Laboratoire de Chimie de Coordination
UPR 8241

Publications Gilles ALCARAZ

[32] Organometallic control at the nanoscale : a new, one-pot method to decorate a magnetic nanoparticle surface with noble metal atoms

Atamena N., Ciuculescu D., Alcaraz G., Smekhova A., Wilhelm F., Rogalev A., Chaudret B., Lecante P., Benfield R. E., Amiens C.

Chem. Commun., 2010, DOI : 10.1039/b925054a, Abstract

[31] Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine-Boranes : Trapping of H₂BNH₂.

G. Alcaraz, L. Vendier, E. Clot, S. Sabo-Etienne,

Angew. Chem., Int. Ed. 2010, 49, 918.Abstract

[30] Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes : Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release

G. Alcaraz, M. Grellier, S. Sabo-Etienne

Acc. Chem. Res.2009, 42 , 1640–1649 Abstract

[29] Tert-butylborane : A bis (σ-B–H) ligand in ruthenium hydride chemistry

Y. Gloaguen, G. Alcaraz, L. Vendier and S. Sabo-Etienne

J. Organomet. Chem.2009, 694, 2839–2841, Abstract

[28] Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

M. Blug, D. Grünstein, G. Alcaraz, S. Sabo-Etienne, X.-F. Le Goff, P. Le Floch and N. Mézailles

Chem. Commun., 2009, DOI : 10.1039/b907813d Abstract

[27] Phosphinoborane and sulfidoborohydride as chelating ligands in polyhydride ruthenium complexes : agostic σ-borane versus dihydroborate coordination

Y. Gloaguen, G. Alcaraz*, A.-F. Pecharman, E. Clot, L. Vendier, S. Sabo-Etienne*

Angew. Chem., Int. Ed. 2009, 48(16), 2964-2968. Abstract

[26] A Terminal Borylene Ruthenium Complex : From B-H Activation to Reversible Hydrogen Release.

G. Alcaraz,* U. Helmstedt, E. Clot, L. Vendier, S. Sabo-Etienne*

J. Am. Chem. Soc., 2008,130, 12878–12879. Abstract

[25]Copper nanoparticles and OrganoMetallic Chemical Liquid Deposition (OMCLD) for substrate metallisation

Clément Barrière, Gilles Alcaraz, Olivier Margeat, Pierre Fau, Jean-Baptiste Quoirin, Christine Anceau, Bruno Chaudret

Journal of Materials Chemistry, 2008, 18, 3084 - 3086 Abstract

[24]NMR : a good tool to ascertain σ-silane or σ-borane formulations ?

G. Alcaraz, S. Sabo-Etienne

Coordination Chemistry Reviews, 2008,252, 2395-2409. Abstract .

[23]Dispirofluorene-Indenofluorene Derivatives as New Building Blocks for Blue Organic Electroluminescent Devices and Electroactive Polymers, Chemistry

Cyril Poriel, Jing-Jing Liang, Joëlle Rault-Berthelot, Frédéric Barrière, Nicolas Cocherel, Alexandra M. Z. Slawin, David Horhant, Morgane Virboul, Gilles Alcaraz, Nathalie Audebrand, Laurence Vignau, Nolwenn Huby, Guillaume Wantz, Lionel Hirsch

Chemistry A European Journal, 2007, 13, 10055-10069.Abstract

[22]Mesitylborane as a bis(σ-B-H) Ligand : an Unprecedented Bonding Mode to a Metal Center

G. Alcaraz, U. Helmstedt, E. Clot, S. Sabo-Etienne

Journal of the American Chemical Society, 2007, 129, 8704-8705.Abstract

[21]Functionnalization of silicon surfaces with Si-C linked -beta-cyclodextrin monolayers

C. Lagrost, A. Gilles, J.-F. Bergamini, B. Fabre, I. Serbanescu

Chemical Communications (Cambridge, United Kingdom) 2007, 1050.Abstract

[20]Dispirofluorene-indenofluorene (DSFIF) : Synthesis, Electrochemical, and Optical Properties of a Promising New Family of Luminescent Materials

D. Horhant, J.-J. Liang, M. Virboul, C. Poriel, G. Alcaraz, J. Rault-Berthelot

Organic Letters 2006, 8, 257.Abstract

[19]Stereospecific palladium-catalyzed borylation reaction of 1-alkenyl halides with diispropylaminoborane

L. Euzenat, D. Horhant, C. Brielles, G. Alcaraz, M. Vaultier

Journal of Organometallic Chemistry 2005, 690, 2721.Abstract

[18]Arylpyrrole, arylfuran, and arylthiophene derivatives with antitubulin activity, their preparation, and use as antimitotic for treating proliferative diseases including cancer

Y. Arlot, B. Martin, J. G. Delcros, G. Alcaraz, O. Paulus

Patent written in French. Application : FR 2004-5278 20040514. 2005, p. 59 pp.Abstract

[17]Product subclass 28 : vinylboranes

M. Vaultier, G. Alcaraz

Science of Synthesis 2004, 6, 721.Abstract

[16](Aryl)(amino)borane compounds and method for their preparation by conversion of amine-borane complex to aminoborane and subsequent catalytic reaction with aryl halides

M. Vaultier, C. Duriez, L. Euzenat, Y. Ribourdouille, G. Alcaraz

Patent written in French. Application : FR 2001-16734 20011221 2003, p. 15 pp.Abstract

[15]Monomeric (dialkylamino)boranes : a new and efficient boron source in palladium catalyzed C-B bond formation with aryl halides

L. Euzenat, D. Horhant, Y. Ribourdouille, C. Duriez, G. Alcaraz, M. Vaultier

Chemical Communications (Cambridge, United Kingdom) 2003, 2280.Abstract

[14]Improved transparency- nonlinearity trade-off with boroxine-based octupolar molecules

G. Alcaraz, L. Euzenat, O. Mongin, C. Katan, I. Ledoux, J. Zyss, M. Blanchard-Desce, M. Vaultier

Chemical Communications (Cambridge, United Kingdom) 2003, 2766.Abstract

[13]A facile synthesis of N-boc-protected pyrroles by cyclodehydration of γ-amino-α,β-enals and -enones

O. Paulus, G. Alcaraz, M. Vaultier

European Journal of Organic Chemistry 2002, 2565.Abstract

[12]Application of the ’resin-capture-release’ methodology to macrocyclization via intramolecular Suzuki-Miyaura coupling

V. Lobregat, G. Alcaraz, H. Bienayme, M. Vaultier

Chemical Communications (Cambridge, United Kingdom) 2001, 817.Abstract

[11]Very stable phosphiranes

J. Liedtke, S. Loss, G. Alcaraz, V. Gramlich, H. Grutzmacher

Angewandte Chemie International Edition 1999, 38, 1623.Abstract

[10]Reactions of a carbosilylated methylenephosphonium ion with p-conjugated hydrocarbons

J. Thomaier, G. Alcaraz, H. Gruetzmacher, H. Hillebrecht, C. Marchand, U. Heim

Journal of Organometallic Chemistry 1997, 535, 91.Abstract

[9]Mechanism of the Exchange Reaction of Halodiazirines with Nucleophiles Revisited. Synthesis of Neutral, Mono- or Dicationic 4-16-Membered Phosphorus Heterocycles

G. Alcaraz, V. Piquet, A. Baceiredo, F. Dahan, W. W. Schoeller, G. Bertrand

Journal of the American Chemical Society 1996, 118, 1060.Abstract

[8] X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2l5-Diazaphosphetes : A New Type of 4-p-Electron 4-Membered Heterocycle

G. Alcaraz, A. Baceiredo, M. Nieger, W. W. Schoeller, G. Bertrand

Inorganic Chemistry 1996, 35, 2458.Abstract

[7]Synthesis of a 2H-azirine by [1+2] cycloaddition of a phosphinocarbene with a nitrile and is ring-expansion to a 1,2l5-azaphosphete

G. Alcaraz, U. Wecker, A. Baceiredo, F. Dahan, G. Bertrand

Angewandte Chemie, International Edition in English 1995, 34, 1246.Abstract

[6]Reactions of stable (phosphino)(silyl)carbenes with iminophosphines

V. Romanenko, A. O. Gudima, A. N. Chernega, J.-M. Sotiropoulos, G. Alcaraz, G. Bertrand

Bulletin de la Societe Chimique de France 1994, 131, 748.

[5]Evidence for Imidoylnitrene Intermediates in the Reaction of Bromophenyldiazirine with Phosphines : First Ring-Expansion Reaction of a Diazirine

G. Alcaraz, A. Baceiredo, M. Nieger, G. Bertrand,

Journal of the American Chemical Society 1994, 116, 2159.Abstract

[4]λ5-Phosphonitriles and λ3-Phosphinonitrenes : Evidence for Nitrene-Lewis Acid Adducts

G. Alcaraz, A. Baceiredo, F. Dahan, G. Bertrand

Journal of the American Chemical Society 1994, 116, 1225.Abstract

[3]Phosphanylcarbenes : from unstable intermediates to x-ray characterized compounds

M. Soleilhavoup, G. Alcaraz, R. Reau, A. Baceiredo, G. Bertrand

Phosphorus, Sulfur and Silicon and the Related Elements 1993, 76, 309.Abstract

[2]Synthesis and evolution of phosphinocarbene-borane adducts

G. Alcaraz, R. Reed, A. Baceiredo, G. Bertrand

Journal of the Chemical Society, Chemical Communications 1993, 1354.Abstract

[1]Phosphanylcarbenes : from unstable intermediates to X-ray characterized compounds

M. Soleilhavoup, G. Alcaraz, R. Réau, A. Bacereido, G. Bertrand

Phosphorus, Sulfur and Silicon, 1993, 76, 49-52.Abstract