Laboratoire de Chimie de Coordination UPR 8241

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Bruneau-Voisine, A., Pallova, L., Bastin, S., Cesar, V., & Sortais, J. - B. (2019). Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chem. Commun., 55(3), 314–317.
Cloutier, J. - P., Rechignat, L., Canac, Y., Ess, D. H., & Zargarian, D. (2019). C–O and C–N functionalization of cationic, NCN-type pincer complexes of trivalent nickel: Mechanism, selectivity, and kinetic isotope effect. Inorg. Chem., 58(6), 3861–3874.
Kulai, I., Karpus, A., Soroka, L., Valyaev, D. A., Bourdon, V., Manoury, E., Poli, R., Destarac, M., & Mazieres, S. (2019). Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment. Polym. Chem., 10(2), 267–277.
Taakili, R., Lepetit, C., Duhayon, C., Valyaev, D. A., Lugan, N., & Canac, Y. (2019). Palladium(ii) pincer complexes of a C,C,C-NHC, diphosphonium bis(ylide) ligand. Dalton Trans., 48, 1709–1721.


Azouzi, K., Duhayon, C., Benaissa, I., Lugan, N., Canac, Y., Bastin, S., & Cesar, V. (2018). Bidentate iminophosphorane-NHC ligand derived from the imidazo[1,5-a]pyridin-3-ylidene scaffold. Organometallics, 37(24), 4726–4735.
Barthes, C., Bijani, C., Lugan, N., & Canac, Y. (2018). A palladium(II) complex of a C4 chelating bis(NHC) diphosphonium bis(ylide) igand. Organometallics, 37(5), 673–678.
Canac, Y. (2018). Carbeniophosphines versus phosphoniocarbenes: The role of the positive charge. Chem. – Asian J., 13(15), 1872–1887.
Cesar, V., Mallardo, V., Nano, A., DePeter, S. F., Bastin, S., Sournia-Saquet, A., Maisse-François, A., Lugan, N., & Bellemin-Laponnaz, S. (2018). Homo- and heteropolymetallic complexes of the hybrid, ambidentate N-heterocyclic carbene Ligand IMes-acac. ACS Omega, 3(11), 15582–15591.
Grineva, A. A., Valyaev, D. A., Cesar, V., Filippov, O. A., Khrustalev, V. N., Nefedov, S. E., & Lugan, N. (2018). Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s. Angew. Chem., Int. Ed., 57(27), 7986–7991.
Lepetit, C., Vabre, B., Canac, Y., Alikhani, M. E., & Zargarian, D. (2018). Pentacoordinated, square pyramidal cationic PCP Ni(II) pincer complexes: ELF and QTAIM topological analyses of nickel–triflate interactions. Theor. Chem. Acc., 137(11), 141.
Li, H., Wei, D., Bruneau-Voisine, A., Ducamp, M., Henrion, M., Roisnel, T., Dorcet, V., Darcel, C., Carpentier, J. - F., Soulé, J. - F., & Sortais, J. - B. (2018). Rhenium and manganese complexes bearing amino-bis(phosphinite) ligands: Synthesis, characterization, and catalytic activity in hydrogenation of ketones. Organometallics, 37(8), 1271–1279.
Ruamps, M., Bastin, S., Rechignat, L., Sournia-Saquet, A., Valyaev, D. A., Mouesca, J. - M., Lugan, N., Maurel, V., & Cesar, V. (2018). Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes. Chem. Commun., 54(55), 7653–7656.
Valyaev, D. A., Utegenov, K. I., Krivykh, V. V., Willot, J., Ustynyuk, N. A., & Lugan, N. (2018). Dual reactivity pattern of Mn(I) carbyne complexes Cp(CO)2Mn+≡C–R (R = Ar, Alk) vs. dppm: Subtle balance between double intramolecular nucleophilic addition and nucleophilic addition followed by migratory CO insertion. J. Organomet. Chem., 867, 353–358.
Wang, D., Bruneau-Voisine, A., & Sortais, J. - B. (2018). Practical (asymmetric) transfer hydrogenation of ketones catalyzed by manganese with (chiral) diamines ligands. Catal. Commun., 105, 31–36.
Wei, D., Bruneau-Voisine, A., Chauvin, T., Dorcet, V., Roisnel, T., Valyaev, D. A., Lugan, N., & Sortais, J. - B. (2018). Hydrogenation of carbonyl derivatives catalysed by manganese complexes bearing bidentate pyridinyl-phosphine ligands. Adv. Synth. Catal., 360(4), 676–681.
Wei, D., Bruneau-Voisine, A., Valyaev, D. A., Lugan, N., & Sortais, J. - B. (2018). Manganese catalyzed reductive amination of aldehydes using hydrogen as a reductant. Chem. Commun., 54(34), 4302–4305.
Wei, D., Carboni, B., Sortais, J. - B., & Darcel, C. (2018). Iron-catalyzed dehydrogenative borylation of terminal alkynes. Adv. Synth. Catal., 360(19), 3649–3654.
Wei, D., Sadek, O., Dorcet, V., Roisnel, T., Darcel, C., Gras, E., Clot, E., & Sortais, J. - B. (2018). Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study. J. Catal., 366, 300–309.


Benaissa, I., Taakili, R., Lugan, N., & Canac, Y. (2017). A convenient access to N-phosphonio-substituted NHC metal complexes [M = Ag(i), Rh(i), Pd(ii)]. Dalton Trans., 46(36), 12293–12305.
Canac, Y., & Lepetit, C. (2017). Classification of the electronic properties of chelating ligands in cis-[LL′Rh(CO)2] complexes. Inorg. Chem., 56(1), 667–675.
Cesar, V., Gade, L. H., & Bellemin-Laponnaz, S. (2017). NHC-Cobalt, -Rhodium, and -Iridium Complexes in Catalysis. In S. Diez-Gonzalez (Ed.), (2nd ed., pp. 302–335). N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools. RSC Publishing.
Cesar, V., Zhang, Y., Kosnik, W., Zielinski, A., Rajkiewicz, A. A., Ruamps, M., Bastin, S., Lugan, N., Lavigne, G., & Grela, K. (2017). Ruthenium catalysts supported by amino-substituted N-heterocyclic carbene ligands for olefin metathesis of challenging substrates. Chem. – Eur. J., 23(8), 1950–1955.
Darcel, C., & Sortais, J. - B. (2017). Homogeneous iron catalysis – Highlights on the increasing impact of a non-noble metal. Isr. J. Chem., 57(12).
Henrion, M., de P. Cardoso, B., Cesar, V., Chetcuti, M. J., & Ritleng, V. (2017). Nickel(II) complexes of highly σ-donating cyclic (alkyl)(amino)- and malonate-carbenes: Syntheses and catalytic studies. Organometallics, 36(6), 1113–1121.
Quintero-Duque, S., Li, H., Misal Castro, L. C., Dorcet, V., Roisnel, T., Clot, E., Grellier, M., Sortais, J. - B., & Darcel, C. (2017). N-heterocyclic carbene iron silyl hydride complexes. Isr. J. Chem., 57(12), 1216–1221.
Ruamps, M., Lavigne, G., & Cesar, V. (2017). Synthesis of N-Heterocyclic Carbene Complexes. In S. P. Nolan, & C. S. J. Cazin (Eds.), (Science of Synthesis Reference Library ed., pp. 47–53). N-Heterocyclic Carbenes in Catalytic Organic Synthesis, 1. Stuttgart: Georg Thieme Verlag KG.
Ruamps, M., Lugan, N., & Cesar, V. (2017). A cationic N-heterocyclic carbene containing an ammonium moiety. Organometallics, 36(5), 1049–1055.
Ruamps, M., Lugan, N., & Cesar, V. (2017). Experimental assessment of the π-acidity of anionic and neutral malonate-derived N-heterocyclic carbenes. Eur. J. Inorg. Chem., 2017(36), 4167–4173.
Valyaev, D. A., Willot, J., Mangin, L. P., Zargarian, D., & Lugan, N. (2017). Manganese-mediated synthesis of an NHC core non-symmetric pincer ligand and evaluation of its coordination properties. Dalton Trans., 46(31), 10193–10196.
Zhang, Y., Lavigne, G., Lugan, N., & Cesar, V. (2017). Buttressing effect as a key design principle towards highly efficient palladium/N-heterocyclic carbene Buchwald–Hartwig amination catalysts. Chem. – Eur. J., 23(55), 13792–13801.