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Jean-Baptiste SORTAIS

LCC

Jean-Baptiste SORTAIS

Professeur à l’Université Toulouse III, Paul Sabatier
Équipe A

jean-baptiste.sortais@lcc-toulouse.fr

+33 (0)5 61 33 32 03

Numéro ORCID : 0000-0003-1178-8588

ResearcherID : B-3801-2014

Jean-Baptiste Sortais est Professeur à l’Université Toulouse III, Paul-Sabatier et mène ses travaux de recherches centrés sur la catalyse homogène organométallique au Laboratoire de Chimie de Coordination du CNRS, UPR 8241.

Suite à des études effectuées à l’Ecole Normale Supérieure de Lyon (lauréat du concours de l’Agrégation de Sciences Physiques, option Chimie en 2003), Jean-Baptiste Sortais prépare son DEA, puis son doctorat à l’Université Louis Pasteur à Strasbourg sous la direction du Dr. Michel Pfeffer. Ses travaux de recherches portent alors sur la synthèse de complexes chiraux cyclométalés du ruthénium et leurs applications en catalyse. Il effectue ensuite deux séjours post-doctoraux, successivement avec le Pr. Jan-Erling Bäckvall à l’Université de Stockholm en Suède sur les dédoublements cinétiques dynamiques, puis avec le Pr. Gerhard Erker à l’Université de Münster en Allemagne dans le domaine des paires de Lewis-Frustrées. En 2009, il est recruté comme Maître de Conférences à l’Université de Rennes 1, à l’Institut des Sciences Chimiques de Rennes, dans l’équipe Organométalliques : Matériaux et Catalyse. En 2017, il est promu Professeur à l’Université Toulouse III, Paul Sabatier.

Ses travaux de recherches actuels sont centrés principalement sur le développement de nouveaux catalyseurs moléculaires à base de métaux de transition abondants 3d, tel que le fer, le nickel, le cobalt, et le manganèse. Les applications en catalyse se focalisent autour de processus de réduction au sens large (hydroélémentation, hydrogénation, déshydrogénation, transfert d’hydrogène, hydrosilylation, hydroboration et auto-transfert d’hydrogène) et d’activation directe de liaisons C-H. L’objectif principal de ses travaux est ainsi de promouvoir de nouvelles réactivités et/ou de nouvelles sélectivités sur la base de catalyseurs faisant appel à des métaux facilement disponibles et peu onéreux dans le cadre d’une chimie durable.

En 2016, il a été nommé Membre Junior de l’Institut Universitaire de France et en 2019 il a reçu le prix Jeune Chercheur de la Division Catalyse de la SCF.

 

 

 

 

Domaines d’expertise – projets en cours

Son programme de recherche porte sur le développement de transformations catalytiques sélectives à l’aide de complexes métalliques portant des ligands NHCs.

Ses intérêts de recherche incluent la synthèse organique, la chimie organométallique et la (photo)catalyse homogène, avec un accent particulier sur les réactions de fonctionnalisation des liaisons carbone-hydrogène.

Domaine d’expertise

Catalyse homogène organométallique, complexes des métaux de transition 3d abondants (manganèse, fer, nickel, cobalt), réactions d’hydroélémentation (hydrosilylation, hydroboration), réduction (hydrogénation, transfert d’hydrogène), fonctionnalisation de liaison C-H, auto-transfert d’hydrogène, catalyse asymétrique, chimie verte, étude mécanistique.

Domaine d’applications

Chimie fine, production d’hydrogène, stockage réversible d’hydrogène dans les molécules organiques, recyclage des plastiques par dépolymérisation réductrice, utilisation du méthanol comme source de carbone C1 en chimie organique, silicones

Production scientifique



86 documents

Articles dans une revue

  • Ekaterina S Gulyaeva, Elena S Osipova, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais, et al.. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes. Coordination Chemistry Reviews, Elsevier, 2022, 458, pp.214421. ⟨10.1016/j.ccr.2022.214421⟩. ⟨hal-03566299⟩
  • Karim Azouzi, Dmitry A. Valyaev, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese – new prominent actor in transfer hydrogenation catalysis. Current opinion in green and sustainable chemistry, Elsevier, 2021, 31, pp.100511. ⟨10.1016/j.cogsc.2021.100511⟩. ⟨hal-03230650⟩
  • Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Hydrosilylation Reactions Catalyzed by Rhenium. Molecules, MDPI, 2021, 26 (9), pp.2598. ⟨10.3390/molecules26092598⟩. ⟨hal-03230574⟩
  • Alina A Grineva, Oleg A Filippov, Yves Canac, Jean-Baptiste Sortais, Sergei E Nefedov, et al.. Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes. Inorganic Chemistry, American Chemical Society, 2021, 60 (6), pp.4015-4025. ⟨10.1021/acs.inorgchem.1c00073⟩. ⟨hal-03200528⟩
  • Ruqaya Buhaibeh, Carine Guyard-Duhayon, Dmitry A. Valyaev, Jean-Baptiste Sortais, Yves Canac. Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis. Organometallics, American Chemical Society, 2021, 40 (2), pp.231−241. ⟨hal-03128901⟩
  • Nikolay Kireev, Oleg Filippov, Ekaterina Gulyaeva, Elena V Shubina, Laure Vendier, et al.. Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H 2 activation. Chemical Communications, Royal Society of Chemistry, 2020, 56 (14), pp.2139-2142. ⟨10.1039/c9cc07713h⟩. ⟨hal-02489712⟩
  • Karim Azouzi, Antoine Bruneau-Voisine, Laure Vendier, Jean-Baptiste Sortais, Stéphanie Bastin. Asymmetric transfer hydrogenation of ketones promoted by manganese(I) pre-catalysts supported by bidentate aminophosphines. Catalysis Communications, Elsevier, 2020, 142, pp.106040. ⟨10.1016/j.catcom.2020.106040⟩. ⟨hal-02638441⟩
  • Duo Wei, Ruqaya Buhaibeh, yves Canac, Jean-Baptiste Sortais. Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes. Chemical Communications, Royal Society of Chemistry, 2020, 56 (78), pp.11617-11620. ⟨10.1039/d0cc03580g⟩. ⟨hal-02959788⟩
  • D. Wei, Antoine Bruneau-Voisine, M. Dubois, Stéphanie Bastin, Jean-Baptiste Sortais. Manganese-Catalyzed Transfer Hydrogenation of Aldimines. ChemCatChem, Wiley, 2019, 11 (21), pp.5256-5259. ⟨10.1002/cctc.201900314⟩. ⟨hal-02122163⟩
  • Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Rhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes. Organic Letters, American Chemical Society, 2019, 21 (19), pp.7713-7716. ⟨10.1021/acs.orglett.9b02449⟩. ⟨hal-02307033⟩
  • Duo Wei, Vincent Dorcet, Christophe Darcel, Jean-Baptiste Sortais. Synthesis of Quinolines Through Acceptorless Dehydrogenative Coupling Catalyzed by Rhenium PN(H)P Complexes. ChemSusChem, ChemPubSoc Europe/Wiley, 2019, 12 (13), pp.3078-3082. ⟨10.1002/cssc.201802636⟩. ⟨hal-02019486⟩
  • Antoine Bruneau-Voisine, Lenka Pallova, Stéphanie Bastin, Vincent César, Jean-Baptiste Sortais. Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chemical Communications, Royal Society of Chemistry, 2019, 55 (3), pp.314-317. ⟨10.1039/c8cc08064j⟩. ⟨hal-01976517⟩
  • Ruqaya Buhaibeh, Oleg A Filippov, Antoine Bruneau-Voisine, Jérémy Willot, Carine Guyard-Duhayon, et al.. Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H Activation Mode. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2019, 58 (20), pp.6727-6731. ⟨10.1002/anie.201901169⟩. ⟨hal-02120809⟩
  • Duo Wei, Bertrand Carboni, Jean-Baptiste Sortais, Christophe Darcel. Iron-Catalyzed Dehydrogenative Borylation of Terminal Alkynes. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (19), pp.3649-3654. ⟨10.1002/adsc.201800588⟩. ⟨hal-01902040⟩
  • Duo Wei, Omar Sadek, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Selective mono N-methylation of anilines with methanol catalyzed by rhenium complexes: An experimental and theoretical study. Journal of Catalysis, Elsevier, 2018, 366, pp.300 - 309. ⟨10.1016/j.jcat.2018.08.008⟩. ⟨hal-01871104⟩
  • Duo Wei, Antoine Bruneau-Voisine, Dmitry A. Valyaev, Noël Lugan, Jean-Baptiste Sortais. Manganese catalyzed reductive amination of aldehydes using hydrogen as a reductant. Chemical Communications, Royal Society of Chemistry, 2018, 54 (34), pp.4302-4305. ⟨10.1039/C8CC01787E⟩. ⟨hal-01807069⟩
  • Haoran Li, Duo Wei, Antoine Bruneau-Voisine, Maxime Ducamp, Mickael Henrion, et al.. Rhenium and Manganese Complexes Bearing Amino-Bis(phosphinite) Ligands Synthesis, Characterization, and Catalytic Activity in Hydrogenation of Ketones. Organometallics, American Chemical Society, 2018, 37 (8), pp.1271-1279. ⟨10.1021/acs.organomet.8b00020⟩. ⟨hal-01807088⟩
  • D. Wang, Antoine Bruneau-Voisine, Jean-Baptiste Sortais. Practical (asymmetric) transfer hydrogenation of ketones catalyzed by manganese with (chiral) diamines ligands. Catalysis Communications, Elsevier, 2018, 105, pp.31-36. ⟨10.1016/j.catcom.2017.10.028⟩. ⟨hal-01671636⟩
  • Duo Wei, Antoine Bruneau-Voisine, Teo Chauvin, Vincent Dorcet, Thierry Roisnel, et al.. Hydrogenation of Carbonyl Derivatives Catalysed by Manganese Complexes Bearing Bidentate Pyridinyl-Phosphine Ligands. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2018, 360 (4), pp.676-681. ⟨10.1002/adsc.201701115⟩. ⟨hal-01737372⟩
  • Christophe Darcel, Jean-Baptiste Sortais. Homogeneous iron catalysis – Highlights on the increasing impact of a non-noble metal. Israel Journal of Chemistry, Wiley-VCH Verlag, 2017, 57 (12), pp.1069-1069. ⟨10.1002/ijch.201700128⟩. ⟨hal-01938387⟩
  • Antoine Bruneau-Voisine, Ding Wang, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Mono-N-methylation of anilines with methanol catalyzed by a manganese pincer-complex. Journal of Catalysis, Elsevier, 2017, 347, pp.57-62. ⟨10.1016/j.jcat.2017.01.004⟩. ⟨hal-01475818⟩
  • Antoine Bruneau-Voisine, Ding Wang, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Hydrogenation of ketones with a manganese PN3P pincer pre-catalyst. Catalysis Communications, Elsevier, 2017, 92, pp.1-4. ⟨10.1016/j.catcom.2016.12.017⟩. ⟨hal-01475820⟩
  • S. Quintero-Duque, H. Li, L.C. Misal Castro, V. Dorcet, T. Roisnel, et al.. N-Heterocyclic Carbene Iron Silyl Hydride Complexes. Israel Journal of Chemistry, Wiley-VCH Verlag, 2017, 57 (12), pp.1216-1221. ⟨10.1002/ijch.201700122⟩. ⟨hal-01713508⟩
  • Antoine Bruneau-Voisine, Ding Wang, Vincent Dorcet, Thierry Roisnel, Christophe Darcel, et al.. Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst. Organic Letters, American Chemical Society, 2017, 19 (13), pp.3656-3659. ⟨10.1021/acs.orglett.7b01657⟩. ⟨hal-01560307⟩
  • Duo Wei, Thierry Roisnel, Christophe Darcel, Eric Clot, Jean-Baptiste Sortais. Hydrogenation of Carbonyl Derivatives with a Well-Defined Rhenium Precatalyst. ChemCatChem, Wiley, 2017, 9 (1), pp.80-83. ⟨10.1002/cctc.201601141⟩. ⟨hal-01435008⟩
  • Mickaël Henrion, Thierry Roisnel, Jean-Luc Couturier, Jean-Luc Dubois, Jean-Baptiste Sortais, et al.. Ruthenium complexes bearing amino-bis(phosphinite) or amino-bis(aminophosphine) ligands: Application in catalytic ester hydrogenation. Molecular Catalysis, Elsevier, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩. ⟨hal-01532177⟩
  • Dmitry A. Valyaev, Duo Wei, Saravanakumar Elangovan, Matthieu Cavailles, Vincent Dorcet, et al.. Half-Sandwich Manganese Complexes Bearing Cp Tethered N-Heterocyclic Carbene Ligands: Synthesis and Mechanistic Insights into the Catalytic Ketone Hydrosilylation. Organometallics, American Chemical Society, 2016, 35 (24), pp.4090-4098. ⟨10.1021/acs.organomet.6b00785⟩. ⟨hal-01475468⟩
  • Saravanakumar Elangovan, Jacob Neumann, Jean-Baptiste Sortais, Kathrin Junge, Christophe Darcel, et al.. Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes. Nature Communications, Nature Publishing Group, 2016, 7 (1), pp.12641. ⟨10.1038/ncomms12641⟩. ⟨hal-01395480⟩
  • C. Gunnar Werncke, Mohammed-Amine Bouammali, Julie Baumard, Nicolas Suaud, Cyril Martins, et al.. Ising-type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes. Inorganic Chemistry, American Chemical Society, 2016, 55 (21), pp.10968-10977. ⟨10.1021/acs.inorgchem.6b01512⟩. ⟨hal-01413205⟩
  • Shi Jiang, Samuel Quintero-Duque, Thierry Roisnel, Vincent Dorcet, Mary Grellier, et al.. Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (27), pp.11101--11108. ⟨10.1039/c6dt01149g⟩. ⟨hal-01357395⟩
  • Bin Li, Jean-Baptiste Sortais, Christophe Darcel. Amine synthesis via transition metal homogeneous catalysed hydrosilylation. RSC Advances, Royal Society of Chemistry, 2016, 6 (62), pp.S7603--S7625. ⟨10.1039/c6ra10494k⟩. ⟨hal-01357397⟩
  • Anuj Kumar, Linus Paulin Bheeter, Manoj Kumar Gangwar, Jean-Baptiste Sortais, Christophe Darcel, et al.. Nickel complexes of 1,2,4-triazole derived amido-functionalized N-heterocyclic carbene ligands: Synthesis, theoretical studies and catalytic application. Journal of Organometallic Chemistry, Elsevier, 2015, 786, pp.63--70. ⟨10.1016/j.jorganchem.2015.03.007⟩. ⟨hal-01224508⟩
  • Luis C. Misal Castro, Haoquan Li, Jean-Baptiste Sortais, Christophe Darcel. When iron met phosphines: a happy marriage for reduction catalysis.. Green Chemistry, Royal Society of Chemistry, 2015, 17 (4), pp.2283--2303. ⟨10.1039/C4GC01866D⟩. ⟨hal-01153434⟩
  • Thomas Dombray, C. Gunnar Werncke, Shi Jiang, Mary Grellier, Laure Vendier, et al.. Iron-Catalyzed C-H Borylation of Arenes.. Journal of the American Chemical Society, American Chemical Society, 2015, 137 (12), pp.4062-4065. ⟨10.1021/jacs.5b00895⟩. ⟨hal-01153417⟩
  • Saravanakumar Elangovan, Jean-Baptiste Sortais, Matthias Beller, Christophe Darcel. Iron-Catalyzed α-Alkylation of Ketones with Alcohols. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 54 (48), pp.14483-14486. ⟨10.1002/anie.201506698⟩. ⟨hal-01216296⟩
  • Saravanakumar Elangovan, Samuel Quintero-Duque, Vincent Dorcet, Thierry Roisnel, Lucie Norel, et al.. Knolker-Type Iron Complexes Bearing an N-Heterocyclic Carbene Ligand: Synthesis, Characterization, and Catalytic Dehydration of Primary Amides. Organometallics, American Chemical Society, 2015, 34 (18), pp.4521-4528. ⟨10.1021/acs.organomet.5b00553⟩. ⟨hal-01205446⟩
  • Linus P. Bheeter, Duo Wei, Vincent Dorcet, Thierry Roisnel, Prasenjit Ghosh, et al.. 1,2,4-Triazole-Based N-Heterocyclic Carb-ene Nickel Complexes - Synthesis and Catalytic Application. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, 2015 (31), pp.5226-5231. ⟨10.1002/ejic.201500852⟩. ⟨hal-01216291⟩
  • Jianxia Zheng, Christophe Darcel, Jean-Baptiste Sortais. Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by iron complexes.. Chemical Communications, Royal Society of Chemistry, 2014, 50 (91), pp.14229-32. ⟨10.1039/C4CC05517A⟩. ⟨hal-01114594⟩
  • Serpil Demir, Yasemin Gökçe, Thierry Roisnel, Jean-Baptiste Sortais, Christophe Darcel, et al.. Imidazolidinium ferrate complexes: Synthesis and catalytic properties. Comptes Rendus. Chimie, Académie des sciences (Paris), 2014, 17 (6), pp.541-548. ⟨10.1016/j.crci.2014.03.015⟩. ⟨hal-01121095⟩
  • Jianxia Zheng, Jean-Baptiste Sortais, Christophe Darcel. [(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes. ChemCatChem, Wiley, 2014, 6 (3), pp.763-766. ⟨10.1002/cctc.201301062⟩. ⟨hal-01114927⟩
  • Jianxia Zheng, Saravanakumar Elangovan, Dmitry A. Valyaev, Rémy Brousses, Vincent César, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2014, 356 (5), pp.1093-1097. ⟨10.1002/adsc.201300905⟩. ⟨hal-01114930⟩
  • Dharmendra Kumar, A. P. Prakasham, Linus P. Bheeter, Jean-Baptiste Sortais, Manoj Grangwar, et al.. Cationic Iron(II) Complexes of the Mixed Cyclopentadienyl (Cp) and the N-heterocyclic Carbene (NHC) Ligands as Effective Precatalysts for the Hydrosilylation of Carbonyl Compounds. Journal of Organometallic Chemistry, Elsevier, 2014, 762, pp.81-87. ⟨10.1016/j.jorganchem.2014.03.016⟩. ⟨hal-01121131⟩
  • Haoquan Li, Mathieu Achard, Christian Bruneau, Jean-Baptiste Sortais, Christophe Darcel. Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines. RSC Advances, Royal Society of Chemistry, 2014, 4 (49), pp.25892-25897. ⟨10.1039/C4RA04037F⟩. ⟨hal-01114838⟩
  • Thomas Dombray, Camille Helleu, Christophe Darcel, Jean-Baptiste Sortais. Cobalt Carbonyl-Based Catalyst for Hydrosilylation of Carboxamides. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2013, 355 (17), pp.3358-3362. ⟨10.1002/adsc.201300664⟩. ⟨hal-01089274⟩
  • Demir Serpil, Gökçe Yasemin, Nazan Kaloğlu, Jean-Baptiste Sortais, Christophe Darcel, et al.. Synthesis of new iron-NHC complexes as catalysts for hydrosilylation reactions. Applied Organometallic Chemistry, Wiley-Blackwell, 2013, 27, pp.459-464. ⟨10.1002/aoc.3006⟩. ⟨hal-01089236⟩
  • Bin Li, Jean-Baptiste Sortais, Christophe Darcel. Unexpected selectivity in ruthenium-catalyzed hydrosilylation of primary amides: synthesis of secondary amines.. Chemical Communications, Royal Society of Chemistry, 2013, 49 (35), pp.3691-3. ⟨10.1039/c3cc39149c⟩. ⟨hal-00879855⟩
  • Jean-Baptiste Sortais, Christophe Darcel. Chiral Cyclopentadienyl-type Ligands: a New Breakthrough for Asymmetric C[BOND]H Functionalisation. ChemCatChem, Wiley, 2013, 5 (5), pp.1067-1068. ⟨10.1002/cctc.201200874⟩. ⟨hal-00879852⟩
  • Jianxia Zheng, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Nickel-Catalyzed Reductive Amination with Hydrosilanes.. ChemCatChem, Wiley, 2013, 5, pp.2861--2864. ⟨10.1002/cctc.201300338⟩. ⟨hal-01069941⟩
  • Linus P. Bheeter, Mickael Henrion, Michael J. Chetcuti, Christophe Darcel, Vincent Ritleng, et al.. Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines.. Catalysis Science & Technology, Royal Society of Chemistry, 2013, 3, pp.3111--3116. ⟨10.1039/c3cy00514c⟩. ⟨hal-01069725⟩
  • Jianxia Zheng, Soizic Chevance, Christophe Darcel, Jean-Baptiste Sortais. Selective reduction of carboxylic acids to aldehydes through manganese catalysed hydrosilylation. Chemical Communications, Royal Society of Chemistry, 2013, 49, pp.10010-10012. ⟨10.1039/C3CC45349A⟩. ⟨hal-00870857⟩
  • Jianxia Zheng, Christophe Darcel, Jean-Baptiste Sortais. A convenient nickel-catalysed hydrosilylation of carbonyl derivatives.. Catalysis Science & Technology, Royal Society of Chemistry, 2013, 3 (1), pp.81-84. ⟨10.1039/c2cy20509b⟩. ⟨hal-00808945⟩
  • Haoquan Li, Luis C. Misal Castro, Jianxia Zheng, Thierry Roisnel, Vincent Dorcet, et al.. Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC-Iron Complexes.. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52, pp.8045--8049. ⟨10.1002/anie.201303003⟩. ⟨hal-01069952⟩
  • David Bezier, Jean-Baptiste Sortais, Christophe Darcel. N-Heterocyclic Carbene Ligands and Iron : An Effective Association for Catalysis.. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2013, 355 (1), pp.19-33. ⟨10.1002/adsc.201200666⟩. ⟨hal-00812031⟩
  • Vincent César, Luis C. Misal Castro, Thomas Dombray, Jean-Baptiste Sortais, Christophe Darcel, et al.. (Cyclopentadienyl)iron(II) complexes of N-heterocyclic carbenes bearing a malonate or imidate backbone: Synthesis, structure, and catalytic potential in hydrosilylation. Organometallics, American Chemical Society, 2013, 32 (16), pp.4643-4655. ⟨10.1021/om400625q⟩. ⟨hal-00993533⟩
  • Luis C Misal Castro, Haoquan Li, Jean-Baptiste Sortais, Christophe Darcel. Selective switchable iron-catalyzed hydrosilylation of carboxylic acids.. Chemical Communications, Royal Society of Chemistry, 2012, 48 (85), pp.10514-6. ⟨10.1039/c2cc35727e⟩. ⟨hal-00805237⟩
  • Linus P. Bheeter, Mickaël Henrion, Lydia Brelot, Christophe Darcel, Michael J. Chetcuti, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene-Nickel Hydride Complex under Mild Conditions. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2012, 354 (14-15), pp.2619-2624. ⟨10.1002/adsc.201200460⟩. ⟨hal-00864826⟩
  • Hassen Jaafar, Haoquan Li, Luis C Misal Castro, Jianxia Zheng, Thierry Roisnel, et al.. Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2012, 2012 (22), pp.3546-3550. ⟨10.1002/ejic.201200550⟩. ⟨hal-00868526⟩
  • David Bezier, Gopaladasu T. Venkanna, Luis C Misal Castro, Jianxia Zheng, Thierry Roisnel, et al.. Iron-Catalyzed Hydrosilylation of Esters. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2012, 354 (10), pp.1879-1884. ⟨10.1002/adsc.201200087⟩. ⟨hal-00868444⟩
  • Jianxia Zheng, Luis C Misal Castro, Thierry Roisnel, Christophe Darcel, Jean-Baptiste Sortais. Iron Piano-Stool Phosphine Complexes for Catalytic Hydrosilylation Reaction. Inorganica Chimica Acta, Elsevier, 2012, 380, pp.301-307. ⟨10.1016/j.ica.2011.10.048⟩. ⟨hal-00864821⟩
  • Luis C Misal Castro, Jean-Baptiste Sortais, Christophe Darcel. NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines.. Chemical Communications, Royal Society of Chemistry, 2012, 48 (1), pp.151-3. ⟨10.1039/c1cc14403k⟩. ⟨hal-00805367⟩
  • D. Bézier, F. Jiang, Thierry Roisnel, Jean-Baptiste Sortais, Christophe Darcel. Cyclopentadienyl-NHC Iron Complexes for Solvent Free Catalytic Hydrosilylation of Aldehydes and Ketones. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2012, 9, pp.1333-1337. ⟨10.1002/ejic.201100762⟩. ⟨hal-00698447⟩
  • Jean-Pierre Djukic, Jean-Baptiste Sortais, Laurent Barloy, Nicolas Pannetier, Claude Sirlin, et al.. Synthesis, Characterization, and Fluxional Behavior of a 34 Electron Homochiral Dimetallic Complex with an Unsupported Hydride Bridge between Two Ru Atoms. Organometallics, American Chemical Society, 2012, 31 (7), pp.2821-2828. ⟨10.1021/om201093y⟩. ⟨hal-00698475⟩
  • B. Li, Jean-Baptiste Sortais, Christophe Darcel, Pierre H. Dixneuf. Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts. ChemSusChem, ChemPubSoc Europe/Wiley, 2012, 5, pp.396-399. ⟨10.1002/cssc.201100585⟩. ⟨hal-00698460⟩
  • David Bezier, Gopaladasu T. Venkanna, Jean-Baptiste Sortais, Christophe Darcel. Well-Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles. ChemCatChem, Wiley, 2011, 3 (11), pp.1747-1750. ⟨10.1002/cctc.201100202⟩. ⟨hal-00877671⟩
  • Nicolas Pannetier, Jean-Baptiste Sortais, Jean-Thomas Issenhuth, Laurent Barloy, Claude Sirlin, et al.. Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2011, 353 (14-15), pp.2844-2852. ⟨10.1002/adsc.201100152⟩. ⟨hal-00877679⟩
  • Luis C. Misal Castro, David Bezier, Jean-Baptiste Sortais, Christophe Darcel. Iron Dihydride Complex as the Pre-catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2011, 353 (8), pp.1279-1284. ⟨10.1002/adsc.201000676⟩. ⟨hal-00632082⟩
  • Fan Jiang, David Bezier, Jean-Baptiste Sortais, Christophe Darcel. N-Heterocyclic Carbene Piano-Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2011, 353 (2-3), pp.239-244. ⟨10.1002/adsc.201000781⟩. ⟨hal-00632074⟩
  • Tanja Voss, Jean-Baptiste Sortais, Roland Fröhlich, Gerald Kehr, Gerhard Erker. Alkene Addition of Frustrated P/B and N/B Lewis Pairs at the [3]Ferrocenophane Framework. Organometallics, American Chemical Society, 2011, 30 (3), pp.584-594. ⟨10.1021/om100949k⟩. ⟨hal-00632086⟩
  • Chloé Vovard-Le Bray, Fan Jiang, Xiao-Feng Wu, Jean-Baptiste Sortais, Christophe Darcel. Cyclen-Catalyzed Henry Reaction under Neutral Conditions. Tetrahedron Letters, Elsevier, 2010, 51 (34), pp.4555-4557. ⟨10.1016/j.tetlet.2010.06.106⟩. ⟨hal-00576912⟩
  • K. Parkhomenko, L. Barloy, Jb Sortais, Jp Djukic, M. Pfeffer. Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions. Tetrahedron Letters, Elsevier, 2010, 51, pp.822-825. ⟨10.1016/j.tetlet.2009.12.011⟩. ⟨hal-00492655⟩
  • K. Parkhomenko, L. Barloy, Jb Sortais, Jp Djukic, M. Pfeffer. Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions. Tetrahedron Letters, Elsevier, 2010, 51, pp.822-825. ⟨10.1016/j.tetlet.2009.12.011⟩. ⟨hal-00497877⟩
  • J.P. Djukic, Jean-Baptiste Sortais, L. Barloy, M. Pfeffer. Cycloruthenated Compounds, Synthesis and Applications. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2009, pp.817-853. ⟨10.1002/ejic.200801016⟩. ⟨hal-00448519⟩
  • Jean-Baptiste Sortais, T. Voss, G. Kehr, R. Froehlich, G. Erker. 1,2-Olefin Q1 addition of a frustrated amine–borane Lewis pair. Chemical Communications, Royal Society of Chemistry, 2009, pp.7417-7418. ⟨10.1039/b915657g⟩. ⟨hal-00448526⟩
  • L. K. Thalén, D. Zhao, Jean-Baptiste Sortais, J. Paetzold, C. Hoben, et al.. A Chemoenzymatic Approach to Enantiomerically Pure Amines Using Dynamic Kinetic Resolution. Application to the Synthesis of NorSertraline. Chemistry - A European Journal, Wiley-VCH Verlag, 2009, 15, pp.3403-3410. ⟨10.1002/chin.200929067⟩. ⟨hal-00448515⟩
  • Nicolas Pannetier, Jean-Baptiste Sortais, Pape Sylla Dieng, Laurent Barloy, Claude Sirlin, et al.. Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer. Organometallics, American Chemical Society, 2008, 27 (22), pp.5852-5859. ⟨10.1021/om800420r⟩. ⟨hal-03639733⟩
  • Jean-Baptiste Sortais, Lydia Brelot, Michel Pfeffer, Laurent Barloy. μ 3 -Carbonato-κ 3 O : O ′: O ′′-tris{(η 6 -benzene)[( R )-1-(1-aminoethyl)naphthyl-κ 2 C 2 , N ]ruthenium(II)} hexafluoridophosphate dichloromethane solvate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], International Union of Crystallography, 2008, 64 (3), pp.m483-m484. ⟨10.1107/S1600536808003978⟩. ⟨hal-03639751⟩
  • Jean-Baptiste Sortais, Nicolas Pannetier, Alexandre Holuigue, Laurent Barloy, Claude Sirlin, et al.. Cyclometalation of Primary Benzyl Amines by Ruthenium(II), Rhodium(III), and Iridium(III) Complexes. Organometallics, American Chemical Society, 2007, 26 (8), pp.1856-1867. ⟨10.1021/om060973t⟩. ⟨hal-03639768⟩
  • Jean-Baptiste Sortais, Nicolas Pannetier, Nicolas Clément, Laurent Barloy, Claude Sirlin, et al.. Cyclometalation of Secondary Benzyl Amines by Ruthenium(II) Complexes. Organometallics, American Chemical Society, 2007, 26 (8), pp.1868-1874. ⟨10.1021/om060974l⟩. ⟨hal-03639782⟩
  • Grégory Malaisé, Jean-Baptiste Sortais, Laurent Barloy, Michel Pfeffer, Nathalie Kyritsakas. Nitrogen-containing xanthene-based chiral ligands: Synthesis, NMR and X-ray analyses, and catalytic applications of their palladium, silver and rhodium complexes. Polyhedron, Elsevier, 2006, 25 (17), pp.3349-3365. ⟨10.1016/j.poly.2006.06.006⟩. ⟨hal-03639820⟩
  • Jean-Baptiste Sortais, Laurent Barloy, Claude Sirlin, André de Vries, Johannes de Vries, et al.. Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction. Pure and Applied Chemistry, De Gruyter, 2006, 78 (2), pp.457-462. ⟨10.1351/pac200678020457⟩. ⟨hal-03639847⟩
  • Jean-Baptiste Sortais, Vincent Ritleng, Adeline Voelklin, Alexandre Holuigue, Hakima Smail, et al.. Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for Asymmetric Transfer Hydrogenation. Organic Letters, American Chemical Society, 2005, 7 (7), pp.1247-1250. ⟨10.1021/ol047353d⟩. ⟨hal-03639855⟩
  • David Inschauspe, Jean-Baptiste Sortais, Thierry Billard, Bernard Langlois. Trifluoromethanesulfinic Acid Derivatives as Nucleophilic Trifluoromethylating Reagents. SYNLETT, Georg Thieme Verlag, 2003, pp.0233-0235. ⟨10.1055/s-2003-36788⟩. ⟨hal-03639867⟩

Chapitres d'ouvrage

  • Jean-Baptiste Sortais, Ruqaya Buhaibeh, Yves Canac. Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions. Jean-Baptiste Sortais. Manganese Catalysis in Organic Synthesis, Wiley-VCH, pp.39-66, 2021, 978-3-527-34730-8. ⟨10.1002/9783527826131.ch2⟩. ⟨hal-03376666⟩
  • Christophe Darcel, Jean-Baptiste Sortais. Iron-Catalyzed Reduction and Hydroelementation Reactions. Bauer, Eike. Iron Catalysis II, Springer International Publishing, pp.173--216, 2015, Topics in Organometallic Chemistry, 978-3-319-19395-3 978-3-319-19396-0. ⟨10.1007/3418_2015_104⟩. ⟨hal-01278353⟩
  • Christophe Darcel, Jean-Baptiste Sortais, Samuel Quintero Duque. Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions (chap. 4). Chao-Jun Li (ed.). From C-H to C-C Bonds : Cross-Dehydrogenative-Coupling, Royal Society of Chemistry, pp.67-92, 2015, 978-1-84973-797-5. ⟨10.1039/9781782620082-00067⟩. ⟨hal-01114926⟩

Directions d'ouvrage, Proceedings


Adresse

Laboratoire de chimie de coordination du CNRS

205 route de Narbonne, BP 44099
31077 Toulouse cedex 4
France