The dichotomy of Mn–H bond cleavage and kinetic hydricity of tricarbonyl manganese hydride complexes
Osipova E. S., Kovalenko S. A., Gulyaeva E. S., Kireev N. V., Pavlov A. A., Filippov O. A., Danshina A. A., Valyaev D. A., Canac Y., Shubina E. S., Belkova N. V.
Molecules 2023, 28(8), 3368/1-14.
https://doi.com/10.3390/molecules28083368
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Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C–H silylation
Manguin R., Galiana-Cameo M., Kittikool T., Barthes C., Thongpaen J., Bancal E., Mallet-Ladeira S., Yotphan S., Castarlenas R., Mauduit M., Sortais J.-B., Baslé O.
Chemical Communications 2023, 59(28), 4193-4196.
http://dx.doi.org/10.1039/D2CC06865F
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Phosphonium ylides vs iminophosphoranes: The role of the coordinating ylidic atom in cis-[phosphine-ylide Rh(CO)₂] complexes
Popovici I., Barthes C., Tannoux T., Duhayon C., Casaretto N., Monari A., Auffrant A., Canac Y.
Inorganic Chemistry 2023, 62(5), 2376-2388.
https://doi.org/10.1021/acs.inorgchem.2c04151
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Ruthenium–NHC complex-catalyzed P(iii)-directed C–H borylation of arylphosphines
Thongpaen J., Manguin R., Kittikool T., Camy A., Roisnel T., Dorcet V., Yotphan S., Canac Y., Mauduit M., Baslé O.
Chemical Communications 2022, 58, 12082-12085.
http://dx.doi.org/10.1039/D2CC03909E
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Fused polycyclic NHC ligands in gold catalysis: Recent advances
Teixeira P., Bastin S., César V.
Israel Journal of Chemistry 2022, e202200051.
https://doi.org/10.1002/ijch.202200051
https://hal.archives-ouvertes.fr/hal-03826206

Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-heterocyclic carbene bearing two N-cationic substituents
Padunnappattu A., Duhayon C., César V., Canac Y.
Organometallics 2022, 41(20), 2868–2878.
https://doi.org/10.1021/acs.organomet.2c00429
https://hal.archives-ouvertes.fr/hal-03818692

Chiral oxazolidines acting as transient hydroxyalkyl-functionalized N-heterocyclic carbenes: An efficient route to air stable copper and gold complexes for asymmetric catalysis
Pichon-Barré D., Zhang Z., Cador A., Vives T., Roisnel T., Baslé O., Jarrige L., Cavallo L., Falivene L., Mauduit M.
Chemical Science 2022, 13(30), 8773-8780.
http://dx.doi.org/10.1039/D2SC02908A
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Highly emissive red heterobimetallic Ir^III/M^I (M^I = Cu^I and Au^I) complexes for efficient light-emitting electrochemical cells
Bonfiglio A., Hsiao P.-W., Chen Y., Gourlaouen C., Marchand Q., César V., Bellemin-Laponnaz S., Wang Y.-X., Lu C.-W., Daniel C., Polo F., Su H.-C., Mauro M.
Chemistry of Materials 2022, 34(4), 1756-1769.
https://doi.org/10.1021/acs.chemmater.1c03972
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Redox-switchable behavior of transition-metal complexes supported by amino-decorated N-heterocyclic carbenes
Ruamps M., Bastin S., Rechignat L., Sournia-Saquet A., Vendier L., Lugan N., Mouesca J.-M., Valyaev D. A., Maurel V., César V.
Molecules 2022, 27(12), 3776/1-17.
https://www.mdpi.com/1420-3049/27/12/3776
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Helical chiral N-heterocyclic carbene ligands in enantioselective gold catalysis
Pallova L., Abella L., Jean M., Vanthuyne N., Barthes C., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2022, 28(17), e202200166/1-5.
https://doi.org/10.1002/chem.202200166
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Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(dppm)Mn(CO)₃H]
Osipova E. S., Gulyaeva E. S., Kireev N. V., Kovalenko S. A., Bijani C., Canac Y., Valyaev D. A., Filippov O. A., Belkova N. V., Shubina E. S.
Chemical Communications 2022, 58(32), 5017-5020.
http://dx.doi.org/10.1039/D2CC00999D
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Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Gulyaeva E. S., Osipova E. S., Buhaibeh R., Canac Y., Sortais J.-B., Valyaev D. A.
Coordination Chemistry Reviews 2022, 458, 214421/1-36.
https://doi.org/10.1016/j.ccr.2022.214421
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Diverse C-coordination modes of NHC-tricyclohexylphosphonium ylide ligands in palladium(II) complexes
El Kadiri M., Chihab A., Taakili R., Duhayon C., Valyaev D. A., Canac Y.
Organometallics 2022, 41(4), 456-466.
https://doi.org/10.1021/acs.organomet.1c00700
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Hydrosilylation reactions catalyzed by rhenium
Wei D., Buhaibeh R., Canac Y., Sortais J.-B.
Molecules 2021, 26(9), 2598/1-15.
https://doi.org/10.3390/molecules26092598
https://hal.archives-ouvertes.fr/hal-03230574

Carbenes and phosphonium ylides: A fruitful association in coordination chemistry
Valyaev D. A., Canac Y.
Dalton Transactions 2021, 50(45), 16434-16442.
http://dx.doi.org/10.1039/D1DT03155D
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Editorial overview: Smart use of metal reagents unlocks greener organic synthesis
Valyaev D. A.
Current Opinion in Green and Sustainable Chemistry 2021, 32, 100551/1-3.
https://doi.org/10.1016/j.cogsc.2021.100551
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Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window
Tarrieu R., Delgado I. H., Zinna F., Dorcet V., Colombel-Rouen S., Crévisy C., Baslé O., Bosson J., Lacour J.
Chemical Communications 2021, 57(31), 3793-3796.
https://doi.org/10.1039/d1cc00898f
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Direct access to palladium(II) complexes based on anionic C,C,C-phosphonium ylide core pincer ligand
Taakili R., Barthes C., Lepetit C., Duhayon C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2021, 60(16), 12116-12128.
https://doi.org/10.1021/acs.inorgchem.1c01316
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Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions
Sortais J.-B., Buhaibeh R., Canac Y.
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Manganese Catalysis in Organic Synthesis
Sortais J.-B. (Ed.)
Wiley‐VCH: Weinheim, 2021. (978-3-527-34730-8).
https://doi.org/10.1002/9783527826131
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Synthesis and properties of partially saturated fluorenyl-derived [n]helicenes featuring an overcrowded alkene
Pallova L., Gauthier E., Abella L., Jean M., Vanthuyne N., Dorcet V., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2021, 27(28), 7722-7730.
https://doi.org/10.1002/chem.202100150
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Organometallic Manganese Compounds in Organic Synthesis
Grineva A. A., Lugan N., Valyaev D. A.
in Manganese Catalysis in Organic Synthesis, Sortais J.-B. (Ed.). Wiley-VCH: Weinheim, 2021, pp. 1-37. (978-3-527-34730-8).
https://doi.org/10.1002/9783527826131.ch1
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Experimental and theoretical insights into the electronic properties of anionic n-heterocyclic dicarbenes through the rational synthesis of their transition metal complexes
Grineva A. A., Filippov O. A., Canac Y., Sortais J.-B., Nefedov S. E., Lugan N., César V., Valyaev D. A.
Inorganic Chemistry 2021, 60(6), 4015-4025.
https://doi.org/10.1021/acs.inorgchem.1c00073
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Chiral N-Heterocyclic Carbene-Based Ligands
César V., Fliedel C., Labande A.
in New Directions in Organic & Biological Chemistry Series. Chiral Ligands : Evolution of Ligand Libraries for Asymmetric Catalysis, Diéguez M. (Ed.). CRC Press: Boca Raton, 2021, pp. 195-232. (978-0-367-4-28488).
https://doi.org/10.1201/9780367855734-6
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Carbon ligands: From fundamental aspects to applications
Canac Y.
Molecules 2021, 26(8), 2132/1-3.
https://doi.org/10.3390/molecules26082132
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Cationic PCP and PCN NHC core pincer-type Mn(I) complexes: From synthesis to catalysis
Buhaibeh R., Duhayon C., Valyaev D. A., Sortais J.-B., Canac Y.
Organometallics 2021, 40(2), 231-241.
https://doi.org/10.1021/acs.organomet.0c00717
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Half-sandwich manganese complexes Cp(CO)₂Mn(NHC) as redox-active organometallic fragments
Brousses R., Maurel V., Mouesca J.-M., César V., Lugan N., Valyaev D. A.
Dalton Transactions 2021, 50(40), 14264-14272.
http://dx.doi.org/10.1039/D1DT02182F
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An anionic, chelating C(sp³)/NHC ligand from the combination of an N-heterobicyclic carbene and barbituric heterocycle
Benaissa I., Gajda K., Vendier L., Lugan N., Kajetanowicz A., Grela K., Michelet V., César V., Bastin S.
Organometallics 2021, 40(18), 3223-3234.
https://doi.org/10.1021/acs.organomet.1c00458
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Visible-light-induced ruthenium-catalyzed alkylation of activated C(sp³)−H bonds
Baslé O.
Chem Catalysis 2021, 1(2), 256-257.
https://doi.org/10.1016/j.checat.2021.05.015
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Visible-light-induced 3d transition metal-catalysis: A focus on C–H bond functionalization
Baslé O.
Current Opinion in Green and Sustainable Chemistry 2021, 32, 100539/1-6.
https://doi.org/10.1016/j.cogsc.2021.100539
https://hal.archives-ouvertes.fr/hal-03421356

Manganese—New prominent actor in transfer hydrogenation catalysis
Azouzi K., Valyaev D. A., Bastin S., Sortais J.-B.
Current Opinion in Green and Sustainable Chemistry 2021, 31, 100511/1-7.
https://doi.org/10.1016/j.cogsc.2021.100511
https://hal.archives-ouvertes.fr/hal-03230650