LCC
Activité du service
Le Service utilise le centre de microcaractérisation Raimond Castaing (UAR 3623) localisé sur le site de Montaudran qui rassemble et mutualise des compétences techniques et scientifiques complémentaires actuellement dispersées sur le site toulousain.
- La microscopie électronique permet la caractérisation de nano-objets, couches minces… jusqu’à l’échelle nanométrique : microstructure, structures cristallines, composition chimique.
- Domaines d’application au LCC : nanoparticules, nanotubes de carbone, peptides, dendrimères, parasites hématophages, liquides ioniques, complexes métalliques, matériaux métalliques, dépôts sur substrat, céramiques, composites, hybrides organiques-inorganiques.
Membres du service

COLLIERE Vincent
Équipements

Le centre Castaing regroupe en autre, 7 équipements de microscopie électronique ainsi que du matériel de préparation accessible au LCC :
- 2 microscopes électroniques à balayage à émission de champ
Jéol JSM 6700F et Jéol 7800F - 5 microscopes électroniques en transmission
Jéol JEM 1011 (100kV), Jéol JEM 1400 (120kV), Jéol JEM 1400 Flash (120kV), Jéol JEM 2100F (200kV, EDX,STEM), Jéol JEM ARM200F (200kV, EDX,STEM HAADF, EELS).
Prestations
En tant que responsable du service de microscopie du LCC, j’assure, pour le personnel du LCC, l’organisation de tous les travaux effectués au centre de microcaratérisation Raimond Castaing (microscopie électronique à balayage et en transmission).
J’effectue tous les travaux spécifiques nécessitants haute résolution, diffraction électronique, analyse X, cartographie.
Publications
Consulter les publications
Various sizes and shapes of mixed-anion Fe(NH2trz)3(BF4)2−x(SiF6)x/2@SiO2 nanohybrid particles undergoing spin crossover just above room temperature
Yang X., Bielas R., Collière V., Salmon L., Bousseksou A.
Nanomaterials 2025, 15(2), 90/1-11.
10.3390/nano15020090 – hal-05063697
Competition between ordered morphologies of functionalized silver nanoparticles elucidated by a joint experimental and multiscale theoretical study
Loffreda D., Tarrat N., Lacaze-Dufaure C., Rabilloud F., Fajerwerg K., Kahn M., Collière V., Lepetit C., Fau P.
Nano Today 2025, 62, 102662/1-12.
10.1016/j.nantod.2025.102662 – hal-04967280
Spontaneous emulsification of organometallic complexes applied to the synthesis of nanocapsules active for H2 release from ammonia-borane
Gazil O., Rault L., Iglicki D., Collière V., Karacaoglan G., Poinsot D., Bouzid M., Hierso J.-C., Kahn M. L., Virgilio N., Gauffre F.
Langmuir 2024, 40(32), 16824-16832.
10.1021/acs.langmuir.4c01307 – hal-04762632
Synthesis of TiO2/SBA-15 nanocomposites by hydrolysis of organometallic Ti precursors for photocatalytic NO abatement
El Atti O., Hot J., Fajerwerg K., Lorber C., Lebeau B., Ryzhikov A., Kahn M., Collière V., Coppel Y., Ratel-Ramond N., Ménini P., Fau P.
Inorganics 2024, 12(7), 183/1-19.
10.3390/inorganics12070183 – hal-04659095
Colloidal ruthenium catalysts for selective quinaldine hydrogenation: Ligand and solvent effects
Colliere V., Verelst M., Lecante P., Axet M. R.
Chem. – Eur. J. 2024, 30(13), e202302131/1-9.
10.1002/chem.202302131 – hal-04428489
Understanding ion-exchange processes in the synthesis of ZnSx@ZnO1–x heterostructures from controlled sulfidation of ZnO nanocrystals
Bellan E., Jakoobi M., Collière V., Coppel Y., Trébosc J., Lafon O., Lecante P., Fleurat-Lessard P., Dupont C., Hierso J.-C., Fau P., Fajerwerg K., Pautrot-d’Alençon L., Le Mercier T., Kahn M. L.
Chem. Mater. 2024, 36(24), 11781-11794.
10.1021/acs.chemmater.4c01892 – hal-04964187
Ru-based nanoparticles supported on carbon nanotubes for electrocatalytic hydrogen evolution: structural and electronic effects
Romero N., Fenoll D. A., Gil L., Campos S., Creus J., Martí G., Heras-Domingo J., Collière V., Mesa C. A., Giménez S., Francàs L., Rodríguez-Santiago L., Solans-Monfort X., Sodupe M., Bofill R., Philippot K., García-Antón J., Sala X.
Inorg. Chem. Front. 2023, 10(20), 5885-5896.
10.1039/D3QI00698K – hal-04174775
Gas sensing properties of CuWO4@WO3 n-n heterojunction prepared by direct hydrolysis of mesitylcopper (I) on WO3•2H2O nanoleaves
Jońca J., Castello-Lux K., Fajerwerg K., Kahn M. L., Collière V., Menini P., Sówka I., Fau P.
Chemosensors 2023, 11(9), 495/1-21.
10.3390/chemosensors11090495 – hal-04271459
Functionalization of graphene oxide surfaces with phosphorus dendrimer and dendron
Alami O., Laurent R., Tassé M., Coppel Y., Collière V., Bignon J., Majoral J.-P., El Kazzouli S., El Brahmi N., Caminade A.-M.
FlatChem 2023, 42, 100564/1-12.
10.1016/j.flatc.2023.100564 – hal-04268533
Synthesis and study of the physicochemical properties of a hybrid species: Iron phthalocyanine–silver nanoparticles
Tarpaga L., Sessouma B., Ouédraogo S., Colliere V., Bayo-Bangoura M., Amiens C., Bayo K.
Chem. Afr. 2022, 5(4), 811-820.
10.1007/s42250-022-00400-w – hal-03822516
High recyclability magnetic iron oxide-supported ruthenium nanocatalyst for H2 release from ammonia-borane solvolysis
Poinsot D., Bouzid M., Burlot A., Mboyi C. D., Doulain P.-E., Paris J., Heintz O., Domenichini B., Collière V., Kahn M. L., Hierso J.-C.
ChemNanoMat 2022, 8(9), e202200285/1-8.
10.1002/cnma.202200285 – hal-03728542
Synthesis of NiFeOx nanocatalysts from metal–organic precursors for the oxygen evolution reaction
Nguyen Q. T., Robert F., Colliere V., Lecante P., Philippot K., Esvan J., Tran P. D., Amiens C.
Dalton Trans. 2022, 51(30), 11457-11466.
10.1039/D2DT01370C – hal-03755510
Grafting copper atoms and nanoparticles on double-walled carbon nanotubes: Application to catalytic synthesis of propargylamine
Mesguich D., Moumaneix L., Henri V., Legnani M., Collière V., Esvan J., Ouali A., Fau P.
Langmuir 2022, 38(28), 8545–8554.
10.1021/acs.langmuir.2c00771 – hal-03727534
Nano-structuration of WO3 nanoleaves by localized hydrolysis of an organometallic Zn precursor: Application to photocatalytic NO2 abatement
Castello Lux K., Fajerwerg K., Hot J., Ringot E., Bertron A., Collière V., Kahn M. L., Loridant S., Coppel Y., Fau P.
Nanomaterials 2022, 12(24), 4360/1-20.
10.3390/nano12244360 – hal-03965121
In situ ruthenium catalyst modification for the conversion of furfural to 1,2-pentanediol
Bruna L., Cardona-Farreny M., Colliere V., Philippot K., Axet M. R.
Nanomaterials 2022, 12(3), 328/1-11.
10.3390/nano12030328 – hal-03562651
Covalent grafting of ruthenium complexes on iron oxide nanoparticles: Hybrid materials for photocatalytic water oxidation
Nguyen Q. T., Rousset E., Nguyen V. T. H., Colliere V., Lecante P., Klysubun W., Philippot K., Esvan J., Respaud M., Lemercier G., Tran P. D., Amiens C.
ACS Appl. Mater. Interfaces 2021, 13(45), 53829-53840.
10.1021/acsami.1c15051 – hal-03436779
Origin of the synergistic effect between TiO2 crystalline phases in the Ni/TiO2-catalyzed CO2 methanation reaction
Messou D., Bernardin V., Meunier F., Borges Ordoño M., Urakawa A., Machado B. F., Collière V., Philippe R., Serp P., Le Berre C.
Catal. 2021, 398, 14-28.
10.1016/j.jcat.2021.04.004 – hal-03216533
Oxidation of methane to methanol over Pd@Pt nanoparticles under mild conditions in water
Chen J., Wang S., Peres L., Collière V., Philippot K., Lecante P., Chen Y., Yan N.
Catal. Sci. Technol. 2021, 11(10), 3493-3500.
10.1039/D1CY00273B – hal-03234648
Catalysis to discriminate single atoms from subnanometric ruthenium particles in ultra-high loading catalysts
Rivera-Cárcamo C., Leng F., Gerber I. C., Del Rosal I., Poteau R., Collière V., Lecante P., Nechiyil D., Bacsa W., Corrias A., Axet M. R., Serp P.
Catal. Sci. Technol. 2020, 10(14), 4673-4683.
.1039/D0CY00540A – hal-02904642
Straightforward synthesis of gold nanoparticles by adding water to an engineered small dendrimer
Gottis S., Laurent R., Collière V., Caminade A.-M.
Beilstein J. Nanotechnol. 2020, 11, 1110-1118.
10.3762/bjnano.11.95 – hal-02908515
Reorganization of a photosensitive carbo-benzene layer in a triptych nanocatalyst with enhancement of the photocatalytic hydrogen production from water
Assi H., Cocq K., Cure J., Casterou G., Castello Lux K., Collière V., Vendier L., Fau P., Maraval V., Fajerwerg K., Chabal Y. J., Chauvin R., Kahn M. L.
Int. J. Hydrogen Energy 2020, 45(46), 24765-24778.
10.1016/j.ijhydene.2020.06.255 – hal-02947701
Controlled growth of Ag nanocrystals in a H-bonded open framework
Khodja W., Collière V., Kahn M. L., Roques N., Sutter J.-P.
Chem. – Eur. J. 2019, 25(60), 13705-13708.
10.1002/chem.201903684 – hal-02338823
π-Stacking interactions of graphene-coated cobalt magnetic nanoparticles with pyrene-tagged dendritic poly(vinylidene fluoride)
Folgado E., Guerre M., Mimouni N., Collière V., Bijani C., Moineau-Chane Ching K. I., Caminade A.-M., Ladmiral V., Améduri B., Ouali A.
ChemPlusChem 2019, 84(1), 78-84.
10.1002/cplu.201800471 – hal-01996630
Urea-assisted cooperative assembly of phosphorus dendrimer–zinc oxide hybrid nanostructures
El Hankari S., Katir N., Collière V., Coppel Y., Bousmina M., Majoral J.-P., El Kadib A.
New J. Chem. 2019, 43(5), 2141-2147.
10.1039/C8NJ05705B – hal-02332801
LCC CNRS
Laboratoire de chimie de coordination du CNRS
205 route de Narbonne, BP 44099
31077 Toulouse cedex 4
France