Laboratoire de Chimie de Coordination
UPR 8241

Publications Sylviane Sabo-Etienne

[118] Ruthenium-Catalyzed Hydrogenation of Nitriles : Insights into the Mechanism

R. Reguillo, M. Grellier, N. Vautravers, L. Vendier, S. Sabo-Etienne

J. Am. Chem. Soc., 2010, 132 , 7854–7855 Abstract

[117] Interplay between Hydrido/Dihydrogen and Amine/Amido Ligands in Ruthenium-Catalyzed Transfer Hydrogenation of Ketones

A. Picot, H. Dyer, A. Buchard, A. Auffrant, L. Vendier,P. Le Floch, S. Sabo-Etienne,

Inorganic Chemistry 2010, 49, 1310. Abstract

[116] Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine-Boranes : Trapping of H₂BNH₂.

G. Alcaraz, L. Vendier, E. Clot, S. Sabo-Etienne,

Angew. Chem., Int. Ed. 2010, 49, 918.Abstract

[115] High-resolution ²H MAS NMR applied to deuterium analogs of hydrido η²-dihydrogen complexes

S. Macholl, J. Matthes, H.-H. Limbach, S. Sabo-Etienne, B. Chaudret, G. Buntkowsky,

Solid State Nuclear Magnetic Resonance 2009, 36, 137. Abstract

[114] Motional heterogeneity in single-site silica-supported species revealed by deuteron NMR

J. Gath, G. L. Hoaston, R. L. Vold, R. Berthoud, C. Copéret, M. Grellier, S. Sabo-Etienne, A. Lesage, L. Emsley

Phys. Chem. Chem. Phys., 2009, 11, 6962 - 6971 Abstract

[113] Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes : Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release

G. Alcaraz, M. Grellier, S. Sabo-Etienne

Acc. Chem. Res.2009, 42, 1640–1649 Abstract

[112] Tert-butylborane : A bis (σ-B–H) ligand in ruthenium hydride chemistry

Y. Gloaguen, G. Alcaraz, L. Vendier and S. Sabo-Etienne

J. Organomet. Chem.2009, 694, 2839–2841, Abstract

[111] Bonding mode of a new bis-phosphine-borane alkyl ligand to a Rh(I) species

M. Blug, D. Grünstein, G. Alcaraz, S. Sabo-Etienne, X.-F. Le Goff, P. Le Floch and N. Mézailles

Chem. Commun., 2009, 4432 Abstract

[110] Versatile Coordination of 2-Pyridinetetramethyldisilazane at Ruthenium : Ru(II) vs Ru(IV) As Evidenced by NMR, X-ray, Neutron, and DFT Studies

M. Grellier, T. Ayed, J.-C. Barthelat, A. Albinati, S. Mason, L. Vendier, Y. Coppel, and S. Sabo-Etienne

J. Am. Chem. Soc. 2009, 131, 7633. Abstract

[109] Phosphinoborane and sulfidoborohydride as chelating ligands in polyhydride ruthenium complexes : agostic σ-borane versus dihydroborate coordination

Y. Gloaguen, G. Alcaraz*, A.-F. Pecharman, E. Clot, L. Vendier, S. Sabo-Etienne*

Angew. Chem., Int. Ed. 2009, 48(16), 2964-2968. Abstract

[108] When energetic materials, PDMS-based elastomers, and microelectronic processes work together : fabrication of a disposable micro actuator

S. Suhard, P. Fau, B. Chaudret, S. Sabo-Etienne, M. Mauzac, ;A.-F. Mingotaud, , G. Ardila-Rodriguez, C. Rossi ; M.-F. Guimon

Chemistry of Materials 2009, 21(6), 1069-1076. Abstract

[107] A microactuator based on the decomposition of an energetic material for disposable lab-on-chip applications : fabrication and test

G. A Ardila Rodrıguez, S. Suhard, C. Rossi, D. Esteve, P. Fau, S. Sabo-Etienne, A.-F. Mingotaud, M. Mauzac, B. Chaudret

J. Micromech. Microeng. 2009, 19, 015006 Abstract

[106] 2H Solid-State NMR of Ruthenium Complexes

B. Walaszek, A. Adamczyk, T. Pery, X. Yeping, T. Gutmann, N. de Sousa Amadeu, S. Ulrich, H. Breitzke, H. M. Vieth, S.Sabo-Etienne, B. Chaudret, H.-H. Limbach, and G. Buntkowsky*

J. Am. Chem. Soc., 2008, 130, 17502–17508. Abstract

[105] A Terminal Borylene Ruthenium Complex : From B-H Activation to Reversible Hydrogen Release.

G. Alcaraz,* U. Helmstedt, E. Clot, L. Vendier, S. Sabo-Etienne*

J. Am. Chem. Soc., 2008,130, 12878–12879. Abstract

[104] The Bonding Mode of a Bifunctional P Si-H ligand in the Ruthenium Complex "Ru(PPh2CH2OSiMe2H)3"

V. Montiel-Palma, O. Piechaczyk, A. Picot, A. Auffrant, L. Vendier, P. Le Floch,* and S. Sabo-Etienne*

Inorg. Chem., 2008, 47, 8601–8603.Abstract

[103] NMR : A good tool to ascertain σ-silane or σ-borane formulations ?

G. Alcaraz, S. Sabo-Etienne,*

Coord. Chem. Rev., 2008,252, 2395-2409.Abstract

[102] Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols

P. D. Bolton, M. Grellier, N. Vautravers, L. Vendier, S. Sabo-Etienne*

Organometallics, 2008, 27, 5088–5093.Abstract

[101] Heterometallic Werner complexes as energetic materials

C. Pradère, S. Suhard, L. Vendier, G. Jacob, B. Chaudret and S. Sabo-Etienne,*

Dalton Trans., 2008, 2725-2731.Abstract

[100] Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2 Ligands. Easy Access to the FourMembered Ruthenacycle [(p– cymene)RuCl(κC,PCH2CH2PPh2)].

J. Vergnaud, M. Grellier, G. Bouhadir, L. Vendier, S. Sabo-Etienne,* D. Bourissou*,

Organometallics, 2008, 27, 1140-1146.Abstract

[99]Agostic Si-H bond coordination assists C-H bond activation at ruthenium in bis(phosphinobenzylsilane) complexes

V. Montiel-Palma,* M. A. Muñoz-Hernández, T. Ayed, J.-C. Barthelat, M. Grellier, L. Vendier and S. Sabo-Etienne*

Chem. Commun., 2007, 3963-3965.Abstract

[98] Mesitylborane as a bis(σ-B-H) ligand : an unprecedented bonding mode to a metal center

G. Alcaraz,* E. Clot,* U. Helmstedt, L. Vendier, and S. Sabo-Etienne*

J. Am. Chem. Soc. 2007, 129, 8704-8705.Abstract

[97] Activation of chlorosilanes at ruthenium : a route to silyl σ-dihydrogen complexes

S. Lachaize, A. Caballero, L. Vendier and S. Sabo-Etienne*

Organometallics 2007, 26, 3713-3721.Abstract

[96] Synthesis, structure and coordination of the ambiphilic ligand (2-picolyl)BCy2

J. Vergnaud, T. Ayed, K. Hussein, L. Vendier, M. Grellier, G. Bouhadir, J.-C. Barthelat, S. Sabo-Etienne,* D. Bourissou*

Dalton Trans., 2007, 2370-2372.Abstract

[95] Agostic Interaction and Intramolecular Proton Transfer from the Protonation of Dihydrogen Ortho Metalated Ruthenium Complexes.

A. Toner, J. Matthes, S. Gründemann, H.-H. Limbach, B. Chaudret, E. Clot, and S. Sabo-Etienne*

P.N.A.S. 2007, 104, 6945-6950.Abstract

[94] Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands : Reversible Hydrogen Release.

M. Grellier,* L. Vendier, and S. Sabo-Etienne*

Angew. Chem. Int. Ed. 2007, 46, 2613-2615.Abstract

[93] The σ-CAM Mechanism : σ-Bond Metathesis is Established for Late Transition Metals through σ-Complexes.

R. N. Perutz* and S. Sabo-Etienne*

Angew. Chem. Int. Ed.2007, 46, 2578-2592.Abstract

[92] Ruthenium-Catalyzed Hydroboration and Dehydrogenative Borylation of Linear and Cyclic Alkenes with Pinacolborane.

A. Caballero, and S. Sabo-Etienne*

Organometallics 2007, 26, 1191-1195.Abstract

[91] σ-Silane Ruthenium Complexes. The Crucial Role of Secondary Interactions

S. Lachaize and S. Sabo-Etienne*

Eur. J. Inorg. Chem. 2006, 2115-2127.Abstract and Correction

[90] Synthesis, Neutron Structure and Reactivity of the Bis(dihydrogen) Complex RuH2(η2-H2)2(PCyp3)2 Stabilized by Two Tricyclopentylphosphines.

M. Grellier, L. Vendier, B. Chaudret, A. Albinati, S. Rizzato, S. Mason, and S. Sabo-Etienne*

J. Am. Chem. Soc. 2005, 127, 17592-17593.Abstract

[89] Structure and Bonding in a Disilazane Ruthenium Complex. Catalytic Selective Deuteration of Disilazane.

T. Ayed, J.-C. Barthelat, B. Tangour, C. Pradère, B. Donnadieu, M. Grellier, and S. Sabo-Etienne*

Organometallics 2005, 24, 3824-3826.Abstract

[88] Coordination Modes of Boranes in Polyhydride Ruthenium Complexes : σ-Borane versus Dihydridoborate.

S. Lachaize, K. Essalah, V. Montiel-Palma, L. Vendier, B.Chaudret, J.-C. Barthelat, and S. Sabo-Etienne*

Organometallics 2005, 24,2935-2943.Abstract

[87] Ruthenium : Inorganic and Coordination Chemistry.

S. Sabo-Etienne,* M. Grellier.

Encyclopedia of Inorganic Chemistry . 2nd edition Editeur : R.B. King, John Wiley & Sons,Ltd. 2005, 7, 4757-4778.Abstract

[86] Platinum Bis(tricyclohexylphosphine) Silyl Hydride Complexes

D. Chan, S. B. Duckett, S. L. Heath, I. G. Khazal, R. N. Perutz, S. Sabo-Etienne and P. L. Timmins

Organometallics2004, 23, 5744-5756.Abstract

[85] Bridging the Gap between Homogeneous and Heterogeneous Catalysis : ortho/para-H2 Conversion, Hydrogen Isotope Scrambling and Hydrogenation of Olefins by Ir(CO)Cl(PPh3)2

J. Matthes, T. Pery, S. Gründemann, G. Buntkowsky, S. Sabo-Etienne, B. Chaudret, and H.-H. Limbach

J. Am. Chem. Soc.,2004, 126, 8366-8367.Abstract

[84] Catalytic isomerization of cyanoolefins involved in the adiponitrile process. C-CN bond cleavage and structure of the nickel -allyl cyanide complex Ni(η3-1-MeC3H4)(CN)(dppb)

A. Chaumonnot, F. Lamy, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, J.-C. Barthelat and J.-C. Galland.

Organometallics, 2004, 23, 3363-3365.Abstract

[83] Orthometallated Hydrido Dihydrogen Ruthenium Complexes : Dynamics, Exchange Couplings and Reactivity

J. Matthes, S. Gründemann, A. Toner, Y. Guari, B. Donnadieu, J. Spandl, S. Sabo-Etienne, E. Clot, H.-H. Limbach and B. Chaudret

Organometallics, 2004, 23, 1424-1433.Abstract

[82] Photochemical oxidative addition of B-H bonds at ruthenium and rhodium.

P. L. Callaghan, R. Fernandez-Pacheco, N. Jasim, S. Lachaize, T. B. Marder, R. N. Perutz, E. Rivalta and S. Sabo-Etienne

Chem. Commun. 2004,.242-243.Abstract

[81] RuH2(H2)2(PCy3)2. A Room Temperature Catalyst for the Murai Reaction.

Y. Guari, A. Castellanos, S. Sabo-Etienne and B. Chaudret.

J. Mol. Catal., 2004, 212, 77-82.Abstract

[80] Reactivity of the Bis(dihydrogen) Complex [RuH2(2-H2)2(PCy3)2] toward S-Heteroaromatic Compounds. Catalytic Hydrogenation of Thiophene

A. F. Borowski, S. Sabo-Etienne, B. Donnadieu, B. Chaudret

Organometallics, 2003, 22, 4803-4809.Abstract

[79] Redistribution at silicon by ruthenium complexes. Bonding Mode of the Bridging Silanes in Ru2H4(--SiH4)(PCy3)4 and Ru2H2(2 :2-H2Si(OMe)2)3(PCy3)2.

R. Ben Said, Khansaa Hussein, J.-C. Barthelat, I. Atheaux, S. Sabo-Etienne, M. Grellier, B. Donnadieu and B. Chaudret

Dalton Trans., 2003, 4139-4146 Abstract

[78] 9-BBN activation. Synthesis, crystal structure and theoretical characterization of the ruthenium complex Ru[(-H)2BC8H14]2(PCy3)

K. Essalah, J.-C. Barthelat, V. Montiel, S. Lachaize, B. Donnadieu, B. Chaudret, S. Sabo-Etienne

J. Organomet. Chem., 2003, (special issue on boron chemistry) 680, 182-187.Abstract

[77]A DFT study of germane activation in ruthenium complexes. -coordination versus oxidative addition.

R. Ben Said, K. Hussein, B. Tangour, S. Sabo-Etienne, J.–C. Barthelat

New J. Chem., 2003, 27, 1385-1391.Abstract

[76] A density functional theory study of dinitrogen bonding in ruthenium complexes

R. Ben Said, K. Hussein, B. Tangour, S. Sabo-Etienne, J. –C. Barthelat

J. Organomet. Chem., 2003, 673, 56-66Abstract

[75] Reactivity of the Bis(dihydrogen) Complex [RuH2(2-H2)2(PCy3)2] towards N-Heteroaromatic Compounds. Regioselective Hydrogenation of Acridine to 1,2,3,4,5,6,7,8-Octahydroacridine

A. F. Borowski, S. Sabo-Etienne, B. Donnadieu, B. Chaudret

Organometallics, 2003, 22, 1630-1637.Abstract

[74] Ruthenium Dihydrogen Complexes with Wide Bite Angle Diphosphines.

K. Almeida Leñero, M. Kranenburg, Y. Guari, P. C. J. Kamer, P. W. N. M. van Leeuwen, S. Sabo-Etienne, B. Chaudret

Inorg. Chem.2003, 42, 2859-2866.Abstract

[73] Mechanistic studies on catalytic ethylene silylation with chlorosilanes by ruthenium complexes.

S. Lachaize, S. Sabo-Etienne, B. Donnadieu, B. Chaudret

Chem. Commun., 2003, 214-215.Abstract

[72] Exchange Processes in Complexes with Two Ruthenium (2-silane) linkages : Role of the Secondary Interactions between Silicon and Hydrogen Atoms

I. Atheaux, F. Delpech, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, K. Hussein, J.-C. Barthelat, T. Braun, S. B. Duckett, R. N. Perutz

Organometallics, 2002, 21, 5347-5357.Abstract

[71] -Borane and dihydroborate complexes of ruthenium

V. Montiel-Palma, M. Lumbierres, B. Donnadieu, S. Sabo-Etienne, B. Chaudret

J. Am. Chem. Soc., 2002, 124, 5624-5625.Abstract

[70] Hydrides and Dihydrogen Ruthenium Complexes : a Continuation of Joe Chatt’s Chemistry

S. Sabo-Etienne, B. Chaudret

Modern Coordination Chemistry. The legacy of Joseph Chatt,eds. G.L. Leigh, N. Winterton, RSC, UK, 2002, 45-58.Abstract

[69] Ruthenium Carbene Complexes Containing a Triazolidene Cationic Ligand

Chaumonnot, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, C. Buron, G. Bertrand, P. Metivier

Organometallics, 2001, 20, 5614-5618.Abstract

[68] Homogeneous hydrogenation of arenes catalyzed by the (bis)dihydrogen) complex RuH2(2-H2)2(PCy3)2

F. Borowski, S. Sabo-Etienne, B. Chaudret

J. Mol. Catal., 2001, 174, 69-79.Abstract

[67] Preparation and characterization of Ruthenium(II) monophosphaferrocene complexes. Reactivity, dynamic solution behavior, and X-ray structure of RuH2(2-H2)(PCy3)2(2-phenyl-3,4-dimethylphosphaferrocene)

A.J. Toner, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, X. Sava, F. Mathey, P. Le Floch

Inorg. Chem., 2001, 40, 3034-3038.Abstract

[66] Synthesis, X-ray crystal structure, NMR characterization and theoretical calculations on [Cp2Ta(2-H2)(CO)]+, the first thermally stable group 5 dihydrogen complex

S. Sabo-Etienne, V. Rodriguez, B. Donnadieu, B. Chaudret, H.A. El Makarim, J.-C. Barthelat, S. Ulrich, H-H. Limbach, C. Moise

New J. Chem., 2001, 55-62.Abstract

[65]Ruthenium-Catalyzed Silylation of Ethylene by Disilanes

F. Delpech, J. Mansas, H. Leuser, S. Sabo-Etienne, B. Chaudret

Organometallics, 2000, 19, 5750-5757.Abstract

[64] Ruthenium assisted reversible proton transfer from an aromatic carbon to a hydride

A.J. Toner, S. Gründemann, E. Clot, H-H. Limbach, B. Donnadieu, S. Sabo-Etienne, B. Chaudret

J. Am. Chem. Soc., 2000, 122, 6777-6778.Abstract

[63] A unique coordination of SiH4 : isolation, characterization and theoretical study of (PR3)2H2Ru(SiH4)RuH2(PR3)2

I. Atheaux, B. Donnadieu, V. Rodriguez, S. Sabo-Etienne, B. Chaudret, K. Hussein, J.C. Barthelat

J. Am. Chem. Soc., 2000, 122, 5664-5665Abstract

[62] Ruthenium dihydridobis(pyrazolyl) borate complexes adopting a k3 N,N,H or k2 N,H or k2 N,N bonding mode.

V. Rodriguez, I. Atheaux, B. Donnadieu, S. Sabo-Etienne, B. Chaudret

Organometallics, 2000,. 19, 2916-2926.Abstract

[61]Two photochemical pathways in competition : matrix isolation, time-resolved and NMR studies of cis-Ru(PMe3)4(H2)2

V. Montiel-Palma, R.N. Perutz, M.W. George, O.S. Jina, S. Sabo-Etienne

Chem. Commun. 2000, 1175-1176.Abstract

[60] X-ray crystal structure of the bis(dihydrogen) complex RuH2(H2) 2(PCy3)2

A. Borowski, B. Donnadieu, J._C. Daran, S. Sabo-Etienne, B. Chaudret

Chem. Commun. 2000, 543-544.Abstract

[59] Proton Transfer in Aminocyclopentadienyl Ruthenium Hydride Complexes

J. A. Ayllon, S. F. Sayers, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, E. Clot

Organometallics, 1999,. 18,.3981-3990.Abstract

[58] Solvent-assisted reversible proton transfer within an intermolecular dihydrogen bond and characterization of an unstable dihydrogen complex

S. Gründemann, S. Ulrich, H-H. Limbach, N. S. Golubev, G. S. Denisov, L. M.  Epstein, S. Sabo-Etienne, B. Chaudret

Inorg.Chem., 1999, 38, 2550-2551.Abstract

[57] X-Ray Structure and Theoretical Studies of RuH2(2-H2)(2-H-SiPh3)(PCy3)2 a Complex with Two Different 2-Coordinated  bonds

K. Hussein, C.J. Marsden, J.-C. Barthelat, V. Rodriguez, S. Conejero, S. Sabo-Etienne, B. Donnadieu, B. Chaudret

Chem. Commun. 1999, 1315-1316.Abstract

[56] Fast 1H NMR Relaxation in some Ruthenium Hydrides

A. Castellanos, J.A. Ayllon, S. Sabo-Etienne, B. Donnadieu, B. Chaudret, W. Yao, K. Kavallieratos and R.H. Crabtree.

Comptes Rendus Acad Sc. 1999, 359-368.Abstract

[55] Ruthenium Complexes Containing Two Ru-(2-Si-H) bonds : Synthesis, Spectroscopic Properties, Structural Data, Theoretical Calculations and Reactivity Studies

F. Delpech, S. Sabo-Etienne, J.-C. Daran, B. Chaudret, K. Hussein, C. J. Marsden, J.-C. Barthelat

J. Am. Chem. Soc., 1999, 121, 6668-6682.Abstract

[54] Distance and Scalar HD-Coupling Correlations in Transition Metal Dihydrides - Dihydrogen Complexes

S. Gründemann, H-H. Limbach, G. Buntkowsky, S. Sabo-Etienne, B. Chaudret

J. Phys. Chem., 1999, 103,4752-4754.Abstract

[53] Catalytic Formation of Carbon-Carbon bonds through Activation of Carbon-Hydrogen Bonds.

Y. Guari, S. Sabo-Etienne, B. Chaudret

Eur. J. Inorg. Chem., 1999, 1047-1055.Abstract

[52] Stoichiometric and Catalytic Activation of Allyl(dimethyl)silane. Synthesis of [RuH24-HSiMe2(CH=CHMe)(PCy3)2].

F. Delpech, S. Sabo-Etienne*, B. Donnadieu, B. Chaudret Organometallics, 1998, 17, 4926-4928.Abstract

[51] NMR and INS line shapes of transition metal hydrides in the presence of coherent and incoherent dihydrogen exchange.

H.H. Limbach, S. Ulrich, S. Grundemann, G. Buntkowski, S. Sabo-Etienne, B. Chaudret, G.J. Kubas, J. Eckert. J. Am. Chem. Soc., 1998, 120, 7929-7943.Abstract

[50] Hydride and dihydrogen ruthenium complexes of the tripyrrolylphosphine ligand.

V. Rodriguez, B. Donnadieu, S. Sabo-Etienne, B. Chaudret

Organometallics, 1998, 17, 3809-3814Abstract

[49] Quantum mechanical exchange coupling in polyhydride and dihydrogen complexes.

S. Sabo-Etienne, B. Chaudret Chem. Rev., 1998,98, 2077-2091.Abstract

[48] Chemistry of bis(dihydrogen) ruthenium complexes and of their derivatives.

S. Sabo-Etienne, B. Chaudret

Coord. Chem. Rev., 1998, 178-180, 381-407.Abstract

[47] Coherent and incoherent dihydrogen dynamics in a ruthenium trihydride complex with the tris(pyrrolyl)phosphine ligand.

S. Grundemann, H.-H. Limbach, V. Rodriguez, B. Donnadieu, S. Sabo-Etienne, B. Chaudret

Berichte der Bunsenges. Phys. Chem., 1998, 102, 344-353.Abstract

[46] Fluxionality and isomerism of the bis(dihydrogen) complex RuH2(H2)2(PCy3)2 ; INS, NMR and theoretical studies.

V. Rodriguez, S. Sabo-Etienne, B. Chaudret, J. Thoburn, S. Ulrich, H.-.H. Limbach, J. Eckert, J.-C. Barthelat, K. Hussein, C. J. Marsden

Inorg. Chem., 1998,.37, 3475-3485.Abstract

[45] Exchange Couplings between a Hydride and a Stretched Dihydrogen Ligand in Ruthenium Complexes.

Y. Guari, S. Sabo-Etienne, B. Chaudret

J. Am. Chem. Soc., 1998, 120, 4228-4229.Abstract

[44] Influence of Hydrogen Bonding on the Spectroscopic Properties and on the Reactivity of Ruthenium Hydrido Dihydrogen Complexes.

Y. Guari, J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, B. Hessen.

Inorg. Chem., 1998, 37, 640-644.Abstract

[43] Exchange Couplings and Hydrogen Dynamics in Ruthenium Trihydride Adducts with Coinage Metal Cations

B. Manzano, F. Jalon, J. Matthes, S. Sabo-Etienne, B. Chaudret, S. Ulrich, H.H. Limbach. J. Chem. Soc. Dalton, 1997, 3153-3157.Abstract

[42] Synthesis, Characterization and Some Chemistry of (bpF)RuH(COD) (bpF = H2B[N2C3H(CF3)2]), an Electrophilic Hydrido Ruthenium Complex.

V. Rodriguez, J. Full, B. Donnadieu, S. Sabo-Etienne, B. Chaudret New J. Chem., 1997, 21, 847-849.Abstract

[41]First NMR observation of the intermolecular dynamic proton transfer equilibrium between a hydride and coordinated dihydrogen : (dppm)2HRuH...H-OR = [(dppm)2HRu(H2)]+(OR)-

J. A. Ayllon, C. Gervaux, S. Sabo-Etienne, B. Chaudret Organometallics, 1997, 16, 2000-2002.Abstract

[40] Synthesis and Characterization of Chelating Bis(silane) Complexes [RuH22-HSiMe2)2X(PCy3)2] (X = C6H4, O) Containing Two Ru-(2-Si-H) Bonds

F. Delpech, S. Sabo-Etienne, B. Chaudret, J.-C. Daran J. Am. Chem. Soc., 1997, 119, 3167-3168.Abstract

[39] Modulation of Quantum Mechanical Exchange Couplings in Transition Metal Hydrides through Hydrogen Bonding

J. A. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich, H.-.H. Limbach

Inorg. Chim. Acta (special issue on hydrides) 1997, 259, 1-4.Abstract

[38] Synthesis and Reactivity of Stretched Dihydrogen Ruthenium Complexes. Unexpected Formation of a Vinylidene Ligand.

Y. Guari, S. Sabo-Etienne, B. Chaudret Organometallics, 1996, 15, 3471-3473.Abstract

[37] Thermal decomposition of the bis(dihydrogen) complex RuH2(H2)2(PCy3)2 in the solid state.

B. Chaudret , P. Dagnac, D. Labroue, S. Sabo-Etienne

New J. Chem., 1996, 20, 1137-1141.Abstract

[36 ] Reactions of RuH2(H2)2(PCy3)2 with boranes. Synthesis of novel unsaturated and dihydrogen borohydride complexes and reactivity towards water

A. Rodriguez, S. Sabo-Etienne, B. Chaudret

Anal. de Quim., 1996, 92, 131-133.Abstract

[35] Versatile Reactivity of the Bis Dihydrogen Complex RuH2(H2)2(PCy3)2 Toward Functionalized Olefins : Olefin Coordination Versus Hydrogen Transfer Via the Stepwise Dehydrogenation of the Phosphine Ligand

A. F. Borowski, S. Sabo-Etienne, M. L. Christ, B. Donnadieu, B. Chaudret

Organometallics, 1996, 15, 1427-1434Abstract

[34] On the reactivity of 1,3-diphenylisobenzofuran in the presence of either tert-butyl hydroperoxide and catalytic amounts of chromium trioxide or oxygen

A. N’Ait-Ajjou, S. Ait-Mohand, C. Richard, S. Sabo-Etienne, J. Muzart.

New J. Chem., 1996, 20, 571-577.Abstract

[33] Upon the chemical origin of exchange couplings in d2 systems

S. Sabo-Etienne, B. Chaudret, H. Abou-el-Makarim, J.C. Barthelat, J.P. Daudey, S. Ulrich, H.H. Limbach, C. Moise.

J. Am. Chem. Soc., 1995, 117, 11602-11603.Abstract

[32] Pentamethylcyclopentadienyl Ruthenium Complexes as Potential Optically Non-Linear Materials

D.W. Bruce, A. Thornton, B. Chaudret, S. Sabo-Etienne, T.L. Axon, G.H. Cross.

Polyhedron, 1995, 14, 1765-1770.Abstract

[31] Synthesis and Reactivity of Hydrido tris(pyrazolyl)borate dihydrogen ruthenium complexes

B. Moreno, S. Sabo-Etienne, B. Chaudret, A. Rodriguez, F. Jalon, S. Trofimenko.

J. Am. Chem. Soc., 1995, 117, 7441-7451.Abstract

[30] Highly Selective Dehydrogenative Silylation of Ethylene Using the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2 as Catalyst Precursor

M.L. Christ, S. Sabo-Etienne, B. Chaudret.

Organometallics, 1995, 14, 1082-1084.Abstract

[29] Reduction of Ketones by Dihydrogen or Hydrogen Transfer Catalysed by a Ruthenium Complex of the Hydruro 3,5-dimethyl-pyrazolylborate Ligand.

C. Vicente, G.B. Shul’pin, B. Moreno, S. Sabo-Etienne, B. Chaudret.

J. Mol. Catal., 1995, 98, L5-L8.Abstract

[28] RuHX(H2)(PiPr3)2 (X= Cl, I) : 16 Electron Dihydrogen-Hydride or Trihydride Complexes ?

T. Burrow, S. Sabo-Etienne, B. Chaudret.

Inorg. Chem., 1995, 34, 2470-2472.Abstract

[27] Synthesis and Some Reactivity of Pentamethylcyclopentadienyl Ruthenium Complexes with a SnCl3 Ligand. X-Ray Crystal Structure of (C5Me5)Ru(SnCl3)(COD).

B. Moreno, S. Sabo-Etienne, F. Dahan, B. Chaudret.

J. Organomet. Chem., 1995, 498, 139-145.Abstract

[26] Reactivity of the Bis Dihydrogen Complex RuH2(H2)2(PCy3)2 Toward Small Molecules and Weak Acids.

M.L. Christ, S. Sabo-Etienne, G. Chung, B. Chaudret.

Inorg. Chem., 1994, 33, 5316-5319.Abstract

[25] Synthesis, Characterization and Chemistry of 16 Electron Dihydrogen Complexes of Ruthenium

M.L. Christ, S. Sabo-Etienne, B. Chaudret.

Organometallics, 1994, 13, 3800-3804.Abstract

[24] [Cp2Ta(2-H2)(CO)]BF4, the First Thermally Stable Group 5 Dihydrogen Complex

S. Sabo-Etienne, B. Chaudret, H. Abou-el-Makarim, J.C. Barthelat, J.P. Daudey, C. Moise, J.C. Leblanc.

J. Am. Chem. Soc., 1994, 116, 9335-9336.Abstract

[23] Design and Study of Rh(III) Catalysts for the Selective Tail-to-Tail Dimerization of Methyl Acrylate.

E. Hauptman, S. Sabo-Etienne, P.S. White, M. Brookhart, M.J. Garner, P.J. Fagan, J.C. Calabrese.

J. Am. Chem. Soc., 1994, 116, 8038-8060.Abstract

[22] Ruthenium : Inorganic and Coordination Chemistry.

B. Chaudret, S. Sabo-Etienne.

Encyclopedia of Inorganic Chemistry. Editeur : R.B. King, John Wiley & Sons,Ltd. 1994,vol 7, 3514-3533.Abstract

[21] Activation of Carbon-Sulfur and Carbon-Chlorine Bonds by the Electrophilic Ruthenium Fragment “Cp*Ru+”.

D. Rondon, J. Delbeau, X.D. He, S. Sabo-Etienne, B. Chaudret.

J. Chem. Soc. Dalton, 1994,1895-1901.Abstract

[20] Synthesis and Reactivity of a Stable Hydrido Bis(dihydrogen) Derivative in a Nitrogen Donor Environment LRuH(H2)2 ; L = HB(3,5Me2-pz), HB(3-iPr,4-Br-pz).

B. Moreno, S. Sabo-Etienne, B. Chaudret, A. Rodriguez-Fernandez, F. Jalon, S.Trofimenko.

J. Am. Chem. Soc., 1994, 116, 2635-2636.Abstract

[19] Substitution Reactions of Coordinated Dihydrogen by Weakly Coordinating Ligands. Preparation of RuH2(N2)2(PCy3)2 and RuH2(2-H2)(HEPh3)(PCy3)2 (E = Si, Ge) .

S. Sabo-Etienne, M. Hernandez, G. Chung, B. Chaudret, A. Castel.

New J. Chem., 1994, 18, 175-177.Abstract

[18] Reactivity of Cp*Ru+ with acyclic unsaturated hydrocarbons : a novel catalytic carbon- carbon bond activation reaction.

R. Carreno, B. Chaudret, D. Labroue, S. Sabo-Etienne.

Organometallics, 1993,12, 13-14.Abstract

[17] Rh(III) catalysts for tail-to-tail dimerization of methyl acrylate.

M. Brookhart, E. Hauptman, S. Sabo-Etienne.

Proceedings of the Fourth Symposium of Organic Synthesis via Organometallics (OSM 4), 1992, 69-77.Abstract

[16] Reactions of quinones and quinoïd molecules with the “Cp*Ru+” fragment.Electron redistribution and transposition reactions.

Y. Huang, S. Sabo-Etienne, X. He, B. Chaudret, K. Boubekeur, P. Batail.

Organometallics, 1992,11, 3031-3035.Abstract

[15] Catalytic tail-to-tail dimerization of methyl acrylate using Rh(III) catalysts.

M. Brookhart, S. Sabo-Etienne.

J. Am. Chem. Soc., 1991, 113, 2777-2779.Abstract

[14] Heterobimetallic Mo-Ru and Mn-Ru complexes from direct reactions of RuH2(dppm)2 with metal carbonyls.

H. Ben Laarab, B. Chaudret, F. Dahan, J. Devillers, R. Poilblanc, S. Sabo-Etienne.

New J. Chem., 1990,14, 321-330.Abstract

[13] Synthesis of the ethyl oxalyl tetracarbonyl iron anion [(CO)4FeCOCO2Et]-, its methylation at the metal into (CO)4Fe(Me)(COCO2Et) and further carbon-carbon coupling into ethyl pyruvate.

S. Sabo-Etienne, A.-M. Larsonneur, H. Des Abbayes.

J. Chem. Soc., Chem. Commun., 1989, 1671-1673.Abstract

[12] Synthesis of alkyl(alkoxycarbonyl)tetracarbonyliron complex (CO)4Fe(CH2CO2Me)(CO2R) : the first evidence of their relevance to the catalytic cycle in the carbonylation of organic halides induced by pentacarbonyliron.

P. Laurent, S. Sabo-Etienne, A.-M. Larsonneur, H. Des Abbayes.

J. Chem. Soc., Chem. Commun., 1988, 929-930. Abstract

[11] Reaction of benzoyl chloride with Collman’s reagent, Na2Fe(CO)4. Synthesis and crystal structure of the unexpected organoiron product, a new binuclear complex with a triply coordinated oxygen atom, Fe2(CO)6(-C2Ph2O).

S. Sabo-Etienne, H. Des Abbayes, L. Toupet.

Organometallics, 1987, 6, 2262-2263.Abstract

[10] Preparation of reactive low-valent bis(diphenylphosphino)methane bridged Mo-Ru complexes. Facile heterobimetallic activation of molecular hydrogen.

B. Chaudret, F. Dahan, S. Sabo. Organometallics, 1985, 4, 1490-1492.Abstract

[9] Metathetical reactions of carbonylate anions with dichlororuthenium complexes :preparation and characterization of ruthenium-molybdenum and ruthenium-manganese complexes.

S. Sabo, B. Chaudret, D. Gervais.

J. Organomet. Chem., 1985, 292, 411-418.

[8] Structure of tricarbonyl bis(triphenylphosphine)ruthenium(0) hemitetrahydrofuran, Ru(CO)3 (P(C6H5)3)2 0.5 (C4H8O).

F. Dahan, S. Sabo, B. Chaudret.

Acta Crystallogr., Sect. C, 1984, 40C, 786-788.Abstract

[7] Direct reactions between organometallic complexes of ruthenium and zirconium ( or titanium) redistribution and formation of a methylene bridged heterobimetallic ruthenium-zirconium complex.

S.Sabo, B. Chaudret, D. Gervais.

Nouv. J. Chim., 1983, 7, 181-184.Abstract

[6] Metal-metal bonded ruthenium-manganese complexes : an unexpected phosphido- bridged complex.

S. Sabo, B. Chaudret, D. Gervais.

J. Organomet. Chem., 1983, 258, C19-C22.Abstract

[5] Electron spin resonance studies on bis(chloroalkoxy)-bis(-cyclopentadienyl) vanadium (IV) complexes.

S. Sabo, R. Choukroun, D. Gervais.

J. Chem. Soc., Dalton Trans., 1983, 2695-2697.Abstract

[4] Activation of a methyl group bonded to zirconium by a ruthenium species : preparation of a methylene briged heterobimetallic ruthenium zirconium complex [(5-C5H5)2Zr(- Cl)(-CH2) RuCl(PPh3)2]2.

S. Sabo, B. Chaudret, D. Gervais, R. Poilblanc. Nouv. J. Chim., 1981,5, 597-598.Abstract

[3] Electron spin resonance spectra of a Ti(IV)-Ti(III) mixed-valence tetranuclear species Ti4(OR)12O.

S. Sabo, R. Choukroun, D. Gervais.

J. Chem. Soc., Dalton Trans., 1981, 2328-2330.Abstract

[2] Un alkoxohydrurotitane à valence mixte : Ti4(OEt)13H.

S. Sabo, D. Gervais.

C. R. Séances Acad. Sci., Sér.C, 1980, 291, 207-209.Abstract

[1] Organometallic compounds of vanadium(V), phenyl alkoxyoxovanadium derivatives.

R. Choukroun, S. Sabo.

J. Organomet. Chem., 1979, 182, 221-224.Abstract