Laboratoire de Chimie de Coordination UPR 8241

Accueil

Vincent CESAR
CR
vincent.cesar chez lcc-toulouse.fr
0561333172
B223
Equipe A

Présentation


Vincent César was born in 1977 in Nancy, France. He was educated at the “Ecole Normale Supérieure de Lyon” (France), where he obtained an “Agrégation” in Physical Sciences (major in chemistry) in 2000. He completed his thesis in 2004 under the supervision of Prof. L. H. Gade and Dr. S. Bellemin-Laponnaz at the “Université Louis Pasteur” in Strasbourg working on chiral oxazolinyl/N-heterocyclic carbene ligands. He then joined Prof. A. Fürstner at the Max Planck Institut für Kohlenforschung in Mülheim/Ruhr (Germany) as an Alexander-von-Humboldt fellow. In 2006, he was appointed CNRS researcher at the “Laboratoire de Chimie de Coordination du CNRS” in Toulouse. His research interests are focused on the design and development of new N-Heterocyclic Carbenes for organometallic chemistry and catalysis.

ORCID : 0000-0002-6203-6434
ResearcherID : E-2877-2016
Publons : 1411259

Publications


2020

Barthes, C., Duhayon, C., Canac, Y., & Cesar, V. (2020). N-cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent. Chem. Commun., 56(22), 3305–3308.
doi
Bonfiglio, A., Pallova, L., Cesar, V., Gourlaouen, C., Bellemin-Laponnaz, S., Daniel, C., Polo, F., & Mauro, M. (2020). Phosphorescent cationic heterodinuclear IrIII/MI complexes (M=CuI, AuI) with a hybrid Janus-type N-Heterocyclic carbene bridge. Chem. – Eur. J., 26(51), 11751–11766.
doi

2019

Benaissa, I., Pallova, L., Morantin, M. - E., Lafitte, T., Huynh, M., Barthes, C., Vendier, L., Lugan, N., Bastin, S., & Cesar, V. (2019). N-heterocyclic carbenes as key intermediates in the synthesis of fused, mesoionic, tricyclic heterocycles. Chem. – Eur. J., 25(56), 13030–13036.
doi
Bruneau-Voisine, A., Pallova, L., Bastin, S., Cesar, V., & Sortais, J. - B. (2019). Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chem. Commun., 55(3), 314–317.
doi
Grineva, A. A., Filippov, O. A., Nefedov, S. E., Lugan, N., Cesar, V., & Valyaev, D. A. (2019). Direct access to IMesF and IMesF2 by electrophilic fluorination of abnormal n-heterocyclic carbenes. Organometallics, 38(11), 2330–2337.
doi
Tang, Y., Benaissa, I., Huynh, M., Vendier, L., Lugan, N., Bastin, S., Belmont, P., Cesar, V., & Michelet, V. (2019). An original L-shape, tunable N-heterocyclic carbene platform for efficient gold(I) catalysis. Angew. Chem., Int. Ed., 58(24), 7977–7981.
doi

2018

Azouzi, K., Duhayon, C., Benaissa, I., Lugan, N., Canac, Y., Bastin, S., & Cesar, V. (2018). Bidentate iminophosphorane-NHC ligand derived from the imidazo[1,5-a]pyridin-3-ylidene scaffold. Organometallics, 37(24), 4726–4735.
doi
Cesar, V., Mallardo, V., Nano, A., DePeter, S. F., Bastin, S., Sournia-Saquet, A., Maisse-François, A., Lugan, N., & Bellemin-Laponnaz, S. (2018). Homo- and heteropolymetallic complexes of the hybrid, ambidentate N-heterocyclic carbene Ligand IMes-acac. ACS Omega, 3(11), 15582–15591.
doi
Grineva, A. A., Valyaev, D. A., Cesar, V., Filippov, O. A., Khrustalev, V. N., Nefedov, S. E., & Lugan, N. (2018). Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s. Angew. Chem., Int. Ed., 57(27), 7986–7991.
doi
Ruamps, M., Bastin, S., Rechignat, L., Sournia-Saquet, A., Valyaev, D. A., Mouesca, J. - M., Lugan, N., Maurel, V., & Cesar, V. (2018). Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes. Chem. Commun., 54(55), 7653–7656.
doi