Laboratoire de Chimie de Coordination UPR 8241

Accueil

Vincent CESAR
CR
vincent.cesar chez lcc-toulouse.fr
0561333172
B223
Equipe A

Présentation


Vincent César was born in 1977 in Nancy, France. He was educated at the “Ecole Normale Supérieure de Lyon” (France), where he obtained an “Agrégation” in Physical Sciences (major in chemistry) in 2000. He completed his thesis in 2004 under the supervision of Prof. L. H. Gade and Dr. S. Bellemin-Laponnaz at the “Université Louis Pasteur” in Strasbourg working on chiral oxazolinyl/N-heterocyclic carbene ligands. He then joined Prof. A. Fürstner at the Max Planck Institut für Kohlenforschung in Mülheim/Ruhr (Germany) as an Alexander-von-Humboldt fellow. In 2006, he was appointed CNRS researcher at the “Laboratoire de Chimie de Coordination du CNRS” in Toulouse. His research interests are focused on the design and development of new N-Heterocyclic Carbenes for organometallic chemistry and catalysis.

ORCID : 0000-0002-6203-6434
ResearcherID : E-2877-2016
Publons : 1411259

Publications


2022

Pallova, L., Abella, L., Jean, M., Vanthuyne, N., Barthes, C., Vendier, L., Autschbach, J., Crassous, J., Bastin, S., & Cesar, V. (2022). Helical chiral N-heterocyclic carbene ligands in enantioselective gold catalysis. Chem. – Eur. J., 28(17), e202200166/1–5.
doi

2021

Benaissa, I., Gajda, K., Vendier, L., Lugan, N., Kajetanowicz, A., Grela, K., Michelet, V., Cesar, V., & Bastin, S. (2021). An anionic, chelating C(sp3)/NHC ligand from the combination of an N-heterobicyclic carbene and barbituric heterocycle. Organometallics, 40(18), 3223–3234.
doi
Brousses, R., Maurel, V., Mouesca, J. - M., Cesar, V., Lugan, N., & Valyaev, D. A. (2021). Half-sandwich manganese complexes Cp(CO)2Mn(NHC) as redox-active organometallic fragments. Dalton Trans., 50(40), 14264–14272.
doi
Cesar, V., Fliedel, C., & Labande, A. (2021). Chiral N-Heterocyclic Carbene-Based Ligands. In M. Diéguez (Ed.), (pp. 195–232). Chiral Ligands : Evolution of Ligand Libraries for Asymmetric Catalysis. Boca Raton: CRC Press.
doi
Grineva, A. A., Filippov, O. A., Canac, Y., Sortais, J. - B., Nefedov, S. E., Lugan, N., Cesar, V., & Valyaev, D. A. (2021). Experimental and theoretical insights into the electronic properties of anionic n-heterocyclic dicarbenes through the rational synthesis of their transition metal complexes. Inorg. Chem., 60(6), 4015–4025.
doi
Pallova, L., Gauthier, E., Abella, L., Jean, M., Vanthuyne, N., Dorcet, V., Vendier, L., Autschbach, J., Crassous, J., Bastin, S., & Cesar, V. (2021). Synthesis and properties of partially saturated fluorenyl-derived [n]helicenes featuring an overcrowded alkene. Chem. – Eur. J., 27(28), 7722–7730.
doi

2020

Barthes, C., Duhayon, C., Canac, Y., & Cesar, V. (2020). N-cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent. Chem. Commun., 56(22), 3305–3308.
doi
Bonfiglio, A., Pallova, L., Cesar, V., Gourlaouen, C., Bellemin-Laponnaz, S., Daniel, C., Polo, F., & Mauro, M. (2020). Phosphorescent cationic heterodinuclear IrIII/MI complexes (M=CuI, AuI) with a hybrid Janus-type N-Heterocyclic carbene bridge. Chem. – Eur. J., 26(51), 11751–11766.
doi

2019

Benaissa, I., Pallova, L., Morantin, M. - E., Lafitte, T., Huynh, M., Barthes, C., Vendier, L., Lugan, N., Bastin, S., & Cesar, V. (2019). N-heterocyclic carbenes as key intermediates in the synthesis of fused, mesoionic, tricyclic heterocycles. Chem. – Eur. J., 25(56), 13030–13036.
doi
Bruneau-Voisine, A., Pallova, L., Bastin, S., Cesar, V., & Sortais, J. - B. (2019). Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chem. Commun., 55(3), 314–317.
doi