. C.; Duhayon, C.; Thiebaut, D.; Kalck, P., Organometallics 2006, 25, (25), 5894.

Ethyl 2-[(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)hydrazono]-2-(4-nitrophe nylsulfanyl)acetate.Feddouli, A.; Itto, M. Y. A.; Hasnaoui, A.; Riahi, A.; Daran, J. C., Acta Crystallographica Section E-Structure Reports Online 2006, 62, O699.

Reduction of [CP2*Mo2O5] by thioglycolic acid in an aqueous medium: Synthesis and structure of [{Cp*Mo(mu-SCH2COO)}(2)(mu-S)]. Demirhan, F.; Taban, G.; Baya, M.; Dinoi, C.; Daran, J. C.; Poli, R., Journal Of Organometallic Chemistry 2006, 691, (4), 648.

Reduction of [Cp*2Mo2O5] in aqueous medium: Structure and properties of a triangular mixed oxo-hydroxo-bridged product, [Cp*Mo-3(3)(mu-O)(2)(mu-OH)(4)](X)(2) (X =CF3CO2 or CF3SO3). Demirhan, F.; Cagatay, B.; Demir, D.; Baya, M.; Daran, J. C.; Poli, R., European Journal Of Inorganic Chemistry 2006, (4), 757.

(2S,4S,S-Fc)-2-[2-(diphenylthiophosphinoyl)ferrocenyl]-4-methoxy-methyl- 1,3-dioxane. Daran, J. C.; Manoury, E.; Routaboul, L.; Rivas, F., Acta Crystallographica Section C-Crystal Structure Communications 2006, 62, M378.

2,3-diphenyl-2,3-dihydrospiro[1,3-oxazole-5(4H),1 '(3 ' H)-2-benzofuran]-3 '-one.  Daran, J. C.; Fihi, R.; Roussel, C.; Laghrib, N.; Azrour, M.; Ciamala, K.; Vebreld, J., Acta Crystallographica Section E-Structure Reports Online 2006, 62, O329.

Three new enantiomerically pure ferrocenylphosphole compounds. Cortes, J. G. L.; Vincendeau, S.; Daran, J. C.; Manoury, E.; Gouygou, M., Acta Crystallographica Section C-Crystal Structure Communications 2006, 62, M188.

New chiral ferrocene-bridged phosphole-phosphane ligands. Cortes, J. G. L.; Ramon, O.; Vincendeau, S.; Serra, D.; Lamy, F.; Daran, J. C.; Manoury, E.; Gouygou, M., European Journal Of Inorganic Chemistry 2006, (24), 5148.

2007

34     Formation and structure of a sterically protected molybdenum hydride complex with a 15-electron configuration: [(1,2,4-C(5)H(2)tBu(3))Mo(PMe3)(2)H](+). Baya, M.; Houghton, J.; Daran, J. C.; Poli, R., Angewandte Chemie-International Edition 2007, 46, (3), 429.


35     Synthesis, structure, and electrochemical properties of sterically protected molybdenum trihydride redox pairs: A paramagnetic "stretched" dihydrogen complex?  Baya, M.; Houghton, J.; Daran, J. C.; Poli, R.; Male, L.; Albinati, A.; Gutman, M. Chemistry-A European Journal 2007, 13, (19), 5347.

36     (1S,3R,6S)-3-Chloro-trans-himachalene.  Benharref, A.; Mazoir, N.; Moha, B.; Essediya, L.; Daran, J. C., Acta Crystallographica Section E-Structure Reports Online 2007, 63, O3681.

37     Reduction of [(CP2Mo2O5)-Mo-*] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound. Dinoi, C.; Prikhodchenko, P.; Demirhan, F.; Gun, J.; Lev, O.; Daran, J. C.; Poli, R., Journal Of Organometallic Chemistry 2007, 692, (12), 2599.

38      Aqueous reduction of [Cp*2W2O5]: Characterization of the triangular clusters [Cp*3W3O4(OH)(2)](2+) and [Cp*3W3O6](+) - Comparison with molybdenum. Dinoi, C.; Sozen, P.; Taban, G.; Dernir, D.; Demirhan, F.; Prikhodchenko, P.; Gun, J.; Lev, O.; Daran, J. C.; Poli, R., European Journal Of Inorganic Chemistry 2007, (27), 4306.

39     Improved syntheses Of [CP*2Mo2O5] and [CP*2W2O5]: Structural characterization of Na[Cp*MoO3].5H2O and [CP*2W2O5]. Dinoi, C.; Taban, G.; Sozen, P.; Demirhan, F.; Daran, J. C.; Poli, R. Journal Of Organometallic Chemistry 2007, 692, (17), 3743.

40     Solvent control in the protonation of [Cp*Mo(dppe)H-3] by CF3COOH. Dub, P. A.; Baya, M.; Houghton, J.; Belkova, N. V.; Daran, J. C.; Poli, R.; Epstein, L. M.; Shubina, E. S., European Journal Of Inorganic Chemistry 2007, (18), 2813.

41     Metalation of cyclic pseudopeptidic thiosulfinates with Ni(II) and Zn(II) after ring opening: A mechanistic investigation. Galardon, E.; Bourles, E.; Artaud, I.; Daran, J. C.; Roussel, P.; Tomas, A., Inorganic Chemistry 2007, 46, (11), 4515.

42     Promoting role of [PtI2(CO)]2 in the iridium-catalyzed methanol carbonylation to acetic acid and its interaction with involved iridium species. Gautron, S.; Lassauque, N.; Le Berre, C.; Azam, L.; Giordano, R.; Serp, P.; Laurenczy, G.; Daran, J. C.; Duhayon, C.; Thiebaut, D.; Kalck, P., Organometallics 2007, 26, (4), 1116.

43     (1,10-phenanthroline-kappa N-2,N ') (triphenylphosphine-kappa P)silver(I) perchlorate acetonitrile hemisolvate. Khalaji, A. D.; Amirnasr, M.; Daran, J. C., Acta Crystallographica Section E-Structure Reports Online 2007, 63, M309.

44     New (1-phosphanylferrocen-1 '- and -2-yl)methyl-linked diaminocarbene ligands: Synthesis and rhodium(I) complexes. Labande, A.; Daran, J. C.; Manoury, E.; Poli, R., European Journal Of Inorganic Chemistry 2007, (9), 1205.

45     (1SR,3RS,5SR)-3-Hydroxy-3-(2-hydroxyethyl)-N-phenyl-5-(p-tolyl)pyrrolidi n-2-one. Laghrib, N.; Azrour, M.; Daran, J. C.; Fihi, R.; Majidi, L., Acta Crystallographica Section E-Structure Reports Online 2007, 63, O402.

46     {2,2 '-[1,1 '-(4-azaheptane-1,7-diyldinitrilo)diethylidyne]diphenolato}(pyridine) cobalt(III)hexafluorophosphate. Meghdadi, S.; Daran, J. C.; Amirnasr, M.; Morshedi, M., Acta Crystallographica Section E-Structure Reports Online 2007, 63, M982.

47     Ourhriss, N.; Mazoir, N.; Daran, J. C.; Berraho, M.; Benharref, A., (1S,3R,6S,7R)-3,7-Dichloro-trans-himachalane. Acta Crystallographica Section E-Structure Reports Online 2007, 63, o1497.

48     Neutral yttrium tris(amide) and ate complexes coordinated by an (R)-N,N '-diisopropyl-1,1 '-binaphthyl-2,2 '-diamido ligand as enantioselective catalysts for intramolecular hydroamination. Riegert, D.; Collin, J.; Daran, J. C.; Fillebeen, T.; Schulz, E.; Lyubov, D.; Fukin, G.; Trifonov, A European Journal Of Inorganic Chemistry 2007, (8), 1159.

49     New phosphorus dendrimers with chiral ferrocenyl phosphine-thioether ligands on the periphery for asymmetric catalysis. Routaboul, L.; Vincendeau, S.; Turrin, C. O.; Caminade, A. M.; Majoral, J. P.; Daran, J. C.; Manoury, E.,  Journal Of Organometallic Chemistry 2007, 692, (5), 1064.

2008

optically active cyclopentadienyl and indenyl ligands obtained from lactic acid esters. Laï, R.; Chanon, F.; Roussel, C.; Sanz, M.; Vanthuyne, N.; Daran, J.-C.,  Journal Of Organometallic Chemistry 2008, 693, (1), 23-32.

New enantiopure palladium(II) complexes from stereodynamic 2,2’-biphosphole ligand. Diab, L.; Daran, J.-C.; Gouygou, M.; Manoury, E.,  Acta Crystallographica, Crystal  Structure Communications, 2008, C64, m43-m45.

Polymorph of {2-[(2-hydroxyethyl)iminiomethyl]phenolato-O}dioxido{2-[(2-oxidoethyl)iminomethyl]phenolato-3O,N,O’}molybdenum(VI). Agustin, D.; Daran, J.-C.; Poli, R. Acta Crystallographica, Crystal  Structure Communications, 2008, C64, m101-m104.

(+/-)-N-[4-Acetyl-5-methyl-5-(4-methylcyclohex-3-enyl)-4,5-dihydro-1,3,4-thiadiazol-2-yl]acetamide. Mohammed, T.; Mazoir, N.; Daran, J.-C.; Berraho, M.; Benharref, A., Acta Crystallographica Section E-Structure Reports Online 2008, E64, o610-o611.

(4aS,10aS)-7-Hydroxy-8-isopropyl-1,1,4a-trimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene: a new diterpenoid compound. Zeroual, A.; Mazoir, N.; Daran, J.-C.; Akssira, M.; Benharref, A., Acta Crystallographica Section E-Structure Reports Online 2008, E64, o604-o605.

Synthesis, characterization and crystal structures of two new platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups. R. Malacea, E. Manoury, J.-C. Daran, R. Poli. Journal of Molecular Structure, 2008, 890, 249-254.

Overall "Pseudocationic" trifluoromethylation of dihydropyridines with triflic anhydride. Rudler, H., Parlier, A., Sandoval-Chavez,  C., Herson, P., Daran, J.-C.  Angewandte Chemie-International Edition 2008, 47, (36), 6843-6846.

Palladium and platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups. Malacea, R., Routaboul, L., Manoury, E., Daran, J.-C., Poli, R.  Journal of Organometallic Chemistry 2008, 693,  2818-2834.

Reactivity of phosphane-imidazolium salts towards [Ir(COD)Cl](2): Preparation of new hydridoiridium(III) complexes bearing abnormal carbenes. Wolf, J., Labande, A, Daran, J.-C., Poli, R. European Journal Of Inorganic Chemistry 2008 19, 3024-3030.

Synthesis and protonation studies of Cp*Os(dppe)H: Kinetic versus thermodynamic control. Dub, P.A., Belkova, N.V., Lyssenko, K.A., Silantyev, G.A., Epstein, L.M., Shubina, E.S., Daran J.-C., Poli, R. Organometallics 2008, 27, 3307-3311.

Synthesis and coordination chemistry of ferrocenyl-1,2,3-triazolyl ligands.Badeche, S., Daran, J.-C., Ruiz, J., Astruc, D. Inorganic Chemistry 2008, 47, 4903-4908.

Diphosphine sulfides derived from 2,2 '-biphosphole: novel chiral S,S ligands for palladium-catalyzed asymmetric allylic substitution. Robe, E., Perlikowska, W., Lemoine, C., Diab, L., Vincendeau, S., Mikolajczyk, M., Daran, J.-C., Gouygou, M. Dalton Trans. 2008, 21, 2894-2898.

Enantiopure platinum(II) complexes with chiral diphosphine and diphosphinite ligands derived from 2,2-biphosphole: Synthesis, crystal structure and catalysis. Robe, E., Hegedues, C., Bakos, J., Coppel, Y., Daran, J.-C., Gouygou, M. Inorganica Chemica Acta 2008, 361, 1861-1867.

Lactonizations of carboxylic acid-substituted 3-fluorodihydropyridines with electrophiles: peculiar behaviour of F. Rudler, H., Parlier, A., Hamon, L., Herson, P., Daran, J.-C. Chem. Comm. 2008, 35, 4150-4152.

6-Hydroxy-7-isopropyl-1,1,4a-trimethyl-2,3,4,4a,10,10a-hexahydrophenanthren-9(1H)-one. Rajouani, N., Itto, M.Y.A., Benharref, A., Auhmani, A., Daran, J.-C.  Acta Crystallographica Section E-Structure Reports Online 2008, E64, o762.

1,4a-Dimethyl-6-methylene-5-(5,5,6,6-tetracyano-2-methylcyclohex-2-enylmethyl)decahydronaphthalene-1-carboxylicacid: a trans-communic acid derivative. Rejouani, N., Auhmani, A., Itto, M.Y.A., Benharref, A., Daran, J.-C. Acta Crystallographica Section E-Structure Reports Online 2008, E64, o475.


Participation récente à des Congrès, conférences:

       Oral presentations

       - C. Verchère-Beaur, I. Sasaki, F. Pezet, J.-C. Daran, G.G.A. Balavoine. Interaction and Photocleavage efficiency of mononuclear and binuclear optically pure Ru(II) tris(diimine) complexes on DNA. 5th European Biological Inorganic Chemistry Conference, 17-20 juillet 2000, Toulouse, France.

       - W. Perlikowska, M. Gouygou, J.-C. Daran, G.G.A. Balavoine, M. Mikolajczyk. Nouvelle voie d’accés à des phosphines chirales énantiomériquement enrichies. 10ème Journée Grand Sud-Ouest, Société Française de Chimie, 24 novembre 2000, Toulouse.

       - M. Gouygou, O. Tissot, F. Dallemer, J.-C. Daran, G.G.A. Balavoine. Dédoublement spontané du BIPHOS : un ligand bidente a symétrie C2 pour la catalyse asymétrique. 10ème Journée Grand Sud-Ouest, Société Française de Chimie, 24 novembre 2000, Toulouse.

       - J.-C. Daran, O. Tissot, J. Hydrio, M. Gouygou, F. Dallemer, G.G.A. Balavoine. Some Aspects of the Structural and Coordination Chemistry of 2,2’-Biphosphole . The Sixth International Conference on Heteroatom Chemistry, 22-27 juin 2001, Lodz, Pologne.

       - J.-C. Daran, E. Bejan, H. Aït Haddou . Structure du complexe [Ru(bpy)2(C10H9N3)](PF6)2. Exemple d’une macle par inversion. AFC 2001, Colloque de l’Association Française de Cristallographie, 3-6 juillet 2001, Orsay, France.

       - E. Manoury, J. Chiffre, G. Iftime, K. Roques, F. Barangé, J.C. Daran, G.G.A. Balavoine : Influence de l’empilement cristallin sur les propriétés en optique non-linéaire de composés férrocéniques. AFC 2001, Colloque de l’Association Française de Cristallographie, 3-6 juillet 2001, Orsay, France.

       - J.-C. Daran, E. Manoury, G. Iftime, J. Chiffre, G. G. A. Balavoine, P. G. Lacroix : Synthesis, Crystal Structures and Second Order Nonlinear Optical Properties of New Ferrocenyl Materials. SFC Eurochem, 8-11 juillet 2002, Toulouse.

        - O. Tissot, M. Gouygou, F. Dallemer, J.-C. Daran, G. G. A. Balavoine :.From a Stereolabile Chiral 2,2’Biphosphole Ligand to Asymmetric Catalysis. SFC Eurochem, 8-11 juillet 2002, Toulouse.- J.-C. Daran. The Coordination and Catalytic Properties of the 1,1’-Diphenyl-3,3’,4,4’-Tetramethyl-2,2’-biphosphole. XIX Congress and General Assembly of the International Union of Crystallography, 6-15 août 2002, Genève.

        - J.-C. Daran. Synthesis, crystal structures and second order non-linear optical properties of new ferrocenyl materials. Congrés Algérien de Cristallographie 1, 2-5 novembre 2002, Alger.

        - J.-C. Daran . La diffraction des rayons X à haute résolution, un outil de choix pour le chimiste. Deuxième Journée Scientifique de Biologie Structurale de l’ IPBS, Toulouse, 26 juin 2003.

        - L. Routaboul, E. Manoury, J.-C. Daran. Synthèse d’une nouvelle famille de ligands P,S ferrocéniques (phosphine-thioether). Coordination et utilisation en catalyse asymétrique. GECOM-2003, 19-23 mai 2003, Ambleteuse.

        - J.-C. Daran . The use of stereolabile ligands in asymmetric catalyses : dream or reality ? Advances in Heteroatom Chemistry, International Workshop, Lodz, Pologne, 21-23 novembre 2003.

        - J.-C. Daran. Design and X-ray Structures of New Chiral Ferrocenyl Ligands to be used in Asymmetric Catalyses. 22nd European Crystallographic Meeting, Budapest, Hongrie, 26-31 aout 2004.

        - J.-C. Daran. La Diffraction des Rayons X à Haute Résolution, un Outil de Choix pour le Chimiste de Synthèse. 2ème Congrés Algérien de Cristallographie, 17-21 avril 2005, Alger.

        - R. Malacea, E. Manoury, J.-C. Daran, R. Poli, S. Duckett, J. Dunne, C. Godard. New Ferrocenyl P-S ligands for Asymmetric Catalysis, Applications in the parahydrogen phenomen. GSO-SFC, Toulouse, 16 Novembre 2004.

        - E. Robé, M. Gouygou, J.-C. Daran, C. Ortega, M. Mikina. Nouveaux Ligands 2,2’-Biphospholes Stéréochimiquement Dynamique pour la Catalyse Asymmétrique. GECOM-CONCOORD, Autrans, 5-10 juin 2005.

        - R. Malacea, E. Manoury, J.-C. Daran, R. Poli, Planar-chiral Ferrocenes : New Ferrocenyl ligands for Asymmetric Catalysis. 2nd Annual HYDROCHEM Meeting , 1-2 octobre 2004, Toulouse.

        - E. Manoury, L. Routaboul, S. Vincendeau, J.-C. Daran, Planar-chiral Ferrocenes : Synthesis and Application to Asymmetric Catalysis. 2nd Annual HYDROCHEM Meeting , 1-2 octobre 2004, Toulouse.

        - E. Manoury, . G. Iftime,  J. Chiffre, L. Routaboul, J.-C. Daran, Planar-chiral Ferrocenes: Synthesis and Application to Asymmetric Catalysis. 2ième  Conférence Toulouse-Kiev, 18-22 mai 2005 , Kiev.

        - E. Manoury, . G. Iftime,  J. Chiffre, L. Routaboul, J.-C. Daran, M. Gouygou, R. Malacea, R. Poli,  Composés du ferrocènes chiraux : synthèse et application à la catalyse asymétrique. Gecom-Concoord 2005, 5-10 juin 2005 ,Autrans-Grenoble.

        - R. Malacea , E. Manoury, J.-C. Daran, R. Poli, Ferrocenyl ligands - Ir and Rh complexes. Applications in catalysis - imines hydrogenation. Annual HYDROCHEM Meeting , 15-16 septembre 2005, Camerino.

        - E. Manoury, L. Routaboul, J.-C. Daran, M. Gouygou, R. Malacea, R. Poli, S. Vincendeau, Nouveaux ligands ferrocéniques pour la Catalyse Asymétrique,  Journée de catalyse, 22 septembre 2005, Toulouse

        - M. Gouygou, E. Robé, C. Ortéga, M. Mikina, J.-C. Daran, Ligands phosphorés stéréodynamiques pour la catalyse asymétrique,  Journée de catalyse, 22 septembre 2005, Toulouse

        - L. Diab, M. Urruitgoity, P. Kalck, M. Gouygou, E. Manoury, J.-C. Daran, Contrôle de la stéréoséléctivité par coordination de ligands chiraux adaptés dans les réactions de cyclocarbonylation ,  GECOM – CONCORD, 7-12 Mai 2006 , Ile de Noirmoutier.

        - R. Malacea L. Routaboul, S. Vincendeau, R. Poli, J.-C Daran, E. Manoury, J. P. Dunne, A. C. Withwood C. Godard, S. B. Duckett, E. Le Roux,  L. Gonsalvi, M. Peruzzini , New Chiral Ferrocenyl P,S Ligands for  Asymmetric Catalysis, XXII International Conference on Organometallic Chemistry (ICOMC 2006), July 18-22 juillet 2006, Zaragoza, Espagne.

        - R. Malacea, L. Routaboul, S. Vincendeau, J.-C Daran, R. Poli, E. Manoury, Phosphine-thioéthers ferrocéniques chiraux : utilisation dans l’hydrogénation asymétrique de cétones catalysée par l’iridium., Journée de catalyse, 8 mars 2007, Toulouse.

        - R. Malacea, L. Routaboul, S. Vincendeau, J.-C Daran, R. Poli, E. Manoury, New Chiral Ferrocenyl Phoshine-Thioether Ligands for Asymmetric Catalysis., 4th International Chemistry Conference Toulouse-Kiev, 6-8 juin 2007, Toulouse.

        - R. Malacea, L. Routaboul, S. Vincendeau, J.-C Daran, R. Poli, E. Manoury, E. Le Roux, L. Gonsalvi, M. Peruzzini, J. M. Hayes, G. Ujaque, A. Lledos,  Asymmetric hydrogenation of ketones catalysed by iridium complexes of planar chiral phosphane thioether ligands, 2nd German-French Congress in Organic and Biomolecular Catalysis., 30 juin-5juillet 2007, Calvi.

        - R. Malacea, E. Le Roux, J. M. Hayes, R. Poli, J.-C Daran, E. Manoury, L. Gonsalvi, M. Peruzzini, G. Ujaque, A. Lledos,  Aryl ketone asymmetric hydrogenation catalyzed by iridium complexes of chiral ferrocene phosphine thioether ligands, 18th Mendeleev Congress on General and Applied Chemistry, 23-28 septembre 2007, Moscow, Russia.

        - E. Robé, L. Diab, E. Manoury, S. Vincendeau, J.-C. Daran, M. Gouygou,  Ligands phosphorés chiraux de type phosphole pour la catalyse asymétrique, 2ième Colloque Maroco-Français en Chimie Moléculaire », 12-15 novembre 2007, Toulouse.

        - J.-C. Daran, R. Malacea, L. Routaboul, S. Vincendeau, R. Poli, E. Manoury. Iridium catalyzed hydrogenation with chiral ferrocenyl  P-S ligands. X-ray structure of precatalysts. XXI Congress of  the International Union of Crystallography, 23-31 aout 2008, Osaka, Japon.


    Invited lectures

       -. Quelques aspects de la chimie des ynamines en présence de clusters carbonyles du fer et du ruthénium. Université de Rennes, 13 février 1991.

       - Some aspects of the chemistry of ynamines in iron cluster complexes.
       Instituto de Quimica, U.N.A.M., Mexico, 5 décembre 1991
       Instituto Politécnico Nacional, C.I.N.V.E.S.T.A.V., Mexico, 9 décembre 1991
       University of South Carolina, Columbia, U.S.A., 13 décembre 1991

       - Some aspects of the chemistry of heterocumulenes X=Z=Y with the diiron carbene complex [Fe2(CO)7{C(R)C(NEt2)}]. University of South Carolina, Columbia, U.S.A., 31 mars 1993.

       - Influence de l'Empilement Cristallin sur les Propriétés en Optique Non Linéaire de Composés Ferrocéniques Chiraux., LCM3B, CNRS UPRESA-7036, Université Henri Poincarré, Nancy I, 26 novembre 1999.

       - Synthesis, Crystal Strucrure and Second Order Non-Linear Optical Properties of New Chiral Ferrocenyl Material.
       Instituto de Quimica, U.N.A.M., Mexico, 16 novembre 2000.
       El Centro de Quimica, IC-UAP, Puebla, 21 novembre 2000.
       Instituto Politécnico Nacional, C.I.N.V.E.S.T.A.V., Mexico, 23 novembre 2000.

       - Twinning, don’t give up. Instituto Politécnico Nacional, C.I.N.V.E.S.T.A.V., Mexico, 27 novembre 2000.

- Some Aspects of the Structural and Coordination Chemistry of the 2,2’-Biphosphole. Instituto Politécnico Nacional, C.I.N.V.E.S.T.A.V., Mexico, 29 novembre 2000.

       - Utiliser un ligand stéréolabile pour la catalyse asymétrique, gageure ou réalité. Université Pierre et Marie CURIE, Paris, 14 octobre 2002.

       - La diffraction des rayons X à haute résolution, un outil de choix pour le chimiste. Deuxième Journée Scientifique de Biologie Structurale de l’ IPBS, Toulouse, 26 juin 2003.

        - The use of stereolabile ligands in asymmetric catalyses : dream or reality ? Instituto de Quimica, Universidad Autonoma de México, Mexique, 24 mars 2004.

       - Design and X-ray structure of new chiral ferrocenyl ligands to be used in asymmetric catalyses. Centro de Investigation y de Estudios Avanzados del I.P.N., Mexico, Mexique, 31 mars 2004.

        - Nouveaux Ligands Chiraux, Synthèse, Chimie de Coordination et Catalyse. LCOO UMR5802, Universite de Bordeaux  I, 26 Novembre 2004.

        - Stéréochimie du 2,2’-biphosphole, un ligand stéréolabile pour la catalyse. Université de Bretagne, Brest, 24 février 2006

Collaborations

2002-06   Exchange program with the Instituto de Quimica, UNAM, Mexico (ECOS: Réf. MO2PO4): "Collaboration Interdisciplinaire en Chimie Organométallique, Catalyse et Synthèse".

1999-01   Exchange program with the CINVESTAV-IPN (CONACYT: Réf. 27929U): "Non Linear Optical properties of Boron compounds".

1993        Invited as Research Assistant Professor  (4 months) at the University of South Carolina, Columbia S.C.. The research on “Metal halide cluster complexes of Molybdenum and Tungsten as imaging agents“ were sponsored by a US Chemical Company in the department of Professor Richard D. Adams.

1988-91   Exchange program with the Anorganisch Chemisches Institut der Universität,  Heidelberg, Germany (PROCOPE). Title : "Réaction d'aminoalcynes avec des clusters phosphinidènes du fer ".

1991        Exchange program with the Instituto de Quimica, Universidad Nacional Autonoma de Mexico, Mexico D.F. (CNRS-CONACYT). Title: “ aide au développement de la cristallochimie”.

Curriculum Vitae

Working address
Laboratoire de Chimie de Coordination
UPR-CNRS 8241
205, route de Narbonne
31077 Toulouse Cedex
Tel.: (33) 5 61-33-31-74
Telefax :(33) 5 61-55-30-03
E-mail: jean-claude.daran@lcc-toulouse.fr

Home address
Le Parc de Gounon, les Buis (Appt. 48)
11, rue Sainte Odile
31100 Toulouse

Date and place of birth :
31 janvier 1941, Toulouse (France)

Degrees :
Doctorat ès-Sciences Physiques - 1973
Doctorat de 3ème Cycle, Chimie Structurale - 1967
Licence ès-Sciences Physiques  - 1965

Scientific career :
1968         Stagiaire de Recherche CNRS : Département de Chimie Inorganique, Université Paul SABATIER, Toulouse.
1969         Attaché de Recherche CNRS : Département de Chimie Inorganique, Université Paul Sabatier, Toulouse
1975         Chargé de Recherche CNRS : Laboratoire de Chimie des  Métaux de Transition, URA-CNRS 419, Université Pierre et Marie CURIE, Paris.
1975-77   Research assistant : Chemical Crystallography Laboratory, Oxford, UK.
1985-93   Directeur de Recherche CNRS : Laboratoire de Chimie des Métaux de Transition, URA-CNRS 419, Université Pierre et Marie CURIE, Paris.
1994-2008 Directeur de Recherche CNRS : Laboratoire de Chimie de Coordination, UPR-CNRS 8241, 205, route de Narbonne, 31077 Toulouse cedex.
2008-        Directeur de Recherche Emérite CNRS : Laboratoire de Chimie de Coordination, UPR-CNRS 8241, 205, route de Narbonne, 31077 Toulouse cedex.