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Jean-Baptiste SORTAIS

LCC

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Domaine d'expertise
Production scientifique

Jean-Baptiste SORTAIS

Professeur à l’Université Toulouse III, Paul Sabatier
Équipe A

jean-baptiste.sortais@lcc-toulouse.fr

+33 (0)5 61 33 31 71

Numéro ORCID : 0000-0003-1178-8588

ResearcherID : B-3801-2014

Jean-Baptiste Sortais est Professeur à l’Université Toulouse III, Paul-Sabatier et mène ses travaux de recherches centrés sur la catalyse homogène organométallique au Laboratoire de Chimie de Coordination du CNRS, UPR 8241.

Suite à des études effectuées à l’Ecole Normale Supérieure de Lyon (lauréat du concours de l’Agrégation de Sciences Physiques, option Chimie en 2003), Jean-Baptiste Sortais prépare son DEA, puis son doctorat à l’Université Louis Pasteur à Strasbourg sous la direction du Dr. Michel Pfeffer. Ses travaux de recherches portent alors sur la synthèse de complexes chiraux cyclométalés du ruthénium et leurs applications en catalyse. Il effectue ensuite deux séjours post-doctoraux, successivement avec le Pr. Jan-Erling Bäckvall à l’Université de Stockholm en Suède sur les dédoublements cinétiques dynamiques, puis avec le Pr. Gerhard Erker à l’Université de Münster en Allemagne dans le domaine des paires de Lewis-Frustrées. En 2009, il est recruté comme Maître de Conférences à l’Université de Rennes 1, à l’Institut des Sciences Chimiques de Rennes, dans l’équipe Organométalliques : Matériaux et Catalyse. En 2017, il est promu Professeur à l’Université Toulouse III, Paul Sabatier.

Ses travaux de recherches actuels sont centrés principalement sur le développement de nouveaux catalyseurs moléculaires à base de métaux de transition abondants 3d, tel que le fer, le nickel, le cobalt, et le manganèse. Les applications en catalyse se focalisent autour de processus de réduction au sens large (hydroélémentation, hydrogénation, déshydrogénation, transfert d’hydrogène, hydrosilylation, hydroboration et auto-transfert d’hydrogène) et d’activation directe de liaisons C-H. L’objectif principal de ses travaux est ainsi de promouvoir de nouvelles réactivités et/ou de nouvelles sélectivités sur la base de catalyseurs faisant appel à des métaux facilement disponibles et peu onéreux dans le cadre d’une chimie durable.

En 2016, il a été nommé Membre Junior de l’Institut Universitaire de France et en 2019 il a reçu le prix Jeune Chercheur de la Division Catalyse de la SCF.

 

 

 

 

Domaines d’expertise – projets en cours

Son programme de recherche porte sur le développement de transformations catalytiques sélectives à l’aide de complexes métalliques portant des ligands NHCs.

Ses intérêts de recherche incluent la synthèse organique, la chimie organométallique et la (photo)catalyse homogène, avec un accent particulier sur les réactions de fonctionnalisation des liaisons carbone-hydrogène.

Domaine d’expertise

Catalyse homogène organométallique, complexes des métaux de transition 3d abondants (manganèse, fer, nickel, cobalt), réactions d’hydroélémentation (hydrosilylation, hydroboration), réduction (hydrogénation, transfert d’hydrogène), fonctionnalisation de liaison C-H, auto-transfert d’hydrogène, catalyse asymétrique, chimie verte, étude mécanistique.

Domaine d’applications

Chimie fine, production d’hydrogène, stockage réversible d’hydrogène dans les molécules organiques, recyclage des plastiques par dépolymérisation réductrice, utilisation du méthanol comme source de carbone C1 en chimie organique, silicones

Production scientifique


90 documents

Articles dans une revue86 documents

  • Ekaterina S Gulyaeva, Ruqaya Buhaibeh, Mohamed Boundor, Karim Azouzi, Jérémy Willot, et al.. Impact of the Methylene Bridge Substitution in Chelating NHC‐Phosphine Mn(I) Catalyst for Ketone Hydrogenation. Chemistry - A European Journal, In press, pp.e202304201. ⟨10.1002/chem.202304201⟩. ⟨hal-04522874⟩
  • Karim Azouzi, Romane Pointis, Ruqaya Buhaibeh, Pablo Hermosilla Fernández, Lucie Pedussaut, et al.. Hydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands. Journal of Catalysis, 2024, Journal of Catalysis, 430, pp.115334. ⟨10.1016/j.jcat.2024.115334⟩. ⟨hal-04432103⟩
  • Karim Azouzi, Lucie Pedussaut, Romane Pointis, Anna Bonfiglio, Riddhi Kumari Riddhi, et al.. Hydrogenation of Carboxylic Esters Catalyzed by Phosphine-Free Bis-N-heterocyclic Carbene Manganese Complexes. Organometallics, 2023, 42 (14), pp.1832-1838. ⟨10.1021/acs.organomet.3c00137⟩. ⟨hal-04174553⟩
  • Romane Manguin, María Galiana-Cameo, Tanakorn Kittikool, Cécile Barthes, Jompol Thongpaen, et al.. Iridium(I) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation. Chemical Communications, 2023, 59 (28), pp.4193-4196. ⟨10.1039/d2cc06865f⟩. ⟨hal-04061785⟩
  • Carine Duhayon, Ruqaya Buhaibeh, Dmitry A. Valyaev, Jean-Baptiste Sortais, Yves Canac. Characterisation by X-ray diffraction of bidentate and tridentate PCP and PCN NHC core pincer-type Mn(I) complexes. Acta Crystallographica Section A : Foundations and Advances [2014-..], 2022, 78 (a2), pp.e487-e487. ⟨10.1107/S2053273322092610⟩. ⟨hal-04288540⟩
  • Ekaterina S Gulyaeva, Elena S Osipova, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais, et al.. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes. Coordination Chemistry Reviews, 2022, 458, pp.214421. ⟨10.1016/j.ccr.2022.214421⟩. ⟨hal-03566299⟩
  • Karim Azouzi, Dmitry A. Valyaev, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese – new prominent actor in transfer hydrogenation catalysis. Current opinion in green and sustainable chemistry, 2021, 31, pp.100511. ⟨10.1016/j.cogsc.2021.100511⟩. ⟨hal-03230650⟩
  • Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Hydrosilylation Reactions Catalyzed by Rhenium. Molecules, 2021, 26 (9), pp.2598. ⟨10.3390/molecules26092598⟩. ⟨hal-03230574⟩
  • Alina A Grineva, Oleg A Filippov, Yves Canac, Jean-Baptiste Sortais, Sergei E Nefedov, et al.. Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes. Inorganic Chemistry, 2021, 60 (6), pp.4015-4025. ⟨10.1021/acs.inorgchem.1c00073⟩. ⟨hal-03200528⟩
  • Ruqaya Buhaibeh, Carine Guyard-Duhayon, Dmitry A. Valyaev, Jean-Baptiste Sortais, Yves Canac. Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis. Organometallics, 2021, 40 (2), pp.231−241. ⟨10.1021/acs.organomet.0c00717⟩. ⟨hal-03128901⟩
  • Nikolay Kireev, Oleg Filippov, Ekaterina Gulyaeva, Elena V Shubina, Laure Vendier, et al.. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation. Chemical Communications, 2020, 56 (14), pp.2139-2142. ⟨10.1039/c9cc07713h⟩. ⟨hal-02489712⟩
  • Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes. Chemical Communications, 2020, 56 (78), pp.11617-11620. ⟨10.1039/d0cc03580g⟩. ⟨hal-02959788⟩
  • Karim Azouzi, Antoine Bruneau-Voisine, Laure Vendier, Jean-Baptiste Sortais, Stéphanie Bastin. Asymmetric transfer hydrogenation of ketones promoted by manganese(I) pre-catalysts supported by bidentate aminophosphines. Catalysis Communications, 2020, 142, pp.106040. ⟨10.1016/j.catcom.2020.106040⟩. ⟨hal-02638441⟩
  • D. Wei, Antoine Bruneau-Voisine, M. Dubois, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese-Catalyzed Transfer Hydrogenation of Aldimines. ChemCatChem, 2019, 11 (21), pp.5256-5259. ⟨10.1002/cctc.201900314⟩. ⟨hal-02122163⟩
  • Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Rhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes. Organic Letters, 2019, 21 (19), pp.7713-7716. ⟨10.1021/acs.orglett.9b02449⟩. ⟨hal-02307033⟩
  • Duo Wei, Vincent Dorcet, Christophe Darcel, Jean-Baptiste Sortais. Synthesis of Quinolines Through Acceptorless Dehydrogenative Coupling Catalyzed by Rhenium PN(H)P Complexes. ChemSusChem, 2019, 12 (13), pp.3078-3082. ⟨10.1002/cssc.201802636⟩. ⟨hal-02019486⟩
  • Antoine Bruneau-Voisine, Lenka Pallova, Stéphanie Bastin, Vincent César, Jean-Baptiste Sortais. Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chemical Communications, 2019, 55 (3), pp.314-317. ⟨10.1039/c8cc08064j⟩. ⟨hal-01976517⟩
  • Ruqaya Buhaibeh, Oleg A Filippov, Antoine Bruneau-Voisine, Jérémy Willot, Carine Guyard-Duhayon, et al.. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H Activation Mode. Angewandte Chemie International Edition, 2019, 58 (20), pp.6727-6731. ⟨10.1002/anie.201901169⟩. ⟨hal-02120809⟩
  • Duo Wei, Bertrand Carboni, Jean-Baptiste Sortais, Christophe Darcel. Iron-Catalyzed Dehydrogenative Borylation of Terminal Alkynes. Advanced Synthesis and Catalysis, 2018, 360 (19), pp.3649-3654. ⟨10.1002/adsc.201800588⟩. ⟨hal-01902040⟩
  • Duo Wei, Omar Sadek, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study. Journal of Catalysis, 2018, 366, pp.300 - 309. ⟨10.1016/j.jcat.2018.08.008⟩. ⟨hal-01871104⟩
  • Duo Wei, Antoine Bruneau-Voisine, Dmitry A. Valyaev, Noël Lugan, Jean-Baptiste Sortais. Manganese catalyzed reductive amination of aldehydes using hydrogen as a reductant. Chemical Communications, 2018, 54 (34), pp.4302-4305. ⟨10.1039/C8CC01787E⟩. ⟨hal-01807069⟩
  • Haoran Li, Duo Wei, Antoine Bruneau-Voisine, Maxime Ducamp, Mickael Henrion, et al.. Rhenium and Manganese Complexes Bearing Amino-Bis(phosphinite) Ligands Synthesis, Characterization, and Catalytic Activity in Hydrogenation of Ketones. Organometallics, 2018, 37 (8), pp.1271-1279. ⟨10.1021/acs.organomet.8b00020⟩. ⟨hal-01807088⟩
  • D. Wang, Antoine Bruneau-Voisine, Jean-Baptiste Sortais. Practical (asymmetric) transfer hydrogenation of ketones catalyzed by manganese with (chiral) diamines ligands. Catalysis Communications, 2018, 105, pp.31-36. ⟨10.1016/j.catcom.2017.10.028⟩. ⟨hal-01671636⟩
  • Duo Wei, Antoine Bruneau-Voisine, Teo Chauvin, Vincent Dorcet, Thierry Roisnel, et al.. Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands. Advanced Synthesis and Catalysis, 2018, 360 (4), pp.676-681. ⟨10.1002/adsc.201701115⟩. ⟨hal-01737372⟩
  • Christophe Darcel, Jean-Baptiste Sortais. Homogeneous iron catalysis – Highlights on the increasing impact of a non-noble metal. Israel Journal of Chemistry, 2017, 57 (12), pp.1069-1069. ⟨10.1002/ijch.201700128⟩. ⟨hal-01938387⟩
  • Antoine Bruneau-Voisine, Ding Wang, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Mono-N-methylation of anilines with methanol catalyzed by a manganese pincer-complex. Journal of Catalysis, 2017, 347, pp.57-62. ⟨10.1016/j.jcat.2017.01.004⟩. ⟨hal-01475818⟩
  • Antoine Bruneau-Voisine, Ding Wang, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst. Catalysis Communications, 2017, 92, pp.1-4. ⟨10.1016/j.catcom.2016.12.017⟩. ⟨hal-01475820⟩
  • S. Quintero-Duque, H. Li, L.C. Misal Castro, V. Dorcet, T. Roisnel, et al.. N-Heterocyclic Carbene Iron Silyl Hydride Complexes. Israel Journal of Chemistry, 2017, 57 (12), pp.1216-1221. ⟨10.1002/ijch.201700122⟩. ⟨hal-01713508⟩
  • Antoine Bruneau-Voisine, Ding Wang, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst. Organic Letters, 2017, 19 (13), pp.3656-3659. ⟨10.1021/acs.orglett.7b01657⟩. ⟨hal-01560307⟩
  • Duo Wei, Thierry Roisnel, Christophe Darcel, Eric Clot, Jean-Baptiste Sortais. Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst. ChemCatChem, 2017, 9 (1), pp.80-83. ⟨10.1002/cctc.201601141⟩. ⟨hal-01435008⟩
  • Mickaël Henrion, Thierry Roisnel, Jean-Luc Couturier, Jean-Luc Dubois, Jean-Baptiste Sortais, et al.. Ruthenium complexes bearing amino-bis(phosphinite) or amino-bis(aminophosphine) ligands: Application in catalytic ester hydrogenation. Molecular Catalysis, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩. ⟨hal-01532177⟩
  • Saravanakumar Elangovan, Jacob Neumann, Jean-Baptiste Sortais, Kathrin Junge, Christophe Darcel, et al.. Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes. Nature Communications, 2016, 7 (1), pp.12641. ⟨10.1038/ncomms12641⟩. ⟨hal-01395480⟩
  • Dmitry A. Valyaev, Duo Wei, Saravanakumar Elangovan, Matthieu Cavailles, Vincent Dorcet, et al.. Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation. Organometallics, 2016, 35 (24), pp.4090-4098. ⟨10.1021/acs.organomet.6b00785⟩. ⟨hal-01475468⟩
  • Bin Li, Jean-Baptiste Sortais, Christophe Darcel. Amine synthesis via transition metal homogeneous catalysed hydrosilylation. RSC Advances, 2016, 6 (62), pp.S7603--S7625. ⟨10.1039/c6ra10494k⟩. ⟨hal-01357397⟩
  • Shi Jiang, Samuel Quintero-Duque, Thierry Roisnel, Vincent Dorcet, Mary Grellier, et al.. Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene. Dalton Transactions, 2016, 45 (27), pp.11101--11108. ⟨10.1039/c6dt01149g⟩. ⟨hal-01357395⟩
  • C. Gunnar Werncke, Mohammed-Amine Bouammali, Julie Baumard, Nicolas Suaud, Cyril Martins, et al.. Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes. Inorganic Chemistry, 2016, 55 (21), pp.10968-10977. ⟨10.1021/acs.inorgchem.6b01512⟩. ⟨hal-01413205⟩
  • Anuj Kumar, Linus Paulin Bheeter, Manoj Kumar Gangwar, Jean-Baptiste Sortais, Christophe Darcel, et al.. Nickel complexes of 1,2,4-triazole derived amido-functionalized N-heterocyclic carbene ligands: Synthesis, theoretical studies and catalytic application. Journal of Organometallic Chemistry, 2015, 786, pp.63--70. ⟨10.1016/j.jorganchem.2015.03.007⟩. ⟨hal-01224508⟩
  • Luis C. Misal Castro, Haoquan Li, Jean-Baptiste Sortais, Christophe Darcel. When iron met phosphines: a happy marriage for reduction catalysis.. Green Chemistry, 2015, 17 (4), pp.2283--2303. ⟨10.1039/C4GC01866D⟩. ⟨hal-01153434⟩
  • Thomas Dombray, C. Gunnar Werncke, Shi Jiang, Mary Grellier, Laure Vendier, et al.. Iron-Catalyzed C-H Borylation of Arenes.. Journal of the American Chemical Society, 2015, 137 (12), pp.4062-4065. ⟨10.1021/jacs.5b00895⟩. ⟨hal-01153417⟩
  • Saravanakumar Elangovan, Jean-Baptiste Sortais, Matthias Beller, Christophe Darcel. Iron-Catalyzed α-Alkylation of Ketones with Alcohols. Angewandte Chemie International Edition, 2015, 54 (48), pp.14483-14486. ⟨10.1002/anie.201506698⟩. ⟨hal-01216296⟩
  • Saravanakumar Elangovan, Samuel Quintero-Duque, Vincent Dorcet, Thierry Roisnel, Lucie Norel, et al.. Knolker-Type Iron Complexes Bearing an N-Heterocyclic Carbene Ligand: Synthesis, Characterization, and Catalytic Dehydration of Primary Amides. Organometallics, 2015, 34 (18), pp.4521-4528. ⟨10.1021/acs.organomet.5b00553⟩. ⟨hal-01205446⟩
  • Linus P. Bheeter, Duo Wei, Vincent Dorcet, Thierry Roisnel, Prasenjit Ghosh, et al.. 1,2,4-Triazole-Based N-Heterocyclic Carb-ene Nickel Complexes - Synthesis and Catalytic Application. European Journal of Inorganic Chemistry, 2015, 2015 (31), pp.5226-5231. ⟨10.1002/ejic.201500852⟩. ⟨hal-01216291⟩
  • Jianxia Zheng, Christophe Darcel, Jean-Baptiste Sortais. Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by iron complexes.. Chemical Communications, 2014, 50 (91), pp.14229-32. ⟨10.1039/C4CC05517A⟩. ⟨hal-01114594⟩
  • Serpil Demir, Yasemin Gökçe, Thierry Roisnel, Jean-Baptiste Sortais, Christophe Darcel, et al.. Imidazolidinium ferrate complexes: Synthesis and catalytic properties. Comptes Rendus. Chimie, 2014, 17 (6), pp.541-548. ⟨10.1016/j.crci.2014.03.015⟩. ⟨hal-01121095⟩
  • Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel. [(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes. ChemCatChem, 2014, 6 (3), pp.763-766. ⟨10.1002/cctc.201301062⟩. ⟨hal-01114927⟩
  • Jianxia Zheng, Saravanakumar Elangovan, Dmitry A. Valyaev, Rémy Brousses, Vincent César, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes. Advanced Synthesis and Catalysis, 2014, 356 (5), pp.1093-1097. ⟨10.1002/adsc.201300905⟩. ⟨hal-01114930⟩
  • Dharmendra Kumar, A. P. Prakasham, Linus P. Bheeter, Jean-Baptiste Sortais, Manoj Grangwar, et al.. Cationic Iron(II) Complexes of the Mixed Cyclopentadienyl (Cp) and the N-heterocyclic Carbene (NHC) Ligands as Effective Precatalysts for the Hydrosilylation of Carbonyl Compounds. Journal of Organometallic Chemistry, 2014, 762, pp.81-87. ⟨10.1016/j.jorganchem.2014.03.016⟩. ⟨hal-01121131⟩
  • Haoquan Li, Mathieu Achard, Christian Bruneau, Jean-Baptiste Sortais, Christophe Darcel. Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines. RSC Advances, 2014, 4 (49), pp.25892-25897. ⟨10.1039/C4RA04037F⟩. ⟨hal-01114838⟩
  • Thomas Dombray, Camille Helleu, Christophe Darcel, Jean-Baptiste Sortais. Cobalt Carbonyl-Based Catalyst for Hydrosilylation of Carboxamides. Advanced Synthesis and Catalysis, 2013, 355 (17), pp.3358-3362. ⟨10.1002/adsc.201300664⟩. ⟨hal-01089274⟩
  • Demir Serpil, Gökçe Yasemin, Nazan Kaloğlu, Jean-Baptiste Sortais, Christophe Darcel, et al.. Synthesis of new iron-NHC complexes as catalysts for hydrosilylation reactions. Applied Organometallic Chemistry, 2013, 27, pp.459-464. ⟨10.1002/aoc.3006⟩. ⟨hal-01089236⟩
  • Bin Li, Jean-Baptiste Sortais, Christophe Darcel. Unexpected selectivity in ruthenium-catalyzed hydrosilylation of primary amides: synthesis of secondary amines.. Chemical Communications, 2013, 49 (35), pp.3691-3. ⟨10.1039/c3cc39149c⟩. ⟨hal-00879855⟩
  • Jean-Baptiste Sortais, Christophe Darcel. Chiral Cyclopentadienyl-type Ligands: a New Breakthrough for Asymmetric C[BOND]H Functionalisation. ChemCatChem, 2013, 5 (5), pp.1067-1068. ⟨10.1002/cctc.201200874⟩. ⟨hal-00879852⟩
  • Jianxia Zheng, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Nickel-Catalyzed Reductive Amination with Hydrosilanes.. ChemCatChem, 2013, 5, pp.2861--2864. ⟨10.1002/cctc.201300338⟩. ⟨hal-01069941⟩
  • Linus P. Bheeter, Mickael Henrion, Michael J. Chetcuti, Christophe Darcel, Vincent Ritleng, et al.. Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines.. Catalysis Science & Technology, 2013, 3, pp.3111--3116. ⟨10.1039/c3cy00514c⟩. ⟨hal-01069725⟩
  • Vincent César, Luis C. Misal Castro, Thomas Dombray, Jean-Baptiste Sortais, Christophe Darcel, et al.. (Cyclopentadienyl)iron(II) complexes of N-heterocyclic carbenes bearing a malonate or imidate backbone: Synthesis, structure, and catalytic potential in hydrosilylation. Organometallics, 2013, 32 (16), pp.4643-4655. ⟨10.1021/om400625q⟩. ⟨hal-00993533⟩
  • Jianxia Zheng, Christophe Darcel, Jean-Baptiste Sortais. A convenient nickel-catalysed hydrosilylation of carbonyl derivatives.. Catalysis Science & Technology, 2013, 3 (1), pp.81-84. ⟨10.1039/c2cy20509b⟩. ⟨hal-00808945⟩
  • Haoquan Li, Luis C. Misal Castro, Jianxia Zheng, Thierry Roisnel, Vincent Dorcet, et al.. Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC-Iron Complexes.. Angewandte Chemie International Edition, 2013, 52, pp.8045--8049. ⟨10.1002/anie.201303003⟩. ⟨hal-01069952⟩
  • Jianxia Zheng, Soizic Chevance, Christophe Darcel, Jean-Baptiste Sortais. Selective reduction of carboxylic acids to aldehydes through manganese catalysed hydrosilylation. Chemical Communications, 2013, 49, pp.10010-10012. ⟨10.1039/C3CC45349A⟩. ⟨hal-00870857⟩
  • David Bezier, Jean-Baptiste Sortais, Christophe Darcel. N-Heterocyclic Carbene Ligands and Iron : An Effective Association for Catalysis.. Advanced Synthesis and Catalysis, 2013, 355 (1), pp.19-33. ⟨10.1002/adsc.201200666⟩. ⟨hal-00812031⟩
  • Luis C Misal Castro, Haoquan Li, Jean-Baptiste Sortais, Christophe Darcel. Selective switchable iron-catalyzed hydrosilylation of carboxylic acids.. Chemical Communications, 2012, 48 (85), pp.10514-6. ⟨10.1039/c2cc35727e⟩. ⟨hal-00805237⟩
  • Linus P. Bheeter, Mickaël Henrion, Lydia Brelot, Christophe Darcel, Michael J. Chetcuti, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene-Nickel Hydride Complex under Mild Conditions. Advanced Synthesis and Catalysis, 2012, 354 (14-15), pp.2619-2624. ⟨10.1002/adsc.201200460⟩. ⟨hal-00864826⟩
  • Hassen Jaafar, Haoquan Li, Luis C Misal Castro, Jianxia Zheng, Thierry Roisnel, et al.. Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction. European Journal of Inorganic Chemistry, 2012, 2012 (22), pp.3546-3550. ⟨10.1002/ejic.201200550⟩. ⟨hal-00868526⟩
  • David Bezier, Gopaladasu T. Venkanna, Luis C Misal Castro, Jianxia Zheng, Thierry Roisnel, et al.. Iron-Catalyzed Hydrosilylation of Esters. Advanced Synthesis and Catalysis, 2012, 354 (10), pp.1879-1884. ⟨10.1002/adsc.201200087⟩. ⟨hal-00868444⟩
  • Jianxia Zheng, Luis C Misal Castro, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Iron Piano-Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction. Inorganica Chimica Acta, 2012, 380, pp.301-307. ⟨10.1016/j.ica.2011.10.048⟩. ⟨hal-00864821⟩
  • Luis C Misal Castro, Jean-Baptiste Sortais, Christophe Darcel. NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines.. Chemical Communications, 2012, 48 (1), pp.151-3. ⟨10.1039/c1cc14403k⟩. ⟨hal-00805367⟩
  • D. Bézier, F. Jiang, Thierry Roisnel, Jean-Baptiste Sortais, Christophe Darcel. Cyclopentadienyl-NHC Iron Complexes for Solvent Free Catalytic Hydrosilylation of Aldehydes and Ketones. European Journal of Inorganic Chemistry, 2012, 9, pp.1333-1337. ⟨10.1002/ejic.201100762⟩. ⟨hal-00698447⟩
  • B. Li, Jean-Baptiste Sortais, Christophe Darcel, Pierre H. Dixneuf. Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts. ChemSusChem, 2012, 5, pp.396-399. ⟨10.1002/cssc.201100585⟩. ⟨hal-00698460⟩
  • Jean-Pierre Djukic, Jean-Baptiste Sortais, Laurent Barloy, Nicolas Pannetier, Claude Sirlin, et al.. Synthesis, Characterization, and Fluxional Behavior of a 34 Electron Homochiral Dimetallic Complex with an Unsupported Hydride Bridge between Two Ru Atoms. Organometallics, 2012, 31 (7), pp.2821-2828. ⟨10.1021/om201093y⟩. ⟨hal-00698475⟩
  • David Bezier, Gopaladasu T. Venkanna, Jean-Baptiste Sortais, Christophe Darcel. Well-Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles. ChemCatChem, 2011, 3 (11), pp.1747-1750. ⟨10.1002/cctc.201100202⟩. ⟨hal-00877671⟩
  • Nicolas Pannetier, Jean-Baptiste Sortais, Jean-Thomas Issenhuth, Laurent Barloy, Claude Sirlin, et al.. Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines. Advanced Synthesis and Catalysis, 2011, 353 (14-15), pp.2844-2852. ⟨10.1002/adsc.201100152⟩. ⟨hal-00877679⟩
  • Luis C. Misal Castro, David Bezier, Jean-Baptiste Sortais, Christophe Darcel. Iron Dihydride Complex as the Pre-catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation. Advanced Synthesis and Catalysis, 2011, 353 (8), pp.1279-1284. ⟨10.1002/adsc.201000676⟩. ⟨hal-00632082⟩
  • Fan Jiang, David Bezier, Jean-Baptiste Sortais, Christophe Darcel. N-Heterocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives. Advanced Synthesis and Catalysis, 2011, 353 (2-3), pp.239-244. ⟨10.1002/adsc.201000781⟩. ⟨hal-00632074⟩
  • Tanja Voss, Jean-Baptiste Sortais, Roland Fröhlich, Gerald Kehr, Gerhard Erker. Alkene Addition of Frustrated P/B and N/B Lewis Pairs at the [3]Ferrocenophane Framework. Organometallics, 2011, 30 (3), pp.584-594. ⟨10.1021/om100949k⟩. ⟨hal-00632086⟩
  • Chloé Vovard-Le Bray, Fan Jiang, Xiao-Feng Wu, Jean-Baptiste Sortais, Christophe Darcel. Cyclen-Catalyzed Henry Reaction under Neutral Conditions. Tetrahedron Letters, 2010, 51 (34), pp.4555-4557. ⟨10.1016/j.tetlet.2010.06.106⟩. ⟨hal-00576912⟩
  • K. Parkhomenko, L. Barloy, Jb Sortais, Jp Djukic, M. Pfeffer. Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions. Tetrahedron Letters, 2010, 51, pp.822-825. ⟨10.1016/j.tetlet.2009.12.011⟩. ⟨hal-00492655⟩
  • Jean-Baptiste Sortais, T. Voss, G. Kehr, R. Froehlich, G. Erker. 1,2-Olefin Q1 addition of a frustrated amine–borane Lewis pair. Chemical Communications, 2009, pp.7417-7418. ⟨10.1039/b915657g⟩. ⟨hal-00448526⟩
  • J.P. Djukic, Jean-Baptiste Sortais, L. Barloy, M. Pfeffer. Cycloruthenated Compounds, Synthesis and Applications. European Journal of Inorganic Chemistry, 2009, pp.817-853. ⟨10.1002/ejic.200801016⟩. ⟨hal-00448519⟩
  • L. K. Thalén, D. Zhao, Jean-Baptiste Sortais, J. Paetzold, C. Hoben, et al.. A Chemoenzymatic Approach to Enantiomerically Pure Amines Using Dynamic Kinetic Resolution. Application to the Synthesis of NorSertraline. Chemistry - A European Journal, 2009, 15, pp.3403-3410. ⟨10.1002/chin.200929067⟩. ⟨hal-00448515⟩
  • Nicolas Pannetier, Jean-Baptiste Sortais, Pape Sylla Dieng, Laurent Barloy, Claude Sirlin, et al.. Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer. Organometallics, 2008, 27 (22), pp.5852-5859. ⟨10.1021/om800420r⟩. ⟨hal-03639733⟩
  • Jean-Baptiste Sortais, Lydia Brelot, Michel Pfeffer, Laurent Barloy. μ 3 -Carbonato-κ 3 O : O ′: O ′′-tris{(η 6 -benzene)[( R )-1-(1-aminoethyl)naphthyl-κ 2 C 2 , N ]ruthenium(II)} hexafluoridophosphate dichloromethane solvate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2008, 64 (3), pp.m483-m484. ⟨10.1107/S1600536808003978⟩. ⟨hal-03639751⟩
  • Jean-Baptiste Sortais, Nicolas Pannetier, Nicolas Clément, Laurent Barloy, Claude Sirlin, et al.. Cyclometalation of Secondary Benzyl Amines by Ruthenium(II) Complexes. Organometallics, 2007, 26 (8), pp.1868-1874. ⟨10.1021/om060974l⟩. ⟨hal-03639782⟩
  • Jean-Baptiste Sortais, Nicolas Pannetier, Alexandre Holuigue, Laurent Barloy, Claude Sirlin, et al.. Cyclometalation of Primary Benzyl Amines by Ruthenium(II), Rhodium(III), and Iridium(III) Complexes. Organometallics, 2007, 26 (8), pp.1856-1867. ⟨10.1021/om060973t⟩. ⟨hal-03639768⟩
  • Grégory Malaisé, Jean-Baptiste Sortais, Laurent Barloy, Michel Pfeffer, Nathalie Kyritsakas. Nitrogen-containing xanthene-based chiral ligands: Synthesis, NMR and X-ray analyses, and catalytic applications of their palladium, silver and rhodium complexes. Polyhedron, 2006, 25 (17), pp.3349-3365. ⟨10.1016/j.poly.2006.06.006⟩. ⟨hal-03639820⟩
  • Jean-Baptiste Sortais, Laurent Barloy, Claude Sirlin, André de Vries, Johannes de Vries, et al.. Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction. Pure and Applied Chemistry, 2006, 78 (2), pp.457-462. ⟨10.1351/pac200678020457⟩. ⟨hal-03639847⟩
  • Jean-Baptiste Sortais, Vincent Ritleng, Adeline Voelklin, Alexandre Holuigue, Hakima Smail, et al.. Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for Asymmetric Transfer Hydrogenation. Organic Letters, 2005, 7 (7), pp.1247-1250. ⟨10.1021/ol047353d⟩. ⟨hal-03639855⟩
  • David Inschauspe, Jean-Baptiste Sortais, Thierry Billard, Bernard Langlois. Trifluoromethanesulfinic Acid Derivatives as Nucleophilic Trifluoromethylating Reagents. SYNLETT, 2003, 2, pp.0233-0235. ⟨10.1055/s-2003-36788⟩. ⟨hal-03639867⟩

Ouvrages (y compris édition critique et traduction)1 document


Chapitres d'ouvrage3 documents

  • Jean-Baptiste Sortais, Ruqaya Buhaibeh, Yves Canac. Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions. Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.39-66, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch2⟩. ⟨hal-03376666⟩
  • Christophe Darcel, Jean-Baptiste Sortais, Samuel Quintero Duque. Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions (chap. 4). Chao-Jun Li (ed.). From C-H to C-C Bonds : Cross-Dehydrogenative-Coupling, Royal Society of Chemistry, pp.67-92, 2015, 978-1-84973-797-5. ⟨10.1039/9781782620082-00067⟩. ⟨hal-01114926⟩
  • Christophe Darcel, Jean-Baptiste Sortais. Iron-Catalyzed Reduction and Hydroelementation Reactions. Bauer, Eike. Iron Catalysis II, 50, Springer International Publishing, pp.173--216, 2015, Topics in Organometallic Chemistry, 978-3-319-19395-3 978-3-319-19396-0. ⟨10.1007/3418_2015_104⟩. ⟨hal-01278353⟩

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