Laboratoire de Chimie de Coordination UPR 8241

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Azouzi, K., Bruneau-Voisine, A., Vendier, L., Sortais, J. - B., & Bastin, S. (2020). Asymmetric transfer hydrogenation of ketones promoted by manganese(I) pre-catalysts supported by bidentate aminophosphines. Catal. Commun., 142, 106040.
Barthes, C., Duhayon, C., Canac, Y., & César, V. (2020). N-Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent. Chem. Commun., 56(22), 3305–3308.
Curbet, I., Colombel-Rouen, S., Manguin, R., Clermont, A., Quelhas, A., Müller, D. S., Roisnel, T., Baslé, O., Trolez, Y., & Mauduit, M. (2020). Expedient synthesis of conjugated triynes via alkyne metathesis. Chem. Sci., 11(19), 4934–4938.
Kireev, N. V., Filippov, O. A., Gulyaeva, E. S., Shubina, E. S., Vendier, L., Canac, Y., Sortais, J. - B., Lugan, N., & Valyaev, D. A. (2020). Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation. Chem. Commun., 56(14), 2139–2142.
Taakili, R., & Canac, Y. (2020). NHC core pincer ligands exhibiting two anionic coordinating extremities. Molecules, 25(9), 2231/1–19.
Taakili, R., Barthes, C., Goëffon, A., Lepetit, C., Duhayon, C., Valyaev, D. A., & Canac, Y. (2020). NHC core phosphonium ylide-based palladium(II) pincer complexes: The second ylide extremity makes the difference. Inorg. Chem., 59, 7082–7096.


Benaissa, I., Pallova, L., Morantin, M. - E., Lafitte, T., Huynh, M., Barthes, C., Vendier, L., Lugan, N., Bastin, S., & Cesar, V. (2019). N-heterocyclic carbenes as key intermediates in the synthesis of fused, mesoionic, tricyclic heterocycles. Chem. – Eur. J., 25(56), 13030–13036.
Bruneau-Voisine, A., Pallova, L., Bastin, S., Cesar, V., & Sortais, J. - B. (2019). Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chem. Commun., 55(3), 314–317.
Buhaibeh, R., Filippov, O. A., Bruneau-Voisine, A., Willot, J., Duhayon, C., Valyaev, D. A., Lugan, N., Canac, Y., & Sortais, J. - B. (2019). Phosphine-NHC manganese hydrogenation catalyst exhibiting a non-classical metal-ligand cooperative H2 activation mode. Angew. Chem., Int. Ed., 58(20), 6727–6731.
Cloutier, J. - P., Rechignat, L., Canac, Y., Ess, D. H., & Zargarian, D. (2019). C–O and C–N functionalization of cationic, NCN-type pincer complexes of trivalent nickel: Mechanism, selectivity, and kinetic isotope effect. Inorg. Chem., 58(6), 3861–3874.
Grineva, A. A., Filippov, O. A., Nefedov, S. E., Lugan, N., Cesar, V., & Valyaev, D. A. (2019). Direct access to IMesF and IMesF2 by electrophilic fluorination of abnormal n-heterocyclic carbenes. Organometallics, 38(11), 2330–2337.
Kulai, I., Karpus, A., Soroka, L., Valyaev, D. A., Bourdon, V., Manoury, E., Poli, R., Destarac, M., & Mazieres, S. (2019). Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment. Polym. Chem., 10(2), 267–277.
Lauberteaux, J., Pichon, D., Baslé, O., Mauduit, M., Marcia de Figueiredo, R., & Campagne, J. - M. (2019). Acyl-imidazoles: A privileged ester surrogate for enantioselective synthesis. ChemCatChem, 11(23), 5705–5722.
Manguin, R., Pichon, D., Tarrieu, R., Vives, T., Roisnel, T., Dorcet, V., Crévisy, C., Miqueu, K., Favereau, L., Crassous, J., Mauduit, M., & Baslé, O. (2019). A kinetic resolution strategy for the synthesis of chiral octahedral NHC–iridium(iii) catalysts. Chem. Commun., 55(43), 6058–6061.
Müller, D. S., Raoul, Y., Le Nôtre, J., Baslé, O., & Mauduit, M. (2019). In situ generation of Ru-based metathesis catalyst. A systematic study. Acs Catalysis, 9(4), 3511–3518.
Taakili, R., Duhayon, C., Lugan, N., & Canac, Y. (2019). Reactivity vs. stability of cyclopropenium substituted phosphonium salts. Eur. J. Inorg. Chem., (36), 3982–3989.
Taakili, R., Lepetit, C., Duhayon, C., Valyaev, D. A., Lugan, N., & Canac, Y. (2019). Palladium(ii) pincer complexes of a C,C,C-NHC, diphosphonium bis(ylide) ligand. Dalton Trans., 48, 1709–1721.
Tang, Y., Benaissa, I., Huynh, M., Vendier, L., Lugan, N., Bastin, S., Belmont, P., Cesar, V., & Michelet, V. (2019). An original L-shape, tunable N-heterocyclic carbene platform for efficient gold(I) catalysis. Angew. Chem., Int. Ed., 58(24), 7977–7981.
Thongpaen, J., Manguin, R., & Baslé, O. (2019). Chiral N-heterocyclic carbene ligands enable asymmetric C−H bond functionalization. Angew. Chem., Int. Ed., 59(26), 10242–10251.
Thongpaen, J., Manguin, R., Dorcet, V., Vives, T., Duhayon, C., Mauduit, M., & Baslé, O. (2019). Visible light induced rhodium(I)-catalyzed C−H borylation. Angew. Chem., Int. Ed., 58(43), 15244–15248.
Wei, D., Bruneau-Voisine, A., Dubois, M., Bastin, S., & Sortais, J. - B. (2019). Manganese-catalyzed transfer hydrogenation of aldimines. ChemCatChem, 11(21), 5256–5259.
Wei, D., Buhaibeh, R., Canac, Y., & Sortais, J. - B. (2019). Rhenium-catalyzed reduction of carboxylic acids with hydrosilanes. Org. Lett., 21(19), 7713–7716.
Wei, D., Dorcet, V., Darcel, C., & Sortais, J. - B. (2019). Synthesis of quinolines through acceptorless dehydrogenative coupling catalyzed by rhenium PN(H)P complexes. ChemSusChem, 12(13), 3078–3082.
Willot, J., Lugan, N., & Valyaev, D. A. (2019). Binuclear Cu(I) and Mn(0) complexes with a tridentate pyridine-NHC-phosphane ligand in a µ-κ2Ĉ,N-M;κ1P-M coordination mode. Eur. J. Inorg. Chem., (39-40), 4358–4364.


Azouzi, K., Duhayon, C., Benaissa, I., Lugan, N., Canac, Y., Bastin, S., & Cesar, V. (2018). Bidentate iminophosphorane-NHC ligand derived from the imidazo[1,5-a]pyridin-3-ylidene scaffold. Organometallics, 37(24), 4726–4735.
Barthes, C., Bijani, C., Lugan, N., & Canac, Y. (2018). A palladium(II) complex of a C4 chelating bis(NHC) diphosphonium bis(ylide) igand. Organometallics, 37(5), 673–678.
Canac, Y. (2018). Carbeniophosphines versus phosphoniocarbenes: The role of the positive charge. Chem. – Asian J., 13(15), 1872–1887.
Cesar, V., Mallardo, V., Nano, A., DePeter, S. F., Bastin, S., Sournia-Saquet, A., Maisse-François, A., Lugan, N., & Bellemin-Laponnaz, S. (2018). Homo- and heteropolymetallic complexes of the hybrid, ambidentate N-heterocyclic carbene Ligand IMes-acac. ACS Omega, 3(11), 15582–15591.
Grineva, A. A., Valyaev, D. A., Cesar, V., Filippov, O. A., Khrustalev, V. N., Nefedov, S. E., & Lugan, N. (2018). Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s. Angew. Chem., Int. Ed., 57(27), 7986–7991.
Lepetit, C., Vabre, B., Canac, Y., Alikhani, M. E., & Zargarian, D. (2018). Pentacoordinated, square pyramidal cationic PCP Ni(II) pincer complexes: ELF and QTAIM topological analyses of nickel–triflate interactions. Theor. Chem. Acc., 137(11), 141.