Sélectionner une page
Dmitry VALYAEV

LCC

Dmitry VALYAEV

Chargé de Recherche CNRS
Équipe A

dmitry.valyaev@lcc-toulouse.fr

+33 (0)5 61 33 31 71

Numéro ORCID : 0000-0002-1772-844X

Dmitry Valyaev a obtenu son doctorat en 2007 à l’INEOS de Moscou sous la direction des Pr N. Ustynyuk et Dr O. Semeikin. Après 3 ans passées en tant que Chercheur à l’INEOS, il a effectué trois stages postdoctorales consécutives au LCC (2009-2010 et 2012-2013) sous la direction du Dr N. Lugan et à l’iSm2 (2011-2012) sous la direction des Dr O. Chuzel et Dr J.-L. Parrain et ensuite obtenu une poste de chercheur CNRS au LCC. Ses activités de recherche sont principalement centrées sur l’application de chimie organométallique du manganèse pour la synthèse organique et en catalyse homogène. 

 

Domaines d’expertise – projets en cours

Chimie organométallique de synthèse avec une forte expertise en manganèse, Chimie du phosphore, Conception de ligands NHCs, Catalyse homogène.

Synthèse métallo-induite de carbènes N-hétérocycliques

Généralement, les ligands en chimie organométallique doivent être préalablement synthétisés avant la coordination au centre métallique. Nous développons la stratégie alternative visant l’élaboration de motifs phosphine-NHC et NHCs fonctionnalisés sur la squelette arrière en exploitant la réactivité originale de complexes du manganèse dérivés de CpMn(CO)3 produit à l’échelle industrielle. Après l’enlèvement d’un fragment manganèse, les NHCs cibles ont utilisés en chimie de coordination, catalyse homogène et en tant que briques moléculaires pour la science de matériaux.

Production scientifique



48 documents

Articles dans une revue

  • Mirko Ruamps, Stéphanie Bastin, Lionel Rechignat, Alix Sournia-Saquet, Laure Vendier, et al.. Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes. Molecules, MDPI, 2022, 27 (12), pp.3776. ⟨10.3390/molecules27123776⟩. ⟨hal-03709012⟩
  • Ekaterina S Gulyaeva, Elena S Osipova, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais, et al.. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes. Coordination Chemistry Reviews, Elsevier, 2022, 458, pp.214421. ⟨10.1016/j.ccr.2022.214421⟩. ⟨hal-03566299⟩
  • Elena Osipova, Ekaterina Gulyaeva, Nikolay Kireev, Sergey Kovalenko, Christian Bijani, et al.. Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]. Chemical Communications, Royal Society of Chemistry, 2022, 58 (32), pp.5017-5020. ⟨10.1039/d2cc00999d⟩. ⟨hal-03652224⟩
  • Mustapha El Kadiri, Abdelali Chihab, Rachid Taakili, Carine Duhayon, Dmitry A. Valyaev, et al.. Diverse C -Coordination Modes of NHC-Tricyclohexylphosphonium Ylide Ligands in Palladium(II) Complexes. Organometallics, American Chemical Society, 2022, 41 (4), pp.456-466. ⟨10.1021/acs.organomet.1c00700⟩. ⟨hal-03579686⟩
  • Dmitry A. Valyaev. Editorial overview: Smart use of metal reagents unlocks greener organic synthesis. Current opinion in green and sustainable chemistry, Elsevier, 2021, 32, pp.100551. ⟨10.1016/j.cogsc.2021.100551⟩. ⟨hal-03361826⟩
  • Rémy Brousses, Vincent Maurel, Jean-Marie Mouesca, Vincent César, Noël Lugan, et al.. Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments. Dalton Transactions, Royal Society of Chemistry, 2021, 50 (40), pp.14264-14272. ⟨10.1039/D1DT02182F⟩. ⟨hal-03403199⟩
  • Rachid Taakili, Cécile Barthes, Christine Lepetit, Carine Duhayon, Dmitry A. Valyaev, et al.. Direct Access to Palladium(II) Complexes Based on Anionic C , C , C -Phosphonium Ylide Core Pincer Ligand. Inorganic Chemistry, American Chemical Society, 2021, 60 (16), pp.12116-12128. ⟨10.1021/acs.inorgchem.1c01316⟩. ⟨hal-03357270⟩
  • Karim Azouzi, Dmitry A. Valyaev, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese – new prominent actor in transfer hydrogenation catalysis. Current opinion in green and sustainable chemistry, Elsevier, 2021, 31, pp.100511. ⟨10.1016/j.cogsc.2021.100511⟩. ⟨hal-03230650⟩
  • Alina A Grineva, Oleg A Filippov, Yves Canac, Jean-Baptiste Sortais, Sergei E Nefedov, et al.. Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes. Inorganic Chemistry, American Chemical Society, 2021, 60 (6), pp.4015-4025. ⟨10.1021/acs.inorgchem.1c00073⟩. ⟨hal-03200528⟩
  • Ruqaya Buhaibeh, Carine Guyard-Duhayon, Dmitry A. Valyaev, Jean-Baptiste Sortais, Yves Canac. Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis. Organometallics, American Chemical Society, 2021, 40 (2), pp.231−241. ⟨hal-03128901⟩
  • Dmitry A. Valyaev, Yves Canac. Carbenes and phosphonium ylides: a fruitful association in coordination chemistry. Dalton Transactions, Royal Society of Chemistry, 2021, 50 (45), pp.16434-16442. ⟨10.1039/D1DT03155D⟩. ⟨hal-03404061⟩
  • Rachid Taakili, Cécile Barthes, Amel Goëffon, Christine Lepetit, Carine Guyard-Duhayon, et al.. NHC Core Phosphonium Ylide-based Palladium(II) Pincer Complexes: The Second Ylide Extremity Makes the Difference. Inorganic Chemistry, American Chemical Society, 2020, 59 (10), pp.7082-7096. ⟨10.1021/acs.inorgchem.0c00561⟩. ⟨hal-02612432⟩
  • Nikolay Kireev, Oleg Filippov, Ekaterina Gulyaeva, Elena V Shubina, Laure Vendier, et al.. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation. Chemical Communications, Royal Society of Chemistry, 2020, 56 (14), pp.2139-2142. ⟨10.1039/c9cc07713h⟩. ⟨hal-02489712⟩
  • Jérémy Willot, Noël Lugan, Dmitry A. Valyaev. Binuclear Cu(I) and Mn(0) Complexes with a Tridentate Pyridine-NHC-Phosphane Ligand in a µ-κ 2 Ĉ,N -M;κ 1 P -M Coordination Mode. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2019, 2019 (39-40), pp.4358-4364. ⟨10.1002/ejic.201900628⟩. ⟨hal-02361486⟩
  • Alina A Grineva, Oleg Filippov, Sergei Nefedov, Noël Lugan, Vincent César, et al.. Direct Access to IMes F and IMes F 2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes. Organometallics, American Chemical Society, 2019, 38 (11), pp.2330-2337. ⟨10.1021/acs.organomet.9b00151⟩. ⟨hal-02333068⟩
  • Rachid Taakili, Christine Lepetit, Carine Guyard-Duhayon, Dmitry A. Valyaev, Noël Lugan, et al.. Palladium( ii ) pincer complexes of a C , C , C -NHC, diphosphonium bis(ylide) ligand. Dalton Transactions, Royal Society of Chemistry, 2019, 48 (5), pp.1709-1721. ⟨10.1039/c8dt04316g⟩. ⟨hal-02140710⟩
  • Ruqaya Buhaibeh, Oleg A Filippov, Antoine Bruneau-Voisine, Jérémy Willot, Carine Guyard-Duhayon, et al.. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H Activation Mode. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2019, 58 (20), pp.6727-6731. ⟨10.1002/anie.201901169⟩. ⟨hal-02120809⟩
  • Ihor Kulai, Andrii Karpus, Liubov Soroka, Dmitry A. Valyaev, Valérie Bourdon, et al.. Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment. Polymer Chemistry, Royal Society of Chemistry - RSC, 2019, 10 (2), pp.267-277. ⟨10.1039/c8py01279b⟩. ⟨hal-02134244⟩
  • Duo Wei, Antoine Bruneau-Voisine, Dmitry A. Valyaev, Noël Lugan, Jean-Baptiste Sortais. Manganese catalyzed reductive amination of aldehydes using hydrogen as a reductant. Chemical Communications, Royal Society of Chemistry, 2018, 54 (34), pp.4302-4305. ⟨10.1039/C8CC01787E⟩. ⟨hal-01807069⟩
  • Duo Wei, Antoine Bruneau-Voisine, Teo Chauvin, Vincent Dorcet, Thierry Roisnel, et al.. Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (4), pp.676-681. ⟨10.1002/adsc.201701115⟩. ⟨hal-01737372⟩
  • Dmitry A. Valyaev, Kamil I. Utegenov, Vassily V. Krivykh, Jérémy Willot, Nikolai A. Ustynyuk, et al.. Dual reactivity pattern of Mn(I) carbyne complexes Cp(CO)2Mn+≡C–R (R = Ar, Alk) vs. dppm: Subtle balance between double intramolecular nucleophilic addition and nucleophilic addition followed by migratory CO insertion. Journal of Organometallic Chemistry, Elsevier, 2018, 867, pp.353-358. ⟨10.1016/j.jorganchem.2017.12.029⟩. ⟨hal-01948411⟩
  • Alina A Grineva, Dmitry A. Valyaev, Vincent César, O. A. Filippov, Victor N. Khrustalev, et al.. Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2018, 57 (27), pp.7986-7991. ⟨10.1002/anie.201801530⟩. ⟨hal-01948415⟩
  • Mirko Ruamps, S. Bastin, Lionel Rechignat, Alix Sournia-Saquet, Dmitry A. Valyaev, et al.. Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes. Chemical Communications, Royal Society of Chemistry, 2018, 54 (55), pp.7653-7656. ⟨10.1039/C8CC03934H⟩. ⟨hal-01948412⟩
  • Dmitry A. Valyaev, Jérémy Willot, Loïc P. Mangin, Davit Zargarian, Noël Lugan. Manganese-mediated synthesis of an NHC core non-symmetric pincer ligand and evaluation of its coordination properties. Dalton Transactions, Royal Society of Chemistry, 2017, 46 (31), pp.10193-10196. ⟨10.1039/C7DT02190A⟩. ⟨hal-01938382⟩
  • Vincent Mesquita, Julien Botton, Dmitry A. Valyaev, Cyril François, Lionel Patrone, et al.. Catalytic Scanning Probe Nanolithography (cSPL): Control of the AFM Parameters in Order to Achieve Sub-100-nm Spatially Resolved Epoxidation of Alkenes Grafted onto a Surface. Langmuir, American Chemical Society, 2016, 32, pp.4034-4042. ⟨10.1021/acs.langmuir.6b00543⟩. ⟨hal-01415128⟩
  • Dmitry A. Valyaev, Guy Lavigne, Noël Lugan. Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects. Coordination Chemistry Reviews, Elsevier, 2016, 308, Part 2, pp.191-235. ⟨10.1016/j.ccr.2015.06.015⟩. ⟨hal-01925253⟩
  • Dmitry A. Valyaev, Duo Wei, Saravanakumar Elangovan, Matthieu Cavailles, Vincent Dorcet, et al.. Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation. Organometallics, American Chemical Society, 2016, 35 (24), pp.4090-4098. ⟨10.1021/acs.organomet.6b00785⟩. ⟨hal-01475468⟩
  • Dmitry A. Valyaev, Marina A. Uvarova, Alina A Grineva, Vincent César, Sergei N. Nefedov, et al.. Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMes(CO2-) ligand. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (30), pp.11953-11957. ⟨10.1039/c6dt02060g⟩. ⟨hal-01925254⟩
  • Dmitry A. Valyaev, Oleg A. Filippov, Noël Lugan, Guy Lavigne, Nikolai A. Ustynyuk. Umpolung of methylenephosphonium ions in their manganese half-sandwich complexes and application to the synthesis of chiral phosphorus-containing ligand scaffolds. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 127 (21), pp.6413-6417. ⟨10.1002/ange.201501256⟩. ⟨hal-01909557⟩
  • Jianxia Zheng, Saravanakumar Elangovan, Dmitry A. Valyaev, Rémy Brousses, Vincent César, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2014, 356 (5), pp.1093-1097. ⟨10.1002/adsc.201300905⟩. ⟨hal-01114930⟩
  • D.A. Valyaev, S. Bastin, K.I. Utegenov, Noël Lugan, Guy Lavigne, et al.. A direct, modular, and efficient construction of the P-C-P structural motif through coupling of manganese carbyne complexes with phosphines. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (8), pp.2175-2178. ⟨10.1002/chem.201304239⟩. ⟨hal-00992333⟩
  • Dmitry A. Valyaev, Sylvain Clair, Lionel Patrone, Mathieu Abel, Louis Porte, et al.. Grafting a homogeneous transition metal catalyst onto a silicon AFM probe: a promising strategy for chemically constructive nanolithography. Chemical Science , The Royal Society of Chemistry, 2013, 4, pp.2815-2821. ⟨10.1039/c3sc50979f⟩. ⟨hal-00861617⟩
  • Noël Lugan, Israel Fernández, Rémy Brousses, Dmitry A. Valyaev, Guy Lavigne, et al.. On the incidence of non-covalent intramolecular interligand interactions on the conformation of carbene complexes: a case study. Dalton Transactions, Royal Society of Chemistry, 2013, 42 (4), pp.898-901. ⟨10.1039/C2DT32554C⟩. ⟨hal-02908209⟩
  • N. Lugan, I. Fernández, Dmitry A. Valyaev, R. Brousses, M. Sierra, et al.. Conformation of half-sandwich Mn(I) O-alkyl and O-aryl Fischer carbene complexes: a joined experimental-theoretical study. Acta Crystallographica Section A : Foundations of Crystallography [1968-2013], International Union of Crystallography, 2011, 67 (a1), pp.C452-C452. ⟨10.1107/S0108767311088611⟩. ⟨hal-03739896⟩
  • Dmitry A. Valyaev, Rémy Brousses, Noël Lugan, Israel Fernández, Miguel Sierra. Do ν(CO) Stretching Frequencies in Metal Carbonyl Complexes Unequivocally Correlate with the Intrinsic Electron-Donicity of Ancillary Ligands?. Chemistry - A European Journal, Wiley-VCH Verlag, 2011, 17 (24), pp.6602-6605. ⟨10.1002/chem.201100651⟩. ⟨hal-03739879⟩
  • Dmitry A. Valyaev, Noël Lugan, Guy Lavigne, Nikolai Ustynyuk. Synthesis of η 1 -α-Phosphinocarbene Complexes of Manganese and Mechanistic Insight into Their Base-Induced Transformations. Organometallics, American Chemical Society, 2011, 30 (8), pp.2318-2332. ⟨10.1021/om2000772⟩. ⟨hal-03739887⟩
  • Vasily Krivykh, Dmitry A. Valyaev, Kamil Utegenov, Andrei Mazhuga, Elena Taits, et al.. Protonation of Zwitterionic Manganese and Rhenium Phosphoniostyryl Complexes (η 5 ‐C 5 H 5 )(CO) 2 M – –C( + PR 3 )=C(H)Ph: Experimental and DFT Study. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2011, 2011 (2), pp.201-211. ⟨10.1002/ejic.201000868⟩. ⟨hal-03739903⟩
  • Dmitry A. Valyaev, Noël Lugan, Guy Lavigne, Nikolai Ustynyuk. Generation of α-Phosphinocarbene Complexes and Their Evolution: New Light on Relevant Isomerization Pathways. Organometallics, American Chemical Society, 2008, 27 (20), pp.5180-5183. ⟨10.1021/om800884v⟩. ⟨hal-03739911⟩
  • Nikolai Ustynyuk, Oleg Gusev, Lyudmila Novikova, Mikhail Peterleitner, Larisa Denisovich, et al.. Redox induced reactions of transition metal π- and σ,π-complexes. Journal of Solid State Electrochemistry, Springer Verlag, 2007, 11 (12), pp.1621-1634. ⟨10.1007/s10008-007-0322-4⟩. ⟨hal-03739918⟩
  • Dmitry A. Valyaev, Mikhail Peterleitner, Oleg Semeikin, Kamil Utegenov, Nikolai Ustynyuk, et al.. Proton reduction catalysis by manganese vinylidene and allenylidene complexes. Journal of Organometallic Chemistry, Elsevier, 2007, 692 (15), pp.3207-3211. ⟨10.1016/j.jorganchem.2007.01.055⟩. ⟨hal-03739916⟩
  • Natalia Belkova, Evgenii Gutsul, Oleg Filippov, Vladislava Levina, Dmitry A. Valyaev, et al.. Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases. Journal of the American Chemical Society, American Chemical Society, 2006, 128 (11), pp.3486-3487. ⟨10.1021/ja057867n⟩. ⟨hal-03739923⟩
  • Dmitry A. Valyaev, Oleg Semeikin, Mikhail Peterleitner, Yuri Borisov, Viktor Khrustalev, et al.. Oxidative dehydrodimerization of rhenium vinylidene complex (η5-C5H5)(CO)2ReCC(H)Ph: two competitive routes of coupling of σ-phenylethynyl intermediate [(η5-C5H5)(CO)2ReCCPh]. X-ray structures of rhenium mononuclear (η5-C5H5)(CO)2ReCC(H)Ph and binuclear [(η5-C5H5)(CO)2Re]2(μ2-CC(Ph)CCPh) vinylidene compounds. Journal of Organometallic Chemistry, Elsevier, 2004, 689 (23), pp.3837-3846. ⟨10.1016/j.jorganchem.2004.07.038⟩. ⟨hal-03739933⟩
  • Dmitry A. Valyaev, Oleg Semeikin, Nikolai Ustynyuk. Redox induced reactions of transition metal vinylidene and related complexes. Coordination Chemistry Reviews, Elsevier, 2004, 248 (15-16), pp.1679-1692. ⟨10.1016/j.ccr.2004.08.008⟩. ⟨hal-03739927⟩
  • Dmitry A. Valyaev, Mikhail Peterleitner, Lidiya Leont'Eva, Lyudmila Novikova, Oleg Semeikin, et al.. Oxidative Activation of the Manganese Bis-vinylidene Complexes [(η 5 -C 5 R 5 )(CO) 2 MnCCPh] 2 (R = H, Me) toward Addition of Nucleophiles. Organometallics, American Chemical Society, 2003, 22 (26), pp.5491-5497. ⟨10.1021/om034015s⟩. ⟨hal-03739935⟩
  • M. Peterleitner, Dmitry A. Valyaev, L. Novikova, O. Semeikin, N. Ustynyuk. Study of Redox-induced Reactions of Vinylidene and bis-Vinylidene Complexes of Manganese. Elektrokhimiya / Russian Journal of Electrochemistry, MAIK Nauka/Interperiodica, 2003, 39 (11), pp.1270-1277. ⟨10.1023/B:RUEL.0000003457.94205.c7⟩. ⟨hal-03739943⟩
  • Lyudmila Novikova, Mikhail Peterleitner, Karine Sevumyan, Oleg Semeikin, Dmitry A. Valyaev, et al.. Oxidative dehydrodimerization of manganese vinylidene complexes (η5-C5R5)(CO)(L)Mn=C=CHPh (R=Me, L=CO; R=H, L=PPh3). Applied Organometallic Chemistry, Wiley-Blackwell, 2002, 16 (9), pp.530-536. ⟨10.1002/aoc.341⟩. ⟨hal-03739954⟩
  • Lyudmila Novikova, Mikhail Peterleitner, Karine Sevumyan, Oleg Semeikin, Dmitry A. Valyaev, et al.. Oxidative dehydrodimerization of manganese phenylvinylidene complex (η5-C5H5)(CO)2Mn=C=C(H)Ph. X-ray structure of phenyl(trityl)vinylidene complex (η5-C5H5)(CO)2Mn=C=C(CPh3)Ph. Journal of Organometallic Chemistry, Elsevier, 2001, 631 (1-2), pp.47-53. ⟨10.1016/S0022-328X(01)01030-0⟩. ⟨hal-03740002⟩

Chapitres d'ouvrage

  • Alina A Grineva, Noël Lugan, Dmitry A. Valyaev. Organometallic Manganese Compounds in Organic Synthesis. Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.1-37, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch1⟩. ⟨hal-03376634⟩

Partenariats

Cliquez pour voir nos collaborations

blabla

Adresse

Laboratoire de chimie de coordination du CNRS

205 route de Narbonne, BP 44099
31077 Toulouse cedex 4
France