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Rinaldo POLI


Rinaldo POLI

Équipe G


+33 (0)5 61 33 31 73

Numéro ORCID : 0000-0002-5220-2515

MS, Università di Pisa, Italy, 4/1981.
PhD, Chemistry, Scuola Normale Superiore, Pisa, Italy, 9/1985.

Professional Experience
Exchange Ph.D. student, Imperial College of Science and Technology, London, 1983–84.
Research Associate, Texas A&M University, 1985–87.
University of Maryland, College Park (1987–96).
Université de Bourgogne, Dijon (1996–2005).
INP-ENSIACET, Toulouse (2005–present).

Domaines d’expertise – projets en cours

  • Effects of the spin state in organometallic reactivity;
  • Hydrides and dihydrogen complexes;
  • Controlled radical polymerization;
  • High oxidation state aqueous organometallic chemistry and oxidation catalysis;
  • Homogeneous catalysis: intermolecular hydroamination of non-activated olefins;
  • Chiral ligands, their coordination chemistry and catalytic applications;
  • Biphasic catalysis with polymeric nanoreactors.

Production scientifique

Research Articles in Refereed Journals


  1. Calderazzo*, D. Vitali, R. Poli, J. L. Atwood*, R. D. Rogers, J. M. Cummings, I. Bernal: “Studies on Organometallic Hetero-multiple-bridged Molecules. Part 7.  Synthesis and Properties of Dichalcogenide-bridged Complexes of Rhenium(I) and the Crystal and Molecular Structure of the Diphenylditelluride-bridged complex, Re2Br2(CO)6Te2Ph2“, J. Chem. Soc., Dalton Trans., 1981, 1004-1009. DOI: 10.1039/DT9810001004.
  2. Calderazzo*, F. Marchetti, R. Poli, D. Vitali, P. F. Zanazzi: “Synthesis and Molecular Structure of Mixed-valence Compounds of Rhenium Obtained by Di-iodine Oxidation of Rhenium(I) Carbonyl Complexes; X-ray Crystal Structure of Re3I6(CO)6“, J. Chem. Soc., Chem. Comm., 1981, 893-894. DOI: 10.1039/C39810000893.
  3. Calderazzo*, F. Marchetti, R. Poli, D. Vitali, P. F. Zanazzi: “Synthesis and Crystal and Molecular Structure of Mixed-valence Tetranuclear and Trinuclear Compounds of Rhenium Obtained by Di-iodine Oxidation of Rhenium(I) Carbonyl Complexes”, J. Chem. Soc., Dalton Trans., 1982, 1665-1670. DOI: 10.1039/DT9820001665.
  4. Calderazzo*, A. Morvillo, G. Pelizzi, R. Poli: “Synthesis and Crystal and Molecular Structure of Tetraphenyldibismuthine, Bi2Ph4, the First Crystallographically Characterized Tetraorganyl of Bismuth(II)”, J. Chem. Soc., Chem. Comm., 1983, 507-508. DOI: 10.1039/C39830000507.
  5. L. Atwood*, I. Bernal, F. Calderazzo*, L. G. Canada, R. Poli, R. D. Rogers, C. A. Veracini, D. Vitali: “Studies on Organometallic Hetero-multiple-bridged Molecules. VIII. Preparation and Crystal and Molecular Structure of Diphenyldichalcogenide Complexes of Manganese(I). Kinetic, Spectroscopic and Equilibrium Data: a Quantitative Assessment of the Solid-state and Solution Properties within Members of Homogeneous Families of Chalcogenide Low-valent Metal Complexes”, Inorg. Chem., 1983, 22, 1797-1804. DOI: 10.1021/ic00154a021.
  6. Calderazzo*, R. Poli, D. Vitali, J. D. Korp, I. Bernal, G. Pelizzi, J. L. Atwood, W. E. Hunter: “Studies on Organometallic Hetero-multiple-bridged Molecules. IX. Synthesis and Crystal and Molecular Structure of Mn2X2(CO)6P2Ph4 (X = Br, I) and Mn2Br2(CO)6As2Ph4, the Products Arising from Co-ordinative Addition of P2Ph4 and As2Ph4 to Manganese(I)”, Gazz. Chim. Ital., 1983, 113, 761-771.
  7. Calderazzo*, R. Poli, A. Barbati, P. F. Zanazzi: “Synthesis, Reactivity, and Structures of Cationic h6-Arene Carbonyl Complexes of Rhenium(I). Crystal and Molecular Structure of the Two Isoelectronic 1,3,5-Trimethylbenzene Tricarbonyl Complexes of Rhenium(I) and Tungsten(0)”, J. Chem. Soc., Dalton Trans., 1984, 1059-1064. DOI: 10.1039/DT9840001059.
  8. Bernal*, J. D. Korp, F. Calderazzo*, R. Poli, D. Vitali: “Hexacarbonyl Complexes of Dirhenium(I) Containing E2Ph4 (E = P, As, Sb) as Ligands”, J. Chem. Soc., Dalton Trans., 1984, 1945-1950. DOI: 10.1039/DT9840001945.
  9. Calderazzo*, R. Poli, G. Pelizzi: “Synthesis, Reactivity and Crystal and Molecular Structure of Tetraphenyldibismuthine, Bi2Ph4“, J. Chem. Soc., Dalton Trans., 1984, 2365-2369. DOI: 10.1039/DT9840002365.
  10. Calderazzo*, R. Poli, G. Pelizzi: “Reactions of Octacarbonyldicobalt with Tetraphenyl Derivatives of Group VA, Including Tetraphenyldibismuthine. Synthesis and Molecular Structure of Tricarbonyl(Diphenylbismuthido)(Triphenylphosphine)-cobalt(I), Co(BiPh2)(CO)3(PPh3)”, J. Chem. Soc., Dalton Trans., 1984, 2535-2540. DOI: 10.1039/DT9840002535.
  11. Calderazzo*, R. Poli, D. Vitali: “Bis(halotetracarbonylmanganese-(I))”, Inorg. Synth., 1985, 23, 32-34. DOI: 10.1002/9780470132548.ch8.
  12. Poli, G. Wilkinson*, M. Motevalli, M. B. Hursthouse: “Reaction of Transition Metal Carbonylate Anions and 1,1,1-Tris(halomethyl)-ethane. X-ray Crystal Structures of h5-Cyclopentadienyltricarbonyl-1-methylcyclopropylmethyltungsten(II), and Tetraethyl­am­mo­nium Iodoennacarbonyldirhenate(0)”, J. Chem. Soc., Dalton Trans., 1985, 931-939. DOI: 10.1039/DT9850000931.
  13. Calderazzo*, R. Poli: “Reduction of Ammonium Perrhenate by CO: a Convenient Method for Preparing Re2(CO)10“, Gazz. Chim. Ital., 1985, 115, 573-574.
  14. A. Cotton*, R. Poli: “Decarbonylation of Mo(II) Carbonyl Complexes: a New Route to Quadruply Bonded Mo(II) Dimers”, J. Am. Chem. Soc., 1986, 108, 5628-5629. DOI: 10.1021/ja00278a046.
  15. A. Cotton*, R. Poli: “The Thermal Reaction of Mo2I4(CO)8 with PMe2Ph, PEt2Ph and Pyridine. Formation of Metal-metal Quadruple Bonds vs. Disproportionation.  X-ray Crystal Structures of MoI3(PMe2Ph)2(POMe2Ph) and [PHEt2Ph][MoI4(PEt2Ph)2]”, Inorg. Chem., 1986, 25, 3624-3629. DOI: 10.1021/ic00240a019.
  16. A. Cotton*, K. R. Dunbar, R. Poli: “Synthesis and Molecular Structure of Mo2I4(dppm)2.2C7H8“, Inorg. Chem., 1986, 25, 3700-3703. DOI: 10.1021/ic00240a037.
  17. A. Cotton*, R. Poli: “The Products of the Reaction Between Mo2I4(CO)8 and bis(dimethylphosphino)methane. X-ray Crystal Structure of MoI2(CO)(dmpm)2“, Inorg. Chem., 1986, 25, 3703-3705. DOI: 10.1021/ic00240a038.
  18. Barbati, F. Calderazzo*, R. Poli, P. F. Zanazzi: “Di-iodine Oxidation of Molybdenum(0) h6-arene Complexes. New Results on Molybdenum(II) Carbonyl Derivatives:  Crystal Structures of [MI(CO)3(h6-C6H3Me3-1,3,5)][M2I5(CO)6] (M = Mo or W) and [MoI(CO)3(h6-C6Me6)][MoI3(CO)4]”, J. Chem. Soc., Dalton Trans., 1986, 2569-2579. DOI: 10.1039/DT9860002569.
  19. A. Cotton*, R. Poli: “Iridium(I) Dimers with Bridging N,N’-di-p-tolylformamidine. X-ray Molecular Structure of Ir2(µ-p-CH3C6H4NCHN-p-C6H4CH3)(µ-NH-p-C6H4CH3)(C8H12)2“, Inorg. Chim. Acta, 1986, 122, 243-248. DOI: 10.1016/S0020-1693(00)81646-1.
  20. A. Cotton*, R. Poli: “N,N’-di-p-tolylformamidinato Bridged Mixed-valence Ir(I)-Ir(III) Dimers Containing a Metal-metal Dative Bond. Synthesis, Molecular Structure and Physico-chemical Properties”, Inorg. Chem., 1987, 26, 590-595. DOI: 10.1021/ic00251a020.
  21. A. Cotton*, M. Matusz, R. Poli: “Synthesis, Structure and Physico-chemical Properties of M2(form)4 (M = Ni, Pd; form = N,N’-di-p-tolylformamidine). Attempts to generate a Pd(III) Dimer”, Inorg. Chem., 1987, 26, 1472-1474. DOI: 10.1021/ic00257a003.
  22. A. Cotton*, R. Poli: “Low-valent Molybdenum Carbonyl Complexes as an Entry to Octahedral MoI3L3 Complexes. Synthesis and X-ray Molecular Structure of MoI3(THF)3“, Inorg. Chem., 1987, 26, 1514-1518. DOI: 10.1021/ic00257a011.
  23. A. Cotton*, L. R. Falvello, R. Poli: “Reactions Between W2I4(CO)8 and Phosphines under Forcing Conditions: Attempted Decarbonylation to Tungsten(II) Dimers with Quadruple Metal-metal Bond. X-ray Molecular Structure of WI2(CO)(dppm)2“, Polyhedron, 1987, 6, 1135-1142. DOI: 10.1016/S0277-5387(00)80967-5.
  24. A. Cotton*, R. Poli: “Synthesis and Molecular Structure of the First Inorganic Quadruply-bridged Ir(II) Dimer (Ir-Ir)”, Polyhedron, 1987, 6, 1625-1628. DOI: 10.1016/S0277-5387(00)80851-7.
  25. A. Cotton*, R. Poli: “Ortho-metalation of Pyridine at a Diiridium Center. Synthesis and Spectroscopic and Crystallographic Characterization of NC5H4– and N,N’-di-p-tolylformamidinato-bridged Complexes of Diiridium(II,II)”, Organometallics, 1987, 6, 1743-1751. DOI: 10.1021/om00151a021.
  26. A. Cotton*, R. Poli: “Synthesis of Mo2X4(PMe3)4 (Mo-Mo) (X = Cl, Br, I) Compounds by Decarbonylation of Mo2X4(CO)8 and by Conproportionation of Mo(CO)6 and MoX3(PMe3)3. X-ray Crystal Structure of Mo2I4(PMe3)4.2THF”, Inorg. Chem., 1987, 26, 3228-3231. DOI: 10.1021/ic00266a035.
  27. A. Cotton*, R. Poli: “Synthesis, Solid-state and Solution Structure, and Physico-chemical Properties of the Iodide-bridged Face-sharing Bioctahedral Molybdenum(III) Dimers, [Cat]+[Mo2I7(PMe3)2] (Cat = PHMe3, NMe4, AsPh4)”, Inorg. Chem., 1987, 26, 3310-3315. DOI: 10.1021/ic00267a019.
  28. A. Cotton*, R. Poli: “Synthesis and Molecular Structure of a Dinuclear Quadruply-bridged Cobalt(II) Compound with a Short Metal-metal Bond, Co2[(p-CH3C6H4)NNN(p-C6H4CH3)]4“, Inorg. Chem., 1987, 26, 3652-3653. DOI: 10.1021/ic00269a006.
  29. A. Cotton*, R. Poli: “Oxygen Abstraction from Tetrahydrofuran by Molybdenum-iodide Complexes. X-ray Molecular Structure of [Mo2(µ-O)(µ-I)(µ-O2CCH3)­I2(THF)4][MoOI4(THF)] (THF = Tetrahydrofuran)”, Polyhedron, 1987, 6, 2181-2186. DOI: 10.1016/S0277-5387(00)84284-9.
  30. A. Cotton*, R. Poli*: “The Thermal Decarbonylation of Molybdenum(II) Carbonyl-iodide Complexes. Molecular and Electronic Structures of the Mixed-valence Trinuclear Clusters, Mo3HI7L3 (L = Tetrahydrofuran, Acetonitrile, Benzonitrile), and Molecular Structure of MoI3(MeCN)3 and Mo2I4(PhCN)4“, J. Am. Chem. Soc. 1988, 110, 830-841. DOI: 10.1021/ja00211a023.
  31. A. Cotton*, X. Feng, M. Matusz, R. Poli: “Dinuclear Formamidinato Complexes of Nickel and Palladium”, J. Am. Chem. Soc., 1988, 110, 1144-1154. DOI: 10.1021/ja00212a024.
  32. A. Cotton*, R. Poli: “Vanadium(II)- and Vanadium(III)-formamidinato Compounds. Synthesis and Molecular Structure of V(form)2(NC5H5)2 and V(h5-C5H5)(form)2 (form = N,N’-di-p-tolylformamidine)”, Inorg. Chim. Acta 1988, 141, 91-98. DOI: 10.1016/S0020-1693(00)86381-1.
  33. Calderazzo*, R. Poli, P. F. Zanazzi: “Oxidation of h6-arene Complexes of Group VI Metals. Part 2. A Convenient Preparation of Mo2I4(CO)8, its Reactivity and its Crystal and Molecular Structure”, Gazz. Chim. Ital., 1988, 118, 583-587.
  34. Barbati, F. Calderazzo*, R. Poli: “Oxidation of h6-arene Complexes of Group VI Metals. Part 3. Di-iodide Catalyzed Carbonylation of Molybdenum(0)-h6-arene Complexes to Mo(CO)6 and Experimental Evidence of an Inner-sphere Electron Transfer Reaction Between Centers of Molybdenum(II) and Molybdenum(0)”, Gazz. Chim. Ital., 1988, 118, 589-594.
  35. Calderazzo*, R. Poli, P. F. Zanazzi: “Oxidation of h6-arene Complexes of Group VI Metals. Part 4. Molybdenum(II)-arene-carbonyl Compounds Containing Polyiodides”, Gazz. Chim. Ital., 1988, 118, 595-601.
  36. A. Cotton*, X. Feng, M. Matusz, R. Poli: “Experimental and Theoretical Studies of the Copper(I) and Silver(I) Dinuclear 1,3-Di(p-tolyl)formamidinato Complexes”, J. Am. Chem. Soc., 1988, 110, 7077-7083. DOI: 10.1021/ja00229a021.
  37. Calderazzo*, A. Morvillo, G. Pelizzi, R. Poli, F. Ungari: “Reactivity of Molecules Containing Element-element Bonds. 1. Non-transition Elements”, Inorg. Chem., 1988, 27, 3730-3733. DOI: 10.1021/ic00294a012.
  38. E. Owens, R. Poli*: “Synthesis, Structure and Properties of Mononuclear and Dinuclear Molybdenum(III)-Bromide Compounds. Ligand-induced, Reversible Breakage of a Metal-metal Bond in Mo2Br6(dppe)2“, Polyhedron, 1989, 8, 545-548. DOI: 10.1016/S0277-5387(00)80756-1.
  39. E. Owens, R. Poli*, A. L. Rheingold: “Conformational Preferences in Six-Coordinate, Octahedral Complexes of Molybdenum(III). Synthesis and Structure of MoX3(dppe)L [X = Cl, Br, I; dppe = Bis(diphenylphosphino)ethane; L = Tetrahydrofuran (THF), Acetonitrile, Trimethylphosphine]”, Inorg. Chem., 1989, 28, 1456-1462. DOI: 10.1021/ic00307a008.
  40. D. Walker, R. Poli*: “FeCl3-Phosphine Adducts With Trigonal Bipyramidal Geometry. Influence of the Phosphine on the Spin State”, Inorg. Chem., 1989, 28, 1793-1801. DOI: 10.1021/ic00309a008.
  41. D. Walker, R. Poli*: “The Interaction of FeCl3 and PPh3 in Chloroform. X-ray Crystal Structure of [Ph3PCH2PPh3][FeCl4]2“, Polyhedron, 1989, 8, 1293-1297. DOI: 10.1016/S0277-5387(00)86526-2.
  42. D. Mui, R. Poli*: “Preparation and Structure of the Dimolybdenum(III) Compound, Mo2Cl6(PEt3)4. An Anomaly in Metal-metal Bonded Edge-sharing Bioctahedral Compounds”, Inorg. Chem., 1989, 28, 3609-3612. DOI: 10.1021/ic00317a045.
  43. Calderazzo*, U. Mazzi, G. Pampaloni, R. Poli, F. Tisato, P. F. Zanazzi: “Reduction of Ammonium Pertechnetate and Ammonium Perrhenate by CO: Synthesis of M2(CO)10 (M = Tc, Re) and Crystal and Molecular Structure of the Trinuclear Cyano-bridged Derivative, Re3(CN)3(CO)12, Gazz. Chim. Ital., 1989, 119, 241-247.
  44. T. Krueger, R. Poli*, A. L. Rheingold, D. L. Staley: “Synthesis, Molecular and Electronic Structure, and Properties of Mononuclear Cyclopentadienyl Derivatives of Molybdenum(III) and Molybdenum(IV). Direct Evidence for Mo(III)-P p back-bonding”, Inorg. Chem., 1989, 28, 4599-4607. DOI: 10.1021/ic00325a013.
  45. D. Walker, R. Poli*: “Iron trichloride – Phosphine Adducts with Tetrahedral Geometry and Their Reaction with Ethanol. Structure and Magnetic Properties of [PH(t-Bu)3]2[Fe2(µ-OEt)2Cl6].”, Inorg. Chem., 1990, 29, 756-761. DOI: 10.1021/ic00329a037.
  46. Poli*, H. D. Mui: “True Nature of Trihalotris(tetrahydrofuran)molybdenum(III), MoX3(THF)3 (X = Cl, Br, I). A Paramagnetic 1H-NMR Study”, J. Am. Chem. Soc., 1990, 112, 2446-2448. DOI: 10.1021/ja00162a070.
  47. Poli*, A. L. Rheingold: “The Unusual Structure of the Novel [Mo2Cp2Cl5] Ion”, J. Chem. Soc., Chem. Comm., 1990, 552-554. DOI: 10.1039/C39900000552.
  48. T. Krueger, B. E. Owens, R. Poli*: “Syntheses and Properties of Paramagnetic Monocyclopentadienylmolybdenum(III) Compounds with Four-legged Piano-stool Structure Containing the Bidentate Bis(diphenylphosphino)ethane Ligands. “, Inorg. Chem., 1990, 29, 2001-2006. DOI: 10.1021/ic00335a045.
  49. Poli*: “Distortions in the ‘Legs’ of Four-legged Piano Stool Structures”, Organometallics, 1990, 9, 1892-1900. DOI: 10.1021/om00156a032.
  50. Poli* H. D. Mui: “Mononuclear Octahedral and Dinuclear Edge-sharing and Face-sharing Bioctahedral Compounds of Molybdenum(III). Electronic Control on the Extent of Metal-metal Interaction in the Dinuclear Systems.  An Equilibrium, Structural, and Paramagnetic NMR Study”, Inorg. Chem., 1991, 30, 65-77. DOI: 10.1021/ic00001a014.
  51. E. Owens, R. Poli*: “Attempts to Prepare the 17-electron Mo(h5-C5H5)X2(dmpe) [X = Cl, Br, I; dmpe = Bis(dimethylphosphino)ethane] Compounds. Formation and X-ray Molecular Structure of (h5-C5H5)MoCl3(dmpe) and [(h5-C5H5)Mo(dmpe)2][MoBr4(dppe)] [dppe = Bis(diphenylphosphino)ethane]”, Inorg. Chim. Acta, 1991, 179, 229-237. DOI: 10.1016/S0020-1693(00)85882-X.
  52. Calderazzo*, A. Juris, R. Poli, F. Ungari: “Reactivity of Molecules Containing Element-element Bonds. 2. Transition Elements.”, Inorg. Chem., 1991, 30, 1274-1279. DOI: 10.1021/ic00006a022.
  53. G. Linck, B. E. Owens, R. Poli*, A. L. Rheingold: “Synthesis and Crystal Structure of MoCpICl(PMe3)2 (Cp = h5-C5H5) and Equilibrium of Disproportionation to MoCpCl2(PMe3)2 and MoCpI2(PMe3)2“, Gazz. Chim. Ital., 1991, 121, 163-168.
  54. Poli*: “Monocyclopentadienyl Halide Complexes of the d- and f- Block Elements”, Chem. Rev., 1991, 91, 509-551. DOI: 10.1021/cr00004a004.
  55. Poli*, S. T. Krueger, F. Abugideiri, B. S. Haggerty, A. L. Rheingold: “Reactions of CpMoCl2L2 (Cp = h5-C5H5, L = Phosphine) with Methyllithium. Preparation and Structure of a Mo(II) Compound Containing an Ortho-metalated PMe2Ph Ligand, CpMo(o-C6H4PMe2)(PMe2Ph)2“, Organometallics 1991, 10, 3041-3046. DOI: 10.1021/om00055a015.
  56. C. Gordon, H. D. Mui and R. Poli*, K. J. Ahmed: “Synthesis, Structure, and Properties of the Face-sharing Bioctahedral Mo2X6(PMe2Ph)3 (X = Br, I) Compounds”, Polyhedron, 1991, 10, 1667-1674. DOI: 10.1016/S0277-5387(00)83780-8.
  57. Calderazzo*, R. Poli*, P. F. Zanazzi: “A Mixed-valence Tetranuclear Rhenium Cluster with Re(I)-Re(III) Dative Bonds”, Inorg. Chem. 1991, 30, 3942-3947. DOI: 10.1021/ic00020a030.
  58. Poli*, B. E. Owens: “Synthesis and Structure of Bis[1,2-bis(diphenylphosphino)ethane]­hexahalodimolybdenum(III), Mo2X6(dppe)2 (X = Cl, Br, I)”, Gazz. Chim. Ital. 1991, 121, 413-417.
  59. Poli*, J. C. Gordon, J. U. Desai, A. L. Rheingold: “Formation and Structure of a Quadruply-Iodo-Bridged Complex of Dimolybdenum(III,IV), [(Cp*Mo)2(µ-I)4]I3 (Cp* = h5-C5Me5) and Its Reversible Oxidation and Reduction.”, J. Chem. Soc., Chem. Comm. 1991, 1518-1520. DOI: 10.1039/C39910001518.
  60. Poli*, J. C. Gordon: “1H-NMR Investigation of the Tetrahydrofuran Replacement by Phosphine Ligands on MoCl3(THF)3. A Trans Effect”, Inorg. Chem. 1991, 30, 4550-4554. DOI: 10.1021/ic00024a017.
  61. Poli*, M. A. Kelland: “Synthesis, Characterization, and Reactivity of Cyclopentadienyltrichloro-molybdenum(IV). X-ray Structure of CpMoCl3­[P(OCH2)3CEt]2 (Cp = h5-C5H5)”, J. Organometal. Chem. 1991, 419, 127-136. DOI: 10.1016/0022-328X(91)86169-Q.
  62. Poli* “Let’s Not Forget About Electronic Correlation”, Comments Inorg. Chem. 1992, 12, 285-314. DOI: 10.1080/02603599208055167.
  63. Poli*, B. E. Owens, R. G. Linck: “Kinetic Investigation of the Halide Substitution Reaction on the 17-electron MoCpX2(PMe3)2 System”, Inorg. Chem. 1992, 31, 662-667. DOI: 10.1021/ic00030a026.
  64. Poli*, B. E. Owens, R. G. Linck: “The First Electron Transfer Catalyzed Ligand Substitution Reaction which Occurs by Transforming an Odd-electron system into an Even-electron One”, J. Am. Chem. Soc. 1992, 114, 1302-1307. DOI: 10.1021/ja00030a027.
  65. Abugideiri, M. A. Kelland, R. Poli*, A. L. Rheingold: “Four-legged Piano Stool Molybdenum(II) Compounds Without Carbonyl Ligands. 1.  Synthesis, Properties, and Chloride Substitution Reactions of (h5-C5R5)MoCl(PMe3)3 (R = H, Me), and X-ray Crystal Structure of [CpMoCl(PMe3)3]+PF6“, Organometallics 1992, 11, 1303-1311. DOI: 10.1021/om00039a040.
  66. Abugideiri, M. A. Kelland, R. Poli*: “Four-legged Piano Stool Molybdenum(II) Compounds Without Carbonyl Ligands. 2.  Reactions of (h5-C5R5)MoCl(PMe3)3 (R = H, Me) With Neutral Donors”, Organometallics 1992, 11, 1311-1318. DOI: 10.1021/om00039a040.
  67. Cole, J. C. Gordon, M. A. Kelland, R. Poli*, A. L. Rheingold: “Synthesis and Structure of the Trimolybdenum Cluster [(CpMoCl)3(µ-Cl)43-O)]”, Organometallics 1992, 11, 1754-1757. DOI: 10.1021/om00040a055.
  68. Poli*, J. C. Gordon, R. J. Khanna, P. Fanwick: “The First Discrete Structure for the I7 Ion”, Inorg. Chem. 1992, 31, 3165-3167. DOI: 10.1021/ic00040a032.
  69. Poli*, J. C. Gordon: “The Question of Metal-Metal Bonding in Edge-Sharing Bioctahedral Mo(III) Complexes. Variable Temperature 1H-NMR Study of Mo2Cl6(PMexEt3-x)4 (x = 0-3) and the Mechanism of the Face-Sharing to Edge-Sharing Transformation”, J. Am. Chem. Soc. 1992, 114, 6723-6734. DOI: 10.1021/ja00043a017.
  70. Poli*, B. E. Owens, S. T. Krueger, A. L. Rheingold: “17-Electron Four-legged Piano Stool CpMoX2L2 Complexes (X = Halogen; L = Tertiary Phosphine). EPR Evidence for the Existence of a Second Isomer in Solution”, Polyhedron 1992, 11, 2301-2312.  DOI: 10.1016/10.1016/S0277-5387(00)83516-0.
  71. Poli*, S. P. Mattamana, L. R. Falvello: “Formation and Structure of Bis(diphenylphosphino)ethanebis(indenyl)molybdenum(II), a Compound with One Eta-3 and One Eta-5 Indenyl Ligand”, Gazz. Chim. Ital. 1992, 122, 315-319. (invited contribution, special issue dedicated to the 80th birthday of Prof. Lamberto Malatesta)
  72. E. Owens, R. Poli*: “Structures of Two Molybdenum Oxo Complexes: MoOCl3(OPPh3)2 and [MoOI(dmpe)2]I “, Acta Cryst., Sect. C. 1992, C48, 2137-2140. DOI: 10.1107/S010827019200475X.
  73. Poli*, A. L. Rheingold, B. E. Owens-Waltermire: “The Structure of Two Analogous 16-electron Piano Stool Molybdenum(IV) Complexes, [YMoI2(PMe3)2]+ (Y = Cp, Cp*)”, Inorg. Chim. Acta 1993, 203, 223-227. DOI: 10.1016/S0020-1693(00)81661-8.
  74. Abugideiri, J. C. Gordon, R. Poli*, B. E. Owens-Waltermire, A. L. Rheingold: “New Phosphine-Containing Cyclopentadienylmolybdenum(IV) Complexes with a 18- and a 16-Electron Count. X-ray Structure of CpMoCl3(PMe2Ph)2 and Cp*MoCl3L (L = PMe3, PMe2Ph)”, Organometallics 1993, 12, 1575-1582. DOI: 10.1021/om00029a015.
  75. Abugideiri, M. A. Kelland, R. Poli*: “Cp*MoH5(PMe3): a Classical Polyhydride with a Pentagonal Bipyramidal Structure and a Long T1 Relaxation Time”, Organometallics 1993, 12, 2388-2389. DOI: 10.1021/om00030a060.
  76. Poli*: “Monocyclopentadienylmolybdenum(III) Chemistry”, J. Coord. Chem. B. 1993, 29, 121-173. DOI: 10.1080/00958979308037131.
  77. C. Gordon, V. T. Lee, R Poli*: “Preparation of CpMoX3 (Cp = h5-C5H5; X = Cl, Br, I) by Thermal Decarbonylation of CpMoX3(CO)2, a Previously Overlooked Phenomenon”, Inorg. Chem. 1993, 32, 4460-4463. DOI: 10.1021/ic00072a047.
  78. U. Desai, J. C. Gordon, H.-B. Kraatz, B. E. Owens-Waltermire, R. Poli*, A. L. Rheingold: “The Redox Behavior of Cp*Mo-Bromide Systems: The Unusual Structure of a Compound Containing Mo(III), Mo(IV) and Mo(V), [Cp*2Mo2Br4]2[Cp*MoBr4]3“, Angew. Chem. 1993, 105, 1506-1508; Angew. Chem., Int. Ed. Engl. 1993, 32, 1486-1488. DOI: 10.1002/anie.199314861.
  79. Poli*, R. C. Torralba: “Further Considerations on the Structure and Bonding of Edge-Sharing Bioctahedral Complexes”, Inorg. Chim. Acta 1993, 212, 123-134. DOI: 10.1016/S0020-1693(00)92317-X (invited contribution, special topical volume on Metal-Metal Bonds/Clusters/Polynuclear Metal Complexes).
  80. A. Herrmann*, S. Bogdanovic, R. Poli, T. Priermeier: “Nitridotris(neopentyl)molybdenum(VI)”, J. Am. Chem. Soc. 1994, 116, 4989-4990. DOI: 10.1021/ja00090a055.
  81. -B. Kraatz, R. Poli*: “Cp*Mo-Halide Chemistry. Rapid Halide Scrambling During the Conproportionation of Cp*2Mo2Y4 (Y = Cl, Br, I) and Cp*MoX4 (X = Cl, Br): A Paramagnetic 1H-NMR Study”, J. Organomet. Chem. 1994, 475, 167-175. DOI: 10.1016/0022-328X(94)84019-9 (invited contribution, Proceedings of the first JOC Conference in honor of Prof. E. O. Fischer’s 75th birthday).
  82. Abugideiri, G. A. Brewer, J. U. Desai, J. C. Gordon, R. Poli*: “Pentamethylcyclopentadienylmolybdenum(IV) Chloride. Synthesis, Structure, and Properties”, Inorg. Chem. 1994, 33, 3745-3751. DOI: 10.1021/ic00095a018.
  83. U. Desai, J. C. Gordon, H.-B. Kraatz, V. T. Lee, B. E. Owens-Waltermire, R. Poli*, A. L. Rheingold, C. B. White: “Pentamethylcyclopentadienylmolybdenum Bromides and Iodides”, Inorg. Chem. 1994, 33, 3752-3769. DOI: 10.1021/ic00095a019.
  84. Abugideiri, D. W. Keogh and R. Poli*: “Stable 16-electron, Paramagnetic Cyclopentadienylmolybenum(II) Complexes”, J. Chem. Soc., Chem. Comm. 1994, 2317-2318. DOI: 10.1039/C39940002317.
  85. A. Herrmann*, S. Bogdanovic, T. Priermeier, R. Poli*, J. C. Fettinger: “Aggregation of Metal Nitrides: the Case of (h5-C5Me5)Mo(N)Cl2“, Angew. Chem. 1995, 107, 63-66; Angew. Chem., Int. Ed. Engl. 1995, 34, 112-115. DOI: 10.1002/anie.199501121.
  86. C. Gordon, R. Poli*: “A Tetranuclear Butterfly Cluster of Molybdenum, [PPh4]2[Mo4I11]”, Acta Crystallogr., Sect. C, 1995, C51, 14-18. DOI: 10.1107/S0108270194004877.
  87. P. Mattamana, R. Poli*: “Preparation of cis-[MoI4(Ph2PCH2CH2PPh2)] and Structure of (THF)3Na(µ-I)3MoI(Ph2PCH2CH2PPh2) with a New Coordination Environment around Sodium”, Inorg. Chim. Acta 1995, 229, 55-60. DOI: 10.1016/0020-1693(94)04226-L (invited contribution, special volume dedicated to Prof. F. A. Cotton’s 65th birthday)
  88. Abugideiri, J. C. Fettinger, R. Poli*: “Metal-Metal Bonding in Pentamethyl­cyclopenta­dienylmolybdenum(IV) Dinuclear Compounds: Chloride Abstraction from Nonbonded Cp*2Mo2Cl6 to Afford Bonded [Cp*2Mo2Cl5]+“, Inorg. Chim. Acta 1995, 229, 445-454. DOI: 10.1016/0020-1693(94)04279-5 (invited contribution, special volume dedicated to Prof. F. A. Cotton’s 65th birthday).
  89. Abugideiri, D. W. Keogh, H.-B. Kraatz, R. Poli*, W. Pearson: “Instability of 15-electron Cp*MoCl2L (L = 2-Electron Donor) Derivatives. X-Ray Structure of Cp*MoCl2(PMe2Ph)2 and [Cp*MoCl2(PMe2Ph)2]AlCl4“, J. Organometal. Chem. 1995, 488, 29-38. DOI: 10.1016/0022-328X(94)00005-W (invited contribution, special volume dedicated to Prof. Fausto Calderazzo’s 65th birthday).
  90. C. Fettinger, D. W. Keogh, R. Poli*: “Cyclopentadienylniobium(V) Phosphine chemistry: Adduct Formation vs Reduction.  X-ray Structure of CpNbCl4(PMePh2)”, Inorg. Chem. 1995, 34, 2343-2347. DOI: 10.1021/ic00113a014.
  91. C. Fettinger, H.-B. Kraatz, R. Poli*, A. L. Rheingold: “[Cp*MoCl(PMe3)3][PF6] and [CpMoCl(PMe3)3][BF4]”, Acta Cryst., Sect. C., 1995, C51, 364-367. DOI: 10.1107/S010827019400898X.
  92. C. Gordon, S. P. Mattamana, R. Poli*, P. E. Fanwick: “Crystal Structure of Base-Free [MoOI4] “, Polyhedron 1995, 14, 1339-1342. DOI: 10.1016/0277-5387(94)00397-W.
  93. R. Falvello, S. P. Mattamana, R. Poli*: “Bis(h5-indenyl)tetrakis(µ2-iodo)dimolybdenum, Synthesis and Structure”, Acta Cryst., Sect. C 1995, C51, 569-571. DOI: 10.1107/S010827019400870X.
  94. C. Fettinger, S. P. Mattamana, C. J. O’Connor, R. Poli*, G. Salem: “Linear Face-Sharing Trioctahedral [Mo3I12]3- by Spontaneous THF Loss from [MoI4(THF)2]. Structure, Bonding, and Magnetic Properties”, J. Chem. Soc., Chem. Comm. 1995, 1265-1266. DOI: 10.1039/C39950001265.
  95. Blackburn, H.-B. Kraatz, R. Poli* and R. C. Torralba: “Cyclopentadienyltungsten(IV) Chemistry: Synthesis and Characterization of (h-Ring)WX3(CO)2 (Ring = C5H5, C5H4Me, C5Me5) and X-ray Structure of (h-C5Me5)WBr3(CO)2“, Polyhedron 1995, 14, 2225-2230. DOI: 10.1016/0277-5387(94)00498-4.
  96. A. Cole, J. C. Fettinger, D. W. Keogh, R. Poli*: “Dissociative Phosphine Exchange for Cyclopentadienylmolybdenum(III) Systems. Bridging the Gap Between Werner-like Coordination Chemistry and Low-valent Organometallic Chemistry”, Inorg. Chim. Acta 1995, 240, 355-366. DOI: 10.1016/0020-1693(95)04554-6 (invited contribution, special volume dedicated to Prof. F. Basolo on occasion of his 75th birthday).
  97. C. Fettinger, D. W. Keogh, R. Poli*: “Stable Mononuclear, 17-Electron Molybdenum(III) Carbonyl Complexes”, J. Am. Chem. Soc. 1996, 118, 3617-3625. DOI: 10.1021/ja9540738.
  98. A. Cole, J. C. Fettinger, S. P. Mattamana, R. Poli*: “Four-legged Piano Stool Molybdenum(II) Compounds Without Carbonyl Ligands. 3.  Cyclopentadienyl and Indenyl Complexes Containing the Tridentate Ligand Ph2PCH2CH2P(Ph)CH2CH2PPh2 (Triphos) via Reduction of Mo(III) Precursors by Transmetalating Agents”, Polyhedron  1996, 15, 2351-2361.  DOI: 10.1016/0277-5387(95)00517-X.
  99. C. Fettinger, B. A. Pleune and R. Poli*: “First Structure of a Cyclopentadienyl Trihydride d2 System: A Pseudo Trigonal Prism Rather than the Expected Pseudo-Octahedron, and its Mechanism of Hydrogen Scrambling”, J. Am. Chem. Soc. 1996, 118, 4906-4907. DOI: 10.1021/ja953408i.
  100. C. Gordon, P. E. Fanwick, R. Poli*: “[(h5-C5Me5)2Mo22-I)4]+[FeI4] x [(h5-C5Me5)2Mo2I22-I)22-O)]”, Acta Cryst., Sect. C 1996, C52, 1098-1101. DOI: 10.1107/S0108270195016283.
  101. A. Quadrelli, H.-B. Kraatz, R. Poli*: “Oxidation and Protonation of Transition Metal Hydrides: The Role of an Added Base as Proton Shuttle and the Nature of Protonated Water in Acetonitrile”, Inorg. Chem. 1996, 35, 5154-5162. DOI: 10.1021/ic960394o.
  102. C. Fettinger, S. P. Mattamana, R. Poli*, R. D. Rogers: “Accessibility of 17-Electron Structures for Cyclopentadienylchromium(III) Compounds. 1.  Experimental Studies on the Dichloride and Dimethyl Compounds”, Organometallics  1996, 15, 4211-4222.  DOI: 10.1021/om960330l.
  103. Poli*: “Open-Shell Organometallics as a Bridge Between Werner-Type and Low-Valent Organometallic Complexes. The Effect of the Spin State on the Stability, Reactivity and Structure”, Chem. Rev., 1996, 96, 2135-2204. DOI: 10.1021/cr9500343.
  104. Abugideiri , J. C. Fettinger, D. W. Keogh, and R. Poli*: “Four-legged Piano Stool Molybdenum(II) Compounds Without Carbonyl Ligands. 4.  Cyclopentadienylmolybdenum(II) Complexes with 16-Electron and 18-Electron Configurations”, Organometallics 1996, 15, 4407-4416.  DOI: 10.1021/om960331d.
  105. C. Fettinger, J. C. Gordon, S. P. Mattamana, C. J. O’Connor, R. Poli*, G. Salem: “New Results in Anionic Halomolybdate(III) Chemistry. Tetrahydrofuran Loss From [MoX3Y(THF)2] (X, Y = Cl, Br, I) and Crystal Structure of the Edge-Sharing Trioctahedral [PPh4]3[Mo3I12]”, Inorg. Chem. 1996, 35, 7404-7412.  DOI: 10.1021/ic9607301.
  106. C. Fettinger, D. W. Keogh, H.-B. Kraatz, R. Poli*: “Structure and Magnetic properties of 16-electron, Half-sandwich Niobium(III) Complexes. A Magneto-structural Correlation for 16-electron Four-legged Piano Stool Complexes”, Organometallics, 1996, 15, 5489-5494.  DOI: 10.1021/om960384v.
  107. A. Saleh, B. A. Pleune, J. C. Fettinger, R. Poli*: “Hydrotris(pyrazolyl)borate Molybdenum Chemistry: Spin Triplet Sixteen-electron Carbonyl Derivatives of Molybdenum(II), and the X-ray Structure of the Oxo Compound {HB(3,5-Me2C3N2H)3}MoOI2“, Polyhedron, 1997, 16, 1391-1397. DOI: 10.1016/S0277-5387(96)00392-0.
  108. Cacelli, D. W. Keogh, R. Poli*, A. Rizzo: “Electron Pairing as a Stabilizing Factor in Open-Shell Organometallics. The Case of 15-Electron CpMCl2(PH3) (M = Cr and Mo)”, New J. Chem., 1997, 21, 133-135.
  109. W. Keogh, R. Poli*: “Spin State Change in Organometallic Reactions. Experimental and MP2 Theoretical Studies of the Thermodynamic and Kinetics of the CO and N2 Addition to Spin Triplet Cp*MoCl(PMe3)2“, J. Am. Chem. Soc., 1997, 119, 2516-2523.  DOI: 10.1021/ja960786u.
  110. Abugideiri, J. C. Fettinger, B. A. Pleune, R. Poli*, C. A. Bayse, M. B. Hall*: “Synthesis, Structure, and Hydride-Deuteride Exchange Studies on CpMoH3(PMe2Ph)2, and Theoretical MP2 Studies of the CpMoH3(PH3)2 Model System”, Organometallics, 1997, 16, 1179-1185. DOI: 10.1021/om960360o.
  111. Pleune, R. Poli*, J. C. Fettinger: “Synthesis, Structure, and Protonation Studies of Cp*MH3(dppe) (M = Mo, W). Pseudo-Trigonal Prismatic vs. Pseudo-Octahedral Structures for Half-sandwich Group 6 M(IV) Derivatives”, Organometallics, 1997, 16, 1581-1594.  DOI: 10.1021/om961002o.
  112. C. Fettinger, H.-B. Kraatz, R. Poli*, E. A. Quadrelli: “First Mononuclear Paramagnetic Organometallics of MoII and MoIII Containing Terminal Hydroxide Ligands. X-ray structure of [Mo(h5-C5H5)(OH)(PMe3)3]BF4“, J. Chem. Soc., Chem. Comm. 1997, 889-890.  DOI: 10.1039/A701616F.
  113. -S. Wang, J. C. Fettinger, R. Poli*: “Cyclopentadienylmolybdenum(II) and -(III) Complexes Containing Diene and Allyl Ligands. 1. Isomeric Preferences and Isomerization Rates in a Pair of Redox-Related Organometallic Complexes”, J. Am. Chem. Soc., 1997, 119, 4453-4464.  DOI: 10.1021/ja964078k.
  114. P. Mattamana, R. Poli*: “Accessibility of 17-Electron Structures for Cyclopentadienylchromium(III) Compounds. 2.  Cyanide Derivatives with 15- and 17-Electron Configurations”, Organometallics , 1997, 16, 2427-2433.  DOI: 10.1021/om9610096.
  115. Galassi, R. Poli*, E. A. Quadrelli, J. C. Fettinger: “Thermodynamic and Kinetic Effects in the H+/AuPPh3+ Exchange for the Hydride Complexes CpMoH(CO)2(L) (L = PMe3, PPh3, CO). Formation and Structure of [Cp(CO)2(PMe3)Mo(AuPPh3)2]+[BF4]“, Inorg. Chem., 1997, 36, 3001-3007.  DOI: 10.1021/ic961265a.
  116. C. Fettinger, D. W. Keogh, B. Pleune, R. Poli*: “Structure of the 17-Electron Cp*MoCl2(dppe): An Unexpectedly Trans Geometry in the Solid State”, Inorg. Chim. Acta, 1997, 261, 1-5. DOI: 10.1016/S0020-1693(96)05569-7.
  117. W. Keogh, R. Poli*: “Experimental and Theoretical Comparison Between CpMCl3Ln Systems of Nb(IV) and Mo(IV)”, J. Chem. Soc., Dalton Trans. 1997, 3325-3333. DOI: 10.1039/a703070c (special volume on occasion of the 1st anniversary of the death of Sir Geoffrey Wilkinson).
  118. Cacelli, D. W. Keogh, R. Poli, A. Rizzo*: “Theoretical studies of the 15- and 17-electron Structures of Cyclopentadienylchromium(III) and cyclopentadienyl­molybdenum(III) compounds. Dichloride and Dimethyl Compounds.”, J. Phys. Chem. A 1997, 101, 9801-9812.  DOI: 10.1021/jp972920i.
  119. Poli*: “Molybdenum Open Shell Organometallics. Spin State Changes and Pairing Energy Effects”.  Acc. Chem. Res. 1997, 30, 494-501. DOI: 10.1021/ar960280g.
  120. Legzdins*, W. S. McNeil, K. M. Smith and R. Poli*: “Density Functional Study of Spin State in CpM(NO)X2 (M = Mo, Cr; X = Cl, NH2, CH3):  Spectrochemical and Nephelauxetic Effects in Organometallic Compounds“, Organometallics 1998, 17, 615-622.  DOI: 10.1021/om970973g.
  121. Poli*, L.-S. Wang: “Cyclopentadienylmolybdenum(II) and -(III) Complexes Containing Diene and Allyl Ligands. 2.  Comparative Reactivity of the Isomeric Complexes CpMo(h-C3H5)(h-C4H6) with either supine or prone Allyl and either scis (supine) or strans Butadiene Ligands Toward Protons”, J. Am. Chem. Soc. 1998, 120, 2831-2842.  DOI: 10.1021/ja9729488.
  122. C. Fettinger, H.-B. Kraatz, R. Poli*: “Structure of Cyclopentadienyltricarbonyl-trimethylphosphinemolybdenum(II) tetrafluoroborate”, Acta Cryst., Sect. C, 1998, C54, 181-183. DOI: 10.1107/S0108270197012651.
  123. C. Fettinger, S. P. Mattamana, R. Poli*: “Two tetrahalooxomolybdate(V) structures, [Ph3PNPPh3][MoOBr4] and [PPh4][MoI4(H2O)]”, Acta Cryst., Sect. C, 1998, C54, 184-187. DOI: 10.1107/S0108270197010718.
  124. Bender-Gresse, E. Collange, R. Poli*, S. Mattamana: “New CpCrCl2(PR3) Complexes: Physical Properties and Reduction Chemistry”, Polyhedron  1998, 17, 1115-1119. DOI: 10.1016/S0277-5387(97)00496-8 (special issue dedicated to Prof. W. A. Herrmann’s 50th birthday).
  125. Pleune, R. Poli*, J. C. Fettinger: “Synthesis and Structure of the Stable Paramagnetic Cyclopentadienyl Polyhydride Complexes [Cp*MH3(dppe)]+ (M = Mo, W): Stronger M-H Bonds upon Oxidation”, J. Am. Chem. Soc. 1998, 120, 3257-3258. DOI: 10.1021/ja9729488.
  126. Poli*, S. T. Krueger, S. P. Mattamana: “Monomeric Tetrahydrofuran-stabilized Molybdenum(III) Halides”, Inorg. Synth. 1998, 32, 198-203. DOI: 10.1002/9780470132630.ch33.
  127. Poli*, E. A. Quadrelli: “Experimental and Computational Studies of the Stability and Reactivity of a Half-Sandwich 16-Electron Spin Triplet Mo(II) Complex Containing a Terminal Hydroxide Ligand”, New J. Chem. 1998, 22, 435-451. DOI: 10.1039/a709187g.
  128. -S. Wang, J. C. Fettinger, R. Poli*, R. Meunier-Prest: “Cyclopentadienyl­molybdenum(II) and -(III) Complexes Containing Diene and Allyl Ligands. 3.  Reactivity Studies of the Bisbutadiene Complex [CpMo(supine-h-C4H6)(strans-h-C4H6)][BF4]”, Organometallics 1998, 17, 2692-2701.  DOI: 10.1021/om971079s.
  129. M. Smith, R. Poli*, P. Legzdins: ” Metal-Based Chirality and Spin State Change in 16-electron CpML2 systems. A Computational Study of CpW(NO)(PH3)”, Chem. Commun. 1998, 1903-1904.  DOI: 10.1039/a805176c.
  130. A. Bayse, M. B. Hall*, B. Pleune, R. Poli*: “Experimental and Theoretical Studies of Nonclassical d0 Cyclopentadienyl Polyhydride Complexes of Molybdenum and Tungsten”, Organometallics 1998, 17, 4309-4315.  DOI: 10.1021/om9803523.
  131. Poli*, L.-S. Wang: “Cyclopentadienylmolybdenum(II) and -(III) Complexes Containing Diene and Allyl Ligands. Part 4.  Reactivity Studies of the Bisallyl Complex CpMo(supine-h-C3H5)2 and the Allyl-Butadiene Complex CpMo(supine-h-C3H5)(supine-h-C4H6)][PF6]”, Polyhedron  1998, 17, 3689-3700. DOI: 10.1016/S0277-5387(98)00164-8.
  132. Poli*, L.-S. Wang: “Comparative Chemistry of 18-Electron Mo(II) and 17-Electron Mo(III) Compounds Containing Only Carbon-Based Ligands”, Coord. Chem. Rev. 1998, 178-179, 169-189. DOI: 10.1016/S0010-8545(98)80121-5.
  133. C. Fettinger, H.-B. Kraatz, R. Poli*, E. A. Quadrelli, R. C. Torralba: ” Electrophilic Addition vs Electron Transfer for the Interaction of Ag+ with Molybdenum(II) Hydrides. Part I : Reaction with CpMoH(PMe3)3 and the Mechanism of Decomposition of [CpMoH(PMe3)3]+“, Organometallics, 1998, 17, 5767-5775. DOI: 10.1021/om9805786.
  134. A. Quadrelli, R. Poli*: “Electrophilic addition vs electron transfer for the interaction of Ag+ with Molybdenum(II) Hydrides. Part II. Reaction with CpMoH(CO)2(PMe3)”, Organometallics, 1998, 17, 5776-5781. DOI: 10.1021/om980579y.
  135. C. Fettinger, H.-B. Kraatz, R. Poli*, E. A. Quadrelli: “Organometallic Hydroxo and Oxo Complexes by Oxidation of Transition Metal Hydrides in the Presence of Water. X-ray Structures of [CpMo(OH)(PMe3)3][BF4] and [CpMo(O)(PMe3)2][BF4]”, J. Chem. Soc., Dalton Trans. 1999, 497-508. DOI: 10.1039/a807111j.
  136. Pleune, D. Morales, R. Meunier-Prest, P. Richard, E. Collange, J. C. Fettinger, R. Poli*: “Stable Paramagnetic Half-Sandwich Mo(V) and W(V) Polyhydride Complexes. Structural, Spectroscopic, Electrochemical, Theoretical, and Decomposition Mechanism Studies of [Cp*MH3(dppe)]+ (M = Mo, W)”, J. Am. Chem. Soc. 1999, 121, 2209-2225. DOI: 10.1021/ja9834881.
  137. Morales, R. Poli*, P. Richard, J. Andrieu, E. Collange: “Half-Sandwich Molybdenum Compounds with Phosphine-Alkylthiolate and Phosphine-Thioether Ligands. Crystal Structure of [CpMo(SCH2CH2PPh2)2][BPh4]”, J. Chem. Soc., Dalton Trans. 1999, 867-874. DOI: 10.1039/a809903k.
  138. Collange, D. Duret, R. Poli*: “Experimental and Computational Investigations of the Phosphine Exchange in 15-Electron CpCrCl2(PR3) Systems by Stopped-Flow and Density Functional Calculations: A Single-State SN2 Mechanism”, J. Chem. Soc., Dalton Trans. 1999, 875-880. DOI: 10.1039/a809129c.
  139. Le Grognec, R. Poli* and L.-S. Wang: “Stable 17-electron Mo(III) Complexes Containing Alkyl Ligands”, Inorg. Chem. Commun. 1999, 2, 95-96. DOI: 10.1016/S1387-7003(99)00019-2.
  140. Poli*, K. M. Smith: “Spin State and Ligand Dissociation in CpCoL2 Complexes (L = PH3, H2C=CH2): a Computational Study”, Eur. J. Inorg. Chem. 1999, 877-880. DOI: 10.1002/(SICI)1099-0682(199905)1999:5.
  141. M. Smith, R. Poli*, P. Legzdins: “A Computational Study of Two-State Conformational Changes in 16-Electron [CpW(NO)L] Complexes (L = PH3, CO, CH2, HCCH, H2CCH2)”, Chem. Eur. J., 1999, 1598-1608. DOI: 10.1002/(SICI)1521-3765(19990503)5:5.
  142. Andrieu, J. Dietz, R. Poli*, P. Richard: “Reversible P-C bond formation for saturated a-aminophosphine ligands in solution: stabilization by coordination to Cu(I)”, New J. Chem. 1999, 23, 581-583. DOI: 10.1039/a902783a.
  143. Poli*: “Different Approaches to Mid-Valent, Paramagnetic Half-Sandwich Complexes of the Heavier Group 6 Metals”, Synlett. 1999, 1019-1028. DOI: 10.1055/s-1999-2746.
  144. Andrieu*, C. Baldoli, S. Maiorana, R. Poli*, P. Richard: “Chiral a-P,N ligands via a diastereoselective Ph2PH addition to tricarbonyl(h6-benzaldimine) chromium complexes”, Eur. J. Org. Chem. 1999, 3095-3097. DOI: 10.1002/(SICI)1099-0690(199911)1999:11.
  145. Poli*, K. M. Smith: “Pairing Energy Effects in Cyanide Complexes of CpCr(III)”, Eur. J. Inorg. Chem., 1999, 2343-2346. DOI: 10.1002/(SICI)1099-0682(199912)1999:12.
  146. Blackburn, J. C. Fettinger, H.-B. Kraatz, R. Poli*, R. C. Torralba: “Preparation of Trichloro- and Tribromocyclopentadienyltungsten(IV)”, J. Organometal. Chem. 2000, 593-594, 27-35. DOI: 10.1016/S0022-328X(99)00292-2 (special volume on the occasion of Professor Calderazzo’s 70th birthday).
  147. Carey, J. C. Fettinger, R. Poli*, K. M. Smith: “Synthesis and Characterization of [Mo(µ-EPh)(CO)3(CH3CN)]2 (E = Se, Te), including the X-ray Structure of the Tellurium Derivative”, Inorg. Chim. Acta., 2000, 299, 118-122. DOI: 10.1016/S0020-1693(99)00478-8.
  148. M. Smith, R. Poli*, J. N. Harvey*: “Ligand Dissociation Accelerated by Spin State Change: Locating the Minimum Energy Crossing Point between Potential Energy Surfaces in Organotransition Metal Reactions”, New J. Chem., 2000, 24, 77-80. DOI: 10.1039/a909646i.
  149. Morales, R. Poli*, P. Richard: “Preparation and Structure of the 17-electron (h5-C5R5)Mo(OH)2(dppe) (R = Me, Et) Organometallic Compounds Containing two gem-Terminal Hydroxide Ligands “, J. Organometal. Chem. 2000, 596, 64-69. DOI: 10.1016/S0022-328X(99)00539-2 (special volume on the occasion of Prof. Cotton’s 70th birthday).
  150. Cacelli, R. Poli*, E. A. Quadrelli, A. Rizzo, K. M. Smith: “A Density Functional Study of Open-shell Cyclopentadienyl-molybdenum(II) Complexes. A Comparison of Stabilizing Factors: Spin-pairing, Mo-X π Bonding, and Release of Steric Pressure”, Inorg. Chem.  2000, 39, 517-524. DOI: 10.1021/ic990875i.
  151. Le Grognec, R. Poli*, P. Richard: “Synthesis, characterisation, and molecular and electronic structure of CpMoCl2(R1CºCR2) (R1, R2 = Ph, Et, Me): a New Class of Half-Sandwich 17-Electron Molybdenum(III) Organometallics”, J. Chem. Soc., Dalton Trans., 2000, 1499-1506. DOI: 10.1039/b000948m.
  152. Morales, R. Poli*, J. Andrieu: “Protonation and Oxidation Chemistry of a Pentaethylcyclopentadienyl-containing Molybdenum(IV) Trihydride Complex”, Inorg. Chim. Acta, 2000, 300-302, 709-720. DOI: 10.1016/S0020-1693(99)00584-8 (special volume No. 300).
  153. Andrieu, P. Braunstein, J.-M. Camus, D. Morales, F. Naud, R. Poli*, P. Richard: “Half-sandwich Complexes of Molybdenum(III), -(IV) and -(V) with the P-O and P-N Bifunctional Ligands Ph2PCH2X (X = 2-oxazoline, C(O)NPh2)”, J. Chem. Soc., Dalton Trans. 2000, 2577-2585. DOI: 10.1039/b002403l.
  154. Poli*, K. M. Smith: “Theoretical Studies of C-H and N-H Bond Activation by Cyclopentadienyl Nitrosyl Alkylidene Species of Molybdenum and Tungsten”, Organometallics 2000, 19, 2858-2867. DOI: 10.1021/om000088p.
  155. Le Grognec, R. Poli*, P. Richard: “Dialkyl(butadiene)cyclopenta­dienyl­molybdenum(III) Complexes. Synthesis, Characterization, and Reactivity”, Organometallics 2000, 19, 3842-3853. DOI: 10.1021/om000329t.
  156. Andrieu*, J.-M. Camus, J. Dietz, P. Richard, R. Poli: “Synthesis of New b-P,N Aminophosphines and Coordination Chemistry to Pd(II). X-ray Structures of [PdCl2(k2:P,N-Ph2PCH2CH(Ph)NHPh)] and [PdCl(h3-C3H5)(k1:P-Ph2P­CH2CH­(Ph)NHPh)]”, Inorg. Chem. 2001, 40, 1597-1605. DOI: 10.1021/ic000867y.
  157. M. Smith, R. Poli*, J. N. Harvey*: “A Computational Study of Ethylene C–H Bond Activation by Cp*Ir(PR3)”, Chem. Eur. J. 2001, 7, 1679-1690. DOI: 10.1002/1521-3765(20010417)7:8.
  158. Le Grognec, R. Poli*, P. Richard: “A Reinvestigation of Compound CpMo(PMe3)2(CH3)2: an Alkylation by Single Electron Transfer and Radical Addition?”, Dalton Trans., 2001, 2251-2257. DOI: 10.1039/b101441m.
  159. Andrieu*, J.-M. Camus, R. Poli, P. Richard: “New Chiral a-Aminophosphine Oxides and Sulfides. An Unexpected Rhodium-catalyzed Ligand Epimerization”, New J. Chem. 2001, 25, 1015-1023. DOI: 10.1039/b100217l.
  160. Le Grognec, J. Claverie*, R. Poli*: “Radical Polymerization of Styrene controlled by Half-Sandwich Mo(III)/Mo(IV) Couples: all Basic Mechanisms are Possible”, J. Am. Chem. Soc., 2001, 123, 9513-9524. DOI: 10.1021/ja010998d.
  161. Le Grognec, R. Poli*: “Diene-Containing Half-Sandwich Mo(III) Complexes as Ethylene Polymerization Catalysts. Experimental and Theoretical Study”, Chem. Eur. J., 2001, 7, 4572-4583. DOI: 10.1002/1521-3765(20011105)7:21
  162. Stoffelbach, D. Saurenz, R. Poli*: “Improved Preparations of a Few Molybdenum Coordination Compounds via Tetrachlorobis(diethylether)molybdenum(IV)”, Eur. J. Inorg. Chem., 2001, 2699-2703. DOI: 10.1002/1099-0682(200109)2001:10.
  163. Le Grognec, R. Poli*, P. Richard, R. Llusar, S. Uriel: “Interaction of Half-Sandwich Alkylmolybdenum(III) Complexes with B(C6F5)3. The X-ray Structure of [CpMo(h4-C4H6)(m-Cl)(m-CH2)(O)MoCp][CH3B(C6F5)3]”, J. Organometal Chem. 2001, 640, 113-120. DOI: 10.1016/S0022-328X(01)01196-2.
  164. Collange, A. Flamini, R. Poli*: “Stopped-Flow and DFT Studies of Proton Transfer and Isomerisation of 5-Amino-3-imino-1,2,6,7-tetracyano-3H-pyrrolizine and Its Related Base 2-(5-Amino-3,4-dicyano-2H-pyrrol-2-ylidene)-1,1,2-tricyanoethanide in Water: a Completely Sorted Out Square Scheme”, J. Phys. Chem. A 2002, 106, 200-208. DOI: 10.1021/jp011628e.
  165. Stoffelbach, J. Claverie, R. Poli*: “Atom Transfer Radical Polymerization of Styrene Controlled by Phosphine-Containing Coordination Compounds of Mo(III)/Mo(IV)”, C. R. Acad. Sci, Série C. 2002, 5, 37-42. DOI: 10.1016/S1631-0748(02)01306-1 (special GECOM-CONCOORD 2001 issue)
  166. C. Green*, J. N. Harvey*, R. Poli*: “Theoretical investigation of the spin crossover transition states of the addition of methane to a series of Group 6 metallocenes using minimum energy crossing points”, Dalton Trans. 2002, 1861-1866. DOI: 10.1039/b111257k.
  167. Saurenz, F. Demirhan, P. Richard, R. Poli* and H. Sitzmann: “Cyclopentadienylmolybdenum(VI) and Molybdenum(V) Oxo Chemistry: New Synthetic and Structural Features”, Eur. J. Inorg. Chem. 2002, 1415-1424. DOI: 10.1002/1099-0682(200206)2002:6.
  168. Demirhan, J. Gun, O. Lev, A. Modestov, R. Poli*, P. Richard: “High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*MoV trinuclear cation by chemical reduction of Cp*2Mo2O5.” Dalton Trans. 2002, 2109-2111. DOI: 10.1039/b203583a.
  169. Collange, J. A. Garcia, R. Poli*: “Nature of (C5Me5)2Mo2O5 in Water-Methanol at pH 0-14. On the Existence of (C5Me5)MoO2(OH) and [(C5Me5)MoO2]+: a Stopped-Flow Kinetic Analysis”, New J. Chem, 2002, 26, 1249-1256. DOI: 10.1039/b202106b.
  170. E. Bitterwolf*, W. B. Scallorn, J. T. Bays, C. A. Weiss, J. C. Linehan, J. Franz, R. Poli: “Photochemical intermediates of trans-Rh(CO)L2Cl where L = PMe3, PBu3, and i-Pr2HN and cis-Rh(CO)2(i-Pr2HN)Cl in frozen organic glasses”, J. Organometal. Chem. 2002, 652, 95-104. DOI: 10.1016/S0022-328X(02)01312-8 (special issue “Frontiers in organometallic Chemistry”)
  171. Bastian, D. Morales, R. Poli*, P. Richard, H. Sitzmann*: “Synthesis of new half sandwich tetrachloro derivatives of molybdenum(V) and tungsten(V). X-ray structures of (C5HPri4)W(CO)3(CH3) and (C5Et5)WCl4”, J. Organometal. Chem. 2002, 654, 109-116. DOI: 10.1016/S0022-328X(02)01392-X.
  172. Andrieu*, J.-M. Camus, P. Richard, R. Poli: “Synthesis, coordination to Rh(I), and hydroformylation catalysis of new b‑aminophosphines bearing a dangling nitrogen group: an unusual inversion of a Rh-coordinated P center”, Inorg. Chem. 2002, 41, 3876-3885. DOI: 10.1021/ic011035i.
  173. C. Gordon*, G. R. Giesbrecht, D. L. Clark, P. J. Hay, D. W. Keogh, R. Poli, B. L. Scott, J. G. Watkin: “The First Example of a m2-Imido Functionality Bound to a Lanthanide Metal Center:  The X-Ray Crystal Structure and a DFT Study of [(m-ArN)Sm(m-NHAr)(m-Me)AlMe2]2 (Ar = 2,6-i-Pr2C6H3)”, Organometallics, 2002, 21, 4726-4734. DOI: 10.1021/om0206960.
  174. L. Clark, J. C. Gordon, P. J. Hay*, R. L. Martin, R. Poli*: “A DFT Study of Tris(bis(trimethylsilyl)methyl)lanthanum and –samarium”, Organometallics, 2002, 21, 5000-5006. DOI: 10.1021/om020506l.
  175. Stoffelbach, R. Poli*, P. Richard: “Half-sandwich Molybdenum(III) Compounds Containing Diazadiene Ligands and Their Use in the Controlled Radical Polymerization of Styrene”, J. Organometal. Chem. 2002, 663, 269-276. DOI: 10.1016/S0022-328X(02)01878-8 (special volume in honor of Prof. Pascual Royo’s 65th birthday)
  176. Poli*, J. N. Harvey*: “Spin Forbidden Chemical Reactions of Transition Metal Compounds. New Ideas and New Computational Challenges.” Chem. Soc. Rev., 2003, 32, 1-8. DOI: 10.1039/b200675h.
  177. Gun*, A. Modestov, O. Lev, D. Saurenz, M. A. Vorotyntsev, R. Poli*: On-Line Electrochemistry/Mass Spectrometry of Organometallic Species: Reduction of (C5Me5)2Mo2O5 in Methanol – Water – Acetate Solutions”, Eur. J. Inorg. Chem., 2003, 482-492. DOI: 10.1002/ejic.200390068.
  178. R. Jensen*, R. Poli*: “Theoretical Investigation of the Low Energy States of CpMoCl(PMe3)2 and Their Role in the Spin Forbidden Addition of N2 and CO”, J. Phys. Chem. A, 2003, 107, 1424-1432. DOI: 10.1021/jp027212y.
  179. Demirhan, P. Richard, R. Poli*: “High oxidation state aqueous organometallics: synthesis and structure of a dinuclear oxo(pentamethylcyclopentadienyl)acetato complex of molybdenum(IV), [Cp*Mo(m-O)(m-O2CCH3)]2”, Inorg. Chim. Acta. DOI: 10.1016/S0020-1693(02)01439-1 (special volume in honor of Prof. Rafael Uson’s career), 2003, 347, 61-66.
  180. -M. Camus, J. Andrieu*, R. Poli, P. Richard, C. Baldoli, S. Maiorana: “Rh(I) coordination chemistry of chiral a-amino-phosphine(h6-arene) chromium tricarbonyl ligands”, Inorg. Chem. 2003, 42, 2384-2390. DOI: 10.1021/ic025588k.
  181. N. Harvey, R. Poli*, K. M. Smith: “Understanding the Reactivity of Transition Metal Complexes Involving Multiple Spin States”, Coord. Chem. Rev., 2003, 238-239, 347-361. DOI: 10.1016/S0010-8545(02)00283-7 (special volume on Theoretical Coordination Chemistry).
  182. Gun, A. Modestov, O. Lev, R. Poli*: “Reduction of (C5Me5)2Mo2O5 and (C5Me5)2Mo2O4 in Methanol – Water – Trifluoroacetate Solutions investigated by Combined On-Line Electrochemistry/Electrospray Mass Spectrometry”, Eur. J. Inorg. Chem. 2003, 2264-2272. DOI: 10.1002/ejic.200200627.
  183. Stoffelbach, D. M. Haddleton, R. Poli*: “Controlled Radical Polymerization with Half–Sandwich Molybdenum(III) complex containing Diazadiene Ligands: Styrene, Alkyl Acrylates and their Block Copolymer”, Eur. Polym. J. 2003, 39, 2099-2105. DOI: 10.1016/S0014-3057(03)00152-6.
  184. N. Harvey*, R. Poli*: “Computational study of the spin-forbidden H2 oxidative addition to 16-electron Fe(0) Complexes”, Dalton Trans. 2003, 4100-4106. DOI: 10.1039/b302916f.
  185. V. Belkova, P. O. Revin, L. M. Epstein, E. V. Vorontsov, V. I. Bakhmutov, E. S. Shubina*, E. Collange, R. Poli*: “Kinetics and Mechanism of the Proton Transfer to Cp*Fe(dppe)H: Absence of a Direct Protonation at the Metal Site”, J. Am. Chem. Soc. 2003, 125, 11106-11115. DOI: 10.1021/ja0358450.
  186. D. Brady, D. L. Clark, J. C. Gordon, P. J. Hay, D. W. Keogh*, R. Poli*, B. L. Scott: “Tris(bis(trimethylsilyl)amido)­samarium: X-ray Structure and DFT Study”, Inorg. Chem. 2003, 42, 6682-6690. DOI: 10.1021/ic0341690.
  187. B. Gillies, K. Matyjaszewski*, P.-O. Norrby, T. Pintauer, R. Poli*, P. Richard: “A DFT Study of R-X Bond Dissociation Enthalpies of Relevance to the Initiation Process of Atom Transfer Radical Polymerization”, Macromolecules, 2003, 36, 8551-8559. DOI: 10.1021/ma0351672.
  188. Andrieu, N. V. Belkova, M. Besora, E. Collange, L.M. Epstein , A. Lledós*, R. Poli*, P. O. Revin, E. S. Shubina*, E. V. Vorontsov: “ Hydrogen bonding and proton transfer involving the trihydride complexes Cp*MH3(dppe) (M = molybdenum, tungsten) and fluorinated alcohols: the competitive role of the hydride ligands and the metal”, Russ. Chem. Bull. 2003, 52, 2679-2682. DOI: 10.1023/B:RUCB.0000019886.18334.55 (original version: Izv. Akad. Nauk., Ser. Khim. 2003, 2535-2538).
  189. Poli*: “High Oxidation State Organometallic Chemistry in Aqueous Media: New Opportunities for Catalysis and Electrocatalysis”, Chem. Eur. J., 2004, 10, 332-341. DOI: 10.1002/chem.200304810 (Concept Article).
  190. Stoffelbach, B. Rebière, R. Poli*: “A bis(diazadiene) adduct of MoCl2: mononuclear octahedral, undistorted and diamagnetic”, Eur. J. Inorg. Chem. 2004, 726-731. DOI: 10.1002/ejic.200300168.
  191. -M. Camus, J. Andrieu*, P. Richard, R. Poli: “Allylpalladium(II) Complexes with Aminophosphane ligands: Solution Behaviour and X-Ray Structure of cis-[Pd(h3-CH2CHCHPh)(Ph2PCH2CHPhNH(2,6-C6H3iPr2)][PF6]”, Eur. J. Inorg. Chem. 2004, 1081-1091. DOI: 10.1002/ejic.200300627.
  192. Pintauer, W. Braunecker, E. Collange, R. Poli*, K. Matyjaszewski*: “ Determination of Rate Constants for the Activation Step in Atom Transfer Radical Polymerization Using the Stopped-Flow Technique ”, Macromolecules, 2004, 52, 2679-2682. DOI: 10.1021/ma035634f.
  193. -M. Camus, J. Andrieu*, P. Richard, R. Poli, C. Darcel, S. Jugé*: “A P-chirogenic b-aminophosphine synthesis by diastereoselective reaction of the a-metallated PAMP-borane complex with benzaldimine”, Tetrahedron: Asymmetry, 2004, 15, 2061-2065. DOI: 10.1016/j.tetasy.2004.05.031.
  194. A. Koridze*, S. A. Kuklin, A. M. Sheloumov, F. M. Dolgushin, V. Yu. Lagunova, I. I. Petukhova, M. G. Ezernitskaya, A. S. Peregudov, P. V. Petrovskii, E. V. Vorontsov , M. Baya , R. Poli: “Ferrocene-Based Pincer Complexes of Palladium: Synthesis, Structures, Spectroscopic and Electrochemical Properties”, Organometallics, 2004, 23, 4585-4593. DOI: 10.1021/om0497285.
  195. Robé, J.-C. Daran, S. Vincendeau, R. Poli*: “A new synthetic method and solution equilibria for the chlorotitanate(IV) anions. Evidence for the existence of a new species: [Ti2Cl11]3-”, Eur. J. Inorg. Chem. 2004, 4108-4114. DOI: 10.1002/ejic.200400293.
  196. Schott, P. Callaghan, J. Dunne, S. B. Duckett*, C. Godard, J. M. Goicoechea, J. N. Harvey, J. P. Lowe, R. J. Mawby, G. Müller, R. N. Perutz, R. Poli, M. K. Whittlesey: “The reaction of M(CO)3(dppe) (dppe = Ph2PCH2CH2PPh2, M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products”, J. Chem. Soc., Dalton Trans., 2004, 3218-3224. DOI: 10.1039/B407457B.
  197. P. Dunne, D. Blazina, S. Aiken, H. A. Carteret, S. B. Duckett*, J. A. Jones, R. Poli, A. C. Whitwood: “A combined parahydrogen and theoretical study of H2 activation by 16–electron d8 ruthenium zero complexes and their subsequent catalytic behaviour”, J. Chem. Soc., Dalton Trans. 2004, 3616-3628. DOI: 10.1039/B410912K.
  198. Collange, L. Metteau, P. Richard, R. Poli*: “Synthesis and structure of a new organometallic polyoxomolybdate, Cp*2Mo6O17”, Polyhedron, 2004, 23, 2605-2610. DOI: 10.1016/j.poly.2004.06.025 (special volume on the occasion of M. L. H. Green’s retirement).
  199. Stoffelbach, R. Poli*: “Al(OPri)3-catalysed halogen exchange processes of relevance to atom transfer radical polymerization: the effect depends on the metal electronic structure”, Chem. Commun., 2004, 2666-2667. DOI: 10.1039/b409992c.
  200. Poli*: “Open Shell Organometallics: a General Analysis of their Electronic Structure and Reactivity”, J. Organometal. Chem., 2004, 689, 4291–4304. DOI: 10.1016/j.jorganchem.2004.05.040 (invited contribution to the special 40th anniversary issue).
  201. V. Belkova, E. Collange, P. Dub, L. M. Epstein, D. A. Lemenovskii, A. Lledós*, O. Maresca, F. Maseras, R. Poli*, P. O. Revin, E. S. Shubina, E. V. Vorontsov: “Experimental and Computational Studies of Hydrogen Bonding and Proton Transfer to Cp*Fe(dppe)H”, Chem. Eur. J. 2005, 11, 873-888. DOI: 10.1002/chem.200400700.
  202. -M. Camus, P. Roy García, J. Andrieu*, P. Richard, R. Poli: “Resolution of b-aminophosphines with chiral cyclopalladated complexes”, J. Organometal. Chem.2005, 690, 1659-1668. DOI: 10.1016/j.jorganchem.2005.01.023.
  203. Poli*, F. Stoffelbach, S. Maria, J. Mata: “An Experimental and Computational Study on the Effect of Al(OPri)3 on Atom Transfer Radical Polymerization and on the Catalyst–Dormant Chain Halogen Exchange”, Chem. Eur. J. 2005, 11, 2537-2548. DOI: 10.1002/chem.200401143.
  204. Maria, F. Stoffelbach, J. Mata, J.-C. Daran, P. Richard, R. Poli*: “The radical trap in atom transfer radical polymerization need not be thermodynamically stable. A study of the MoX3(PMe3)3 (X = Cl, Br, I) catalysts”, J. Am. Chem. Soc. 2005, 127, 5946-5956. DOI: 10.1021/ja043078e.
  205. M. Martins* C. C. Romão*, M. Abrantes, M. C. Azevedo, J. Cui, A. R. Dias, M. T. Duarte, M. A. Lemos, T. Lourenço, R. Poli, “Molybdenum and Tungsten Cyclopentadienyl Oxo Monomers and Dimers: Syntheses and Applications in Olefin Epoxidation Catalysis”, Organometallics, 2005, 24, 2582-2589. DOI: 10.1021/om049107b.
  206. Poli*, I. Cacelli: “Orbital splitting and pairing energy in open-shell organometallics: a study of two families of 16-electron complexes, Cp2M (M = Cr, Mo, W) and CpM(PH3) (M = Co, Rh, Ir), Eur. J. Inorg. Chem. 2005, 2324–2331. DOI: 10.1002/ejic.200400839.
  207. -L. Carreón-Macedo, J. N. Harvey*, R. Poli*: “The reductive elimination of methane from methyl hydrido ansa-metallocenes of molybdenum and tungsten: application of Hammond’s postulate to two-state reactions”, Eur. J. Inorg. Chem. 2005, 2999–3008. DOI: 10.1002/ejic.200500236.
  208. Topaloglu-Sozuer*, A. Gunyar, S.-D. Irdem, M. Baya, R. Poli: “Synthesis, Characterization and Electrochemical Behavior of Oxo-Bridged (Arylimido)[tris(3,5-dimethylpyrazolyl)borato] molybdenum(V) Complexes”, Inorg. Chim. Acta 2005, 358, 3303-3310. DOI: 10.1016/j.ica.2005.05.018.
  209. Matyjaszewski*, R. Poli: “Comparison of Bond Dissociation Energies of Dormant Species Relevant to Degenerative Transfer and Atom Transfer Radical Polymerization”, Macromolecules 2005, 38, 8093-8100. DOI: 10.1021/ma0512049.
  210. L. Clark*, J. C. Gordon*, P. J. Hay*, R. Poli*: “On the Existence and Stability of Lanthanide – Main Group Element Multiple Bonds. New Paradigms In the Bonding of the 4f-Elements. A DFT Study of Cp2CeX (X = F+, O, NH, CH, CH2) and the Ligand Adduct Cp2Ce(CH2)(NH3)”, Organometallics, 2005, 24, 5747-5758. DOI: 10.1021/om050693y.
  211. Andrieu*, J.-M.Camus, P. Richard, R. Poli, L. Gonsalvi, F. Vizza, M. Peruzzini*: “Amino-phosphines in RhI-catalyzed hydroformylation: hemilabile behavior of P,N ligands under high CO pressures and catalytic properties”, Eur. J. Inorg. Chem., 2006, 51-61. DOI: 10.1002/ejic.200500432.
  212. Andrieu*, J.-M. Camus, C. Balan, R. Poli*: “Amino-phosphines in RhI-catalyzed hydroformylation: new mechanistic insights using D2O as deuterium labeling agent”, Eur. J. Inorg. Chem., 2006, 62-68. DOI: 10.1002/ejic.200500448.
  213. Wolf, A. Labande*, J.-C. Daran, R. Poli*: “Nickel(II) Complexes with Bifunctional Phosphine-Imidazolium Ligands and their Catalytic Activity in the Kumada-Corriu Coupling Reaction”, J. Organometal. Chem. 2006, 691, 433-443. DOI: 10.1016/j.jorganchem.2005.09.010.
  214. Petit, P. Richard, I. Cacelli, R. Poli*: “A two-state computational investigation of the methane C-H and ethane C-C oxidative addition to [CpM(PH3)]n+ (M = Co, Rh, Ir; n = 0, 1)”, Chem. Eur. J. 2006, 12, 813-823. DOI: 10.1002/chem.200500896.
  215. Demirhan*, G. Taban, M. Baya, C. Dinoi, J.-C. Daran, R. Poli*: “Reduction of [Cp*2Mo2O5] by thioglycolic acid in an aqueous medium. Synthesis and structure of [{Cp*Mo(m-SCH2COO)}2(m-S)]”, J. Organometal. Chem. 2006, 691, 648–654. DOI: 10.1016/j.jorganchem.2005.10.006.
  216. Demirhan*, B. Çağatay, D. Demir, M. Baya, J.-C. Daran, R. Poli*: “Reduction of Cp*2Mo2O5 in an aqueous medium. Structure and properties of a triangular mixed oxo-hydroxo-bridged product, [Cp*3Mo3(m-O)2(m-OH)4](X)2, with X = CF3CO2 or CF3SO3”, Eur. J. Inorg. Chem. 2006, 757-764. DOI: 10.1002/ejic.200500665.
  217. D. Phillips, S. Bolaño, S. S. Bosquain, J.-C. Daran, R. Malacea, M. Peruzzini*, R. Poli*, L. Gonsalvi*: “A new class of rhodium(I) k1-P and  k2-P,N complexes with rigid PTN(R) ligands (PTN = 7-phospha-1,3,5-triaza-bicyclo[3.3.1]-nonane)”, Organometallics 2006, 25, 2189-2200. DOI: 10.1021/om051099r.
  218. Malacea, E. Manoury*, L. Routaboul, J.-C. Daran, R. Poli, J. P. Dunne, A. C. Withwood, C. Godard, S. B. Duckett: “Coordination chemistry and diphenylacetylene hydrogenation catalysis of planar chiral ferrocenylphosphine-thioether ligands with cyclooctadiene­iridium(I)”, Eur. J. Inorg. Chem. 2006, 1803–1816. DOI: 10.1002/ejic.200600065.
  219. Blazina, J. P. Dunne, S. Aiken, S. B. Duckett*, C. Elkington, J. E. McGrady*, R. Poli, S. J. Walton, M. S. Anwar, J. A. Jones, H. A. Carteret: “Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies”, Dalton Trans. 2006, 2072-2080. DOI: 10.1039/b510616h.
  220. Poli*, M. Baya, R. Meunier-Prest, S. Raveau: “Electrochemical and DFT studies of the oxidative decomposition of the trihydride complexes Cp*M(dppe)H3 (M = Mo, W) in acetonitrile”, New J. Chem. 2006, 30, 759-773. DOI: 10.1039/b518343j.
  221. V. Belkova, P. O. Revin, M. Besora, M. Baya, L. M. Epstein, A. Lledós*, R. Poli*, E. S. Shubina*, E. V. Vorontsov: “Hydrogen bonding and proton transfer to the trihydride complex Cp*MoH3(dppe): IR, NMR, and theoretical investigations”, Eur. J. Inorg. Chem. 2006, 2192-2209. DOI: 10.1002/ejic.200600093.
  222. P. Dunne, S. B. Duckett*, C. Godard, R. Malacea, E. Manoury*, J.-C. Daran, A. C. Whitwood, R. Poli: “Parahydrogen studies of H2 addition to an Ir(I) complex containing a chiral phosphine-thioether ligand: Implications for catalysis”, Dalton Trans. 2006, 3350 – 3359. DOI: 10.1039/b601980c.
  223. A. Mata, S. Maria, J.-C. Daran, R. Poli*: “Synthesis and characterization of MoOI2(PMe3)2, and use of MoOX2(PMe3)2 (X = Cl, I) in controlled radical polymerization”, Eur. J. Inorg. Chem. 2006, 2624–2633. DOI: 10.1002/ejic.200600156.
  224. Poli*: “Relationship between one-electron transition metal reactivity and radical polymerization processes”, Angew. Chem., Int. Ed. Engl., 2006, 45, 5058–5070. DOI: 10.1002/anie.200503785 (Minireview).
  225. Stoffelbach, P. Richard, R. Poli*, T. Jenny, C. Savary: “Half-sandwich Mo(III) complexes with asymmetric diazadiene ligands”, Inorg. Chim. Acta, 2006, 359, 4447–4453. DOI: 10.1016/j.ica.2006.04.013.
  226. Wolf, A. Labande*, M. Natella, J.-C. Daran, R. Poli*: “Aryl Grignard Cross-Coupling of Aryl Chlorides Catalysed by New, Highly Active Phosphine/Imidazolium Nickel(II) Complexes”, J. Mol. Catal. A, 2006, 259, 205-212. DOI: 10.1016/j.molcata.2006.06.004.
  227. Baya, O. Maresca, R. Poli*, Y. Coppel, F. Maseras, A. Lledós*, N. V. Belkova, P. A. Dub, L. M. Epstein, E. S. Shubina*: “Dihydrogen to Dihydride Isomerisation Mechanism in [(C5Me5)FeH2(Ph2PCH2CH2PPh2)]+ through the Experimental and Theoretical Analysis of Kinetic Isotope Effects”, Inorg. Chem. 2006, 45, 10248-10262. DOI: 10.1021/ic061428n.
  228. Baya, J. Houghton, J.-C. Daran, R. Poli*: “Formation and structure of a sterically protected molybdenum hydride complex with a 15-electron configuration: [(1,2,4-C5H2tBu3)Mo(PMe3)2H]+”, Angew. Chem., Int. Ed. Engl. 2007, 46, 429-432. DOI: 10.1002/anie.200603628.
  229. Le Roux, R. Malacea, E. Manoury*, R. Poli, L. Gonsalvi, M. Peruzzini*: “Highly efficient asymmetric hydrogenation of alkyl aryl ketones catalyzed by iridium complexes with chiral planar ferrocenyl phosphino-thioether ligands”, Adv. Synth. & Catal. 2007, 349, 309–313. DOI: 10.1002/adsc.200600350.
  230. Maria, H. Kaneyoshi, K. Matyjaszewski*, R. Poli*: “Effect of Electron Donors on the Radical Polymerization of Vinyl Acetate Mediated by Co(acac)2: degenerative transfer versus reversible homolytic cleavage of an organocobalt(III) complex”, Chem. Eur. J., 2007, 13, 2480-2492. DOI: 10.1002/chem.200601457.
  231. Labande*, J.-C. Daran, E. Manoury, R. Poli*: “New 1,1’- and 1,2-Ferrocenyl Phosphine-Diaminocarbene Ligands: Synthesis, Rh(I) Complexes”, Eur. J. Inorg. Chem. 2007, 1205-1209. DOI: 10.1002/ejic.200601193.
  232. Dinoi, P. Prikhodchenko, F. Demirhan, J. Gun, O. Lev, J.-C. Daran, R. Poli*: “Reduction of [Cp*2Mo2O5] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-propionato(2-)-bridged molybdenum(IV) compound”, J. Organomet. Chem. 2007, 692, 2599-2605. DOI: 10.1016/j.jorganchem.2007.02.046.
  233. Maria, T. Biedroń, R. Poli, P. Kubisa*, “Atom Transfer Radical Polymerization of Methyl Acrylate with Molybdenum Halides as Catalysts in an Ionic Liquid”, J. Appl. Polym. Sci. 2007, 105, 278-281. DOI: 10.1002/app.26046 (special issue dedicated to the memory of Professor Marian Kryszewski).
  234. Robé, S. Maria, P. Richard, R. Poli*: “Mixed titanium-hafnium chlorometallate complexes”, Eur. J. Inorg. Chem., 2007, 2434–2442. DOI: 10.1002/ejic.200700056.
  235. A. Dub, M. Baya, J. Houghton, N. V. Belkova, J. C. Daran, R. Poli*, L. M. Epstein, E. S. Shubina*: “Solvent control in the protonation of Cp*Mo(dppe)H3 by CF3COOH”, Eur. J. Inorg. Chem., 2007, 2813–2826. DOI: 10.1002/ejic.200700021 (special 10th anniversary volume)
  236. -E. Jee, A. Comas-Vives, C. Dinoi, G. Ujaque, R. van Eldik*, A. Lledós*, R. Poli*: “Nature of Cp*MoO2+ in water and intramolecular proton transfer mechanism by stopped-flow kinetics and DFT calculations”, Inorg. Chem. 2007, 46, 4103-4113. DOI: 10.1021/ic062409g.
  237. Baya, J. Houghton, J.-C. Daran, R. Poli*, L. Male, A. Albinati, M. Guttman: “Synthesis, structure and electrochemical properties of sterically protected molybdenum trihydride redox pairs. A paramagnetic “stretched” dihydrogen complex?”, Chem. Eur. J. 2007, 13, 5347 – 5359. DOI: 10.1002/chem.200700293.
  238. Dinoi, G. Taban, P. Sözen, F. Demirhan, J.-C. Daran, R. Poli*: “Improved syntheses of [Cp*2Mo2O5] and [Cp*2W2O5]. Structural characterization of Na[Cp*MoO3]·5H2O and [Cp*2W2O5]”, J. Organomet. Chem. 2007, 692, 3743–3749. DOI: 10.1016/j.jorganchem.2007.05.021.
  239. Stoffelbach, R. Poli*, S. Maria, P. Richard: “How the interplay of different control mechanisms affects the initiator efficiency factor in controlled radical polymerization: an investigation using organometallic MoIII-based catalysts”, J. Organomet. Chem. 2007, 692, 3133-3143 DOI: 10.1016/j.jorganchem.2006.11.031 (special thematic volume on “One-Electron Organometallic Reactivity”).
  240. Dinoi, P. Sözen, G. Taban, D. Demir, F. Demirhan*, P. Prikhodchenko, J. Gun, O. Lev, J.-C. Daran, R. Poli*: “Aqueous reduction of [Cp*2W2O5]: characterization of the triangular clusters [Cp*3W3O4(OH)2]2+ and [Cp*3W3O6]+. Comparison with molybdenum”, Eur. J. Inorg. Chem. 2007, 4306-4316. DOI: 10.1002/ejic.200700419.
  241. Y. Lin, M. L. Coote*, A. Petit, P. Richard, R. Poli*, K. Matyjaszewski*: “Ab Initio Study of the Penultimate Effect for the ATRP Activation Step Using Propylene, Methyl Acrylate, and Methyl Methacrylate Monomers”, Macromolecules, 2007, 40, 5985-5994. DOI: 10.1021/ma070911u.
  242. Wolf, A. Labande*, J.-C. Daran, R. Poli: “Nickel(II), Palladium(II) and Rhodium(I) Complexes of New NHC-Thioether Ligands: Efficient Ketone Hydrosilylation Catalysis by a Cationic Rh Complex”, Eur. J. Inorg. Chem. 2007, 5069-5079. DOI: 10.1002/ejic.200700670.
  243. A. Braunecker, W. C. Brown, B. Morelli, R. Poli, K. Matyjaszewski*: “On the Origin of Activity in Cu, Ru, and Os Mediated Radical Polymerization” Macromolecules 2007, 40, 8576-8585. DOI: 0.1021/ma702008v.
  244. Poli*: “High Oxidation State Organomolybdenum and Organotungsten Chemistry in Protic Enviromnets”, Coord. Chem. Rev. 2008, 252, 1592-1612. DOI: 10.1016/j.ccr.2007.11.029.
  245. Malacea, L. Routaboul, E. Manoury*, J.-C. Daran, R. Poli*: “Palladium and Platinum Complexes with Planar Chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups” J. Organomet. Chem., 2008, 693, 1469–1477. DOI: 10.1016/j.jorganchem.2007.08.021 (special F.A. Cotton memorial issue).
  246. Debuigne, Y. Champouret, R. Jérôme, R. Poli*, C. Detrembleur*: “Mechanistic Insights into Cobalt Mediated Radical Polymerization (CMRP) of Vinyl Acetate via Cobalt(III) Adducts as Initiators”, Chem. Eur. J. 2008, 14, 4046–4059. DOI: 10.1002/chem.200701867.
  247. Agustin, J.-C. Daran*, R. Poli: “Polymorph of Dioxo-(N-salicylidene-2-aminoethanolato-N,O,O’)-((2-Nhydroxyethyliminomethyl) phenolato-O)-molybde­num(VI), Acta Cryst. C. 2008, C64, m101-m104. DOI: 10.1107/S0108270108000127.
  248. Ciclosi, C. Dinoi, L. Gonsalvi, M. Peruzzini, E. Manoury, R. Poli*: “Oxidation of thiophene derivatives with H2O2 in acetonitrile catalyzed by [Cp*2M2O5] (M = Mo, W): a kinetic study”, Organometallics 2008, 27, 2281–2286. DOI: 10.1021/om800035f.
  249. Baisch, R. Poli*: “Copper (I/II) and Cobalt (II) Coordination Chemistry of Relevance to Controlled Radical Polymerization Processes”, Polyhedron 2008, 27, 2175-2185. DOI: 10.1016/j.poly.2008.03.022.
  250. Wolf, A. Labande*, J.-C. Daran, R. Poli*: “Reactivity of phosphine-imidazolium salts toward [Ir(COD)Cl]2: preparation of new hydrido iridium(III) complexes bearing abnormal carbenes”, Eur. J. Inorg. Chem. 2008, 3024-3030. DOI: 10.1002/ejic.200800270.
  251. A. Dub, N. V. Belkova*, K. A. Lyssenko, G. A. Silantyev, L. M. Epstein, E. S. Shubina, J.-C. Daran, R. Poli*: “Synthesis and Protonation Studies of Cp*Os(dppe)H: kinetic vs thermodynamic control” Organometallics 2008, 27, 3307-3311. DOI: 10.1021/om8000235.
  252. Champouret, U. Baisch, R. Poli*, L. Tang, J. L. Conway, K. M. Smith*: “Homolytic bond strengths and formation rates in half-sandwich chrom­ium-alkyl complexes: relevance for controlled radical polymerization” Angew. Chem., Int. Ed. Engl. 2008, 47, 6069-6072. DOI: 10.1002/anie.200801498.
  253. Baya, J. Houghton, D. Konya, J.-C. Daran, K. Almeida, L. Schoon, W. P. Mul*, A. B. V. Oort, N. Meijboom, E. Drent, A. G. Orpen, R. Poli*: “Pd(I) phosphine carbonyl and hydride complexes implicated in the palladium-catalyzed oxo process”, J. Am. Chem. Soc. 2008, 130, 10612-10624. DOI: 10.1021/ja8012903.
  254. Debuigne, C. Michaux, C. Jérôme, R. Jérôme, R. Poli*, C. Detrembleur*: “Cobalt Mediated Radical Polymerization (CMRP) of Acrylonitrile: Kinetic Investigations and DFT Calculations”, Chem. Eur. J., 2008, 14, 7623-7637. DOI: 10.1002/chem.200800371.
  255. Malacea, E. Manoury*, J.-C. Daran, R. Poli*: “Synthesis, characterization and crystal structures of two new platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups”, J. Mol. Struct. 2008, 890, 249-254. DOI: 10.1016/j.molstruc.2008.04.007 (special issue dedicated to the memory of Professor F. Albert Cotton).
  256. V. Belkova, M. Besora, M. Baya, P. A. Dub, L. M. Epstein, A. Lledós*, R. Poli, P. O. Revin, E. S. Shubina*: “Effect of the metal atom nature on hydrogen bonding and proton transfer to [Cp*MH3(dppe)]: tungsten vs. Molybdenum”, Chem. Eur. J. 2008, 14, 9921-9934. DOI: 10.1002/chem.200801003.
  257. Wolf, R. Poli*, J.-H. Xie, J. Nichols, B. Xi, P. Zavalij and M. P. Doyle*: “Removal of Metal-Metal Bonding in a Dimetallic Paddlewheel Complex – Molecular and Electronic Structure of Bis(phenyl) Dirhodium(III) Carboxamidate Compounds”, Organometallics 2008, 27, 5836-5845. DOI: 10.1021/om800631b.
  258. Baya, P. A. Dub, J. Houghton, J.-C. Daran, N. V. Belkova, E. S. Shubina*, L. M. Epstein, A. Lledós*, R. Poli*: “Investigation of the [Cp*Mo(PMe3)3H]n+ (n = 0, 1) redox pair: dynamic processes on very different timescales”, Inorg. Chem., 2009, 48, 209-220. DOI: 10.1021/ic801676n.
  259. Debuigne*, R. Poli*, C. Jérôme, R. Jérôme, C. Detrembleur: “Overview of Cobalt-Mediated Radical Polymerization: Roots, State of the Art and Future Prospects”, Prog. Polym. Sci., 2009, 34, 211-239. DOI: 10.1016/j.progpolymsci.2008.11.003.
  260. Gülcemal, A. Labande*, J.-C. Daran, B. Çetinkaya, R. Poli: “Rhodium(I) complexes of new ferrocenyl benzimidazol-2-ylidene ligands. The importance of chelating effect for ketone hydrosilylation catalysis.”, Eur. J. Inorg. Chem. 2009, 1806-1815. DOI: 10.1002/ejic.200801163.
  261. Santhosh Kumar K. S., Y. Gnanou*, Y. Champouret, J.-C. Daran, R. Poli*: “Radical Polymerization of Vinyl Acetate with Bis(tetramethylheptadionato)cobalt(II): the Cohabitation of Three Different Mechanisms”, Eur. J. 2009, 15, 4874-4885. DOI: 10.1002/chem.200802388.
  262. A. Dub, O. A. Filippov, N. V. Belkova, M. Rodriguez-Zubiri, R. Poli*: “Experimental (IR, Raman) and computational analysis of a series of PtBr2 derivatives: vibrational coupling in the coordinated ethylene and Pt-Br modes” J. Phys. Chem. A. 2009, 6348–6355. DOI: 10.1021/jp902394j.
  263. Li, K. S. Santhosh Kumar, Y. Gnanou*, U. Baisch, Y. Champouret, R. Poli*, K. C. D. Robson and W. S. McNeil: “Electronic and Steric Ligand Effects in the Radical Polymerization of Vinyl Acetate Mediated by b-Ketoiminate Complexes of Cobalt(II)”, Chem. Asian J., 2009, 4, 1257–1265. DOI: 10.1002/asia.200900084.
  264. A. Dub, M. Rodriguez-Zubiri, J.-C. Daran, J.-J. Brunet, R. Poli*: “The Pt-catalyzed ethylene hydroamination with aniline: Synthesis, Characterization and Studies of Intermediates”, Organometallics, 2009, 28, 4764–4777. DOI: 10.1021/om9002494.
  265. Agustin*, C. Bibal, B. Neveux, J.-C. Daran, R. Poli: “Structural Characterization and Theoretical Calculations of cis-Dioxo(N-salicylidene-2-aminophenolato)(ethanol)­molybdenum(VI) complexes MoO2(SAP)(EtOH) (SAP = N-salicylidene-2 amino­pheno­lato)” Z. Anorg. Allg. Chem., 2009, 635, 2120–2125. DOI: 10.1002/zaac.200900185.
  266. Taban-Çaliskan, D. Agustin*, F. Demirhan*, L. Vendier and R. Poli*: “Rational, facile synthesis and characterization of the neutral mixed-metal organometallic oxides Cp*2MoxW6-xO17 (Cp* = C5Me5 , x = 0, 2, 4, 6)”, Eur. J. Inorg. Chem., 2009, 5219–5226. DOI: 10.1002/ejic.200900676.
  267. Poli*: “The Elucidation of Mechanisms in Homogeneous Catalysis”, Comments Inorg. Chem. 2009, 30, 177–228. DOI: 10.1080/02603590903423942. (invited “technique article”).
  268. Benhamou, J. Wolf, V. César, A. Labande, R. Poli, N. Lugan, G. Lavigne*: “Chelation-assisted reactions of phosphine- and olefin-functionalized imidazolium derivatives and their affiliated N-heterocyclic carbenes with Roper’s complex Ru(CO)2(PPh3)3”, Organometallics, 2009, 28, 6981–6993. DOI: 10.1021/om900813p.
  269. Malacea, R. Poli*, E. Manoury*: “Asymmetric hydrosilylation, transfer hydrogenation and hydrogenation of ketones catalyzed by iridium complexes”, Coord. Chem. Rev. 2010, 254, 729-752. DOI: 10.1016/j.ccr.2009.09.033 (special volume dedicated to Prof. F. Calderazzo’s 80th birthday).
  270. A. Dub, N. V. Belkova, O. A. Filippov, J.-C. Daran, L. M. Epstein, A. Lledós, E. S. Shubina*, R. Poli*: “Solvent dependent dihydrogen/dihydride stability for [Cp*Mo(CO)­(PMe3)2H2]+[BF4] determined by multiple solvent∙∙∙anion∙∙∙cation non-covalent interactions”, Chem. Eur. J., 2010, 16, 189-201. DOI: 10.1002/chem.200901613.
  271. Bibal*, J.-C. Daran, S. Deroover, R. Poli: “Ionic Schiff Base Dioxidomolybdenum(VI) Complexes as Catalysts in Ionic Liquid Media for Cyclooctene Epoxidation”, Polyhedron 2010, 29, 639-647. DOI: 10.1016/j.poly.2009.09.001 (special “2009 Young Investigator Issue”).
  272. Champouret, K. C. MacLeod, U. Baisch, B. O. Patrick, K. M. Smith*, R. Poli*: “Cyclopentadienyl Chromium ß-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate”, Organometallics, 2010, 29, 167–176. DOI: 10.1021/om900869p.
  273. Debuigne*, R. Poli, J. D. Winter, P. Laurent, P. Gerbaux, P. Dubois, W. Jean-Paul, C. Jérôme and C. Detrembleur: “Cobalt-Mediated Radical Coupling (CMRC): An Unusual Route to Mid-chain-functionalized Symmetrical Macromolecules”, Chem. Eur. J. 2010, 16, 1799-1811. DOI: 10.1002/chem.200902618.
  274. Comas-Vives, A. Lledós*, R. Poli*: “A computational study of the olefin epoxidation mechanism catalyzed by cyclopentadienyloxidomolybdenum(VI) complexes”, Chem. Eur. J. 2010, 16, 2147-2158. DOI: 10.1002/chem.200902873.
  275. A. Dub, O. A. Filippov, N. V. Belkova*, J.-C. Daran, L. M. Epstein, R. Poli*, E. S. Shubina: “Hydrogen bonding to carbonyl hydride complex Cp*Mo(PMe3)2(CO)H and its role in proton transfer”, Dalton 2010, 36, 2008-2015. DOI: 10.1039/b916084A.
  276. Champouret, R. Poli, J.-C. Daran*: “Tris(1,1,1,5,5,5-hexafluoro­acetyl­acetonate)­moly­bde­num(III)”, Acta Cryst. E., 2010, E66, m299-m300. DOI: 10.1107/S1600536810005489.
  277. A. Dub, O. A. Fillipov, G. A. Silantyev, N. V. Belkova*, J.-C. Daran, L. M. Epstein, R. Poli*, E. S. Shubina*: “Protonation of Cp*M(dppe)H hydrides: peculiarities of the osmium congener”, Eur. J. Inorg. Chem., 2010, 1489–1500. DOI: 10.1002/ejic.200901120.
  278. Debono, A. Labande*, E. Manoury, J.-C. Daran, R. Poli: “Palladium Complexes of Planar Chiral Ferrocenyl Phosphine-NHC Ligands: New Catalysts for the Asymmetric Suzuki-Miyaura Reaction”, Organometallics, 2010, 29, 1879–1882. DOI: 10.1021/om100125k.
  279. Debuigne*, R. Poli, J. D. Winter, P. Laurent, P. Gerbaux, J.-P. Wathelet, C. Jérôme, C. Detrembleur: “Effective Cobalt-Mediated Radical Coupling (CMRC) of Poly(vinyl acetate) and Poly(N-vinylpyrrolidone) (Co)polymers Precursors”, Macromolecules, 2010, 43, 2801-2813. DOI: 10.1021/ma902610m.
  280. A. Dub, R. Poli*: “A computational study of solution equilibria of platinum-based ethylene hydroamination catalytic species including solvation and counterion effects: Proper treatment of the free energy of solvation”, J. Mol. Catal. A, 2010, 324, 89-96. DOI: 10.1016/j.molcata.2010.03.003.
  281. Dinoi, M. F. C. Guedes da Silva, E. C. B. Alegria, P. Smoleński, L. M. D. R. S. Martins, R. Poli, A. J. L. Pombeiro*: “Molybdenum complexes bearing the tris(1-pyrazolyl)­methane­sulfonate ligand: synthesis, characterization and electrochemical behavior”, Eur. J. Inorg. Chem. 2010, 2415-2424. DOI: 10.1002/ejic.201000018.
  282. Dinoi, M. Ciclosi, E. Manoury, L. Maron, L. Perrin*, R. Poli*: “Olefin epoxidation by H2O2/MeCN catalyzed by cyclopentadienyloxidotungsten(VI) and molybdenum(VI) complexes: experiments and computations”, Chem. Eur. J. 2010, 16, 9572–9584. DOI: 10.1002/chem.201000298.
  283. Audin, J.-C. Daran, E. Deydier*, E. Manoury*, R. Poli: “New ferrocenyl P,O ligands with polar substituents”, C.R. Chimie, 2010, 13, 890-899. DOI: 10.1016/j.crci.2010.05.005.
  284. A. Dub, M. Rodriguez-Zubiri, C. Baudequin, R. Poli*: “Hydroamination of ethylene by aniline: catalysis in water”, Green Chem., 2010, 1392-1396. DOI: 10.1039/c004727a.
  285. Champouret, K. C. MacLeod, K. M. Smith, R. Poli*: “Controlled Radical Polymerization of Vinyl Acetate with Cyclopentadienyl Chromium ß-Diketiminate Complexes: ATRP vs. OMRP”, Organometallics, 2010, 29, 3125–3132. DOI: 10.1021/om1002649.
  286. A. Dub, R. Poli*: “The Pt-catalyzed ethylene hydroamination by aniline: a Computational Investigation of the Catalytic Cycle”, J. Am. Chem Soc. 2010, 132, 13799–13812. DOI: 10.1021/ja1051654.
  287. Piché, J.-C. Daigle, R. Poli, J. P. Claverie*: “Investigation of steric and electronic factors in palladium aryl sulfonate phosphine ethylene polymerization catalysts”, Eur. J. Inorg. Chem. 2010, 4595–4601. DOI: 10.1002/ejic.201000533.
  288. Cordelle, D. Agustin*, J.-C. Daran, R. Poli*: “Oxo-bridged bis oxo-vanadium(V) complexes with tridentate Schiff base ligands (VOL)2O (L= SAE, SAMP, SAP): synthesis, structure and epoxidation catalysis under solvent-free conditions”, Inorg. Chim. Acta 2010, 364, 144-149. DOI: 10.1016/j.ica.2010.09.021 (special issue in honor of Arnold L. Rheingold).
  289. -C. Daran*, C. Audin, E. Deydier, E. Manoury, R. Poli: “1-(Diphenylphosphinothioyl)-2-[ (4-methylphenyl)methoxymethyl]ferrocene”, Acta Cryst. E, 2010, E66, m1417–m1418. DOI: 10.1107/S1600536810040791.
  290. A. Dub, J.-C. Daran, V. A. Levina, N. V. Belkova, E. S. Shubina, R. Poli*: “Modeling the platinum-catalyzed intermolecular hydroamination of ethylene: the nucleophilic addition of HNEt2 to coordinated ethylene in trans-PtBr2(C2H4)(HNEt2)”, J. Organomet. Chem. 2011, 696, 1174-1183. DOI: 10.1016/j.jorganchem.2010.09.043 (special issue on the occasion of the 24th ICOMC).
  291. Poli*: “Ruthenium and Osmium Metalloradicals”, Angew. Chem., Int. Ed. Engl., 2011, 50, 43-45. DOI: 10.1002/anie.201002715 (invited Highlight).
  292. Sözen, J.-C. Daran, E. Manoury, F. Demirhan, R. Poli*: “Reaction of [Cp*2W2O5] with mercaptocarboxylic acids: addition rather than reduction. Isolation and characterization of Cp*WO2(SCH2CH2COOH)”, J. Organomet. Chem. 2011, 696, 2275-2279. DOI: 10.1016/j.jorganchem.2010.12.002.
  293. Gulli, J.-C. Daran, R. Poli*: “Synthesis and structure of 4-coordinate copper(II) complexes stabilized by b-ketiminato ligands and application in the reverse ATRP of styrene”, Eur. J. Inorg. Chem. 2011, 1666-1672. DOI: 10.1002/ejic.201001203.
  294. Poli*: “Radical coordination chemistry and its relevance to metal-mediated radical polymerization”, Eur. J. Inorg. Chem., 2011, 1513-1530. DOI: 10.1002/ejic.201001364 (invited Microreview).
  295. Aullón, K. Gómez, G. González, S. Jansat, M. Martínez*, R. Poli, M. Rodríguez-Zubiri: “Kinetico-Mechanistic Information about Alkene Hydroamination with Aniline in Bromide-rich Ionic Media: Importance of Solvolysis”, Inorg. Chem. 2011, 50, 5628-5636. DOI: 10.1021/ic2003222.
  296. Labande*, J.-C. Daran, N. J. Long*, A. J. P. White, R. Poli: “Rhodium(III) and ruthenium(II) complexes of redox-active, chelating N-heterocyclic carbene/thioether ligands”, New J. Chem. 2011, 35, 2162–2168. DOI: 10.1039/C1NJ20224C.
  297. Pisk, D. Agustin*, V. Vrdoljak, R. Poli: “Epoxidation Processes by Pyridoxal Dioxomolybdenum(VI) (Pre)Catalysts Without Organic Solvent”, Adv. Synth. Catal., 2011, 353, 2910-2914. DOI: 10.1002/adsc.201100439.
  298. Xue, J.-C. Daran, Y. Champouret, R. Poli*: “Ligand adducts of bis(acetyl­acetonato)­iron(II): a 1H NMR study”, Inorg. Chem., 2011, 50, 11543−11551. DOI: 10.1021/ic201486v.
  299. A. Dub, A. Béthegnies, R. Poli*: “Reactions of diethylamine and ethylene catalyzed by PtII or Pt0: transalkylation vs. hydroamination”, Eur. J. Inorg. Chem. 2011, 5167–5172. DOI: 10.1002/ejic.201100624.
  300. Béthegnies, V. A. Levina, O. A. Filippov, J.-C. Daran, N. V. Belkova, E. S. Shubina, R. Poli*: “Coordination and organometallic chemistry of relevance to the rhodium based catalyst for ethylene hydroamination”, Inorg. Chem., 2011, 50, 12539–12552. DOI: 10.1021/ic201508m.
  301. Dinoi, R. Poli, L. Perrin*, L. Maron*: “Mechanistic insights into β-oxygen atom transfer in olefin epoxidation mediated by W(VI) complexes and H2O2”, Dalton Trans., 2012, 41, 1131-1133. DOI: 10.1039/C1DT10924C.
  302. A. Dub, A. Béthegnies, R. Poli*: “DFT and experimental studies on the PtX2/X-catalyzed olefin hydroamination: effect of halogen, amine basicity and olefin on activity, regioselectivity and catalyst deactivation”, Organometallics, 2012, 31, 294–305. DOI: 10.1021/om2009149.
  303. Pisk, B. Prugovečki, D. Matković-Čalogović, R. Poli, D. Agustin*, V. Vrdoljak*: “Charged Dioxomolybdenum(VI) Complexes with Pyridoxal Thiosemicarbazone Ligands as Oxygen Atom Transfer Agents and Epoxidation (pre)Catalyst”, Polyhedron, 2012, 33, 441-449. DOI: 10.1016/j.poly.2011.12.003.
  304. Champouret, S. Gulli, J.-C. Daran, R. Poli*: “Preparation of Diamine-b-diketiminato Copper(II) Complexes and their Application in Reverse Atom-Transfer Radical Polymerization of Styrene”, Eur. J. Inorg. Chem. 2012, 1672-1679. DOI: 10.1002/ejic.201200008.
  305. Carletto, A. F. Cardozo, R. Suriano, E. Manoury, S. Turri, R. Poli*: “Core cross-linked amphiphilic star-block copolymers with (meth)acrylic acid shells prepared by atom transfer radical polymerization”, Isr. J. Chem. 2012, 2012, 52, 328–338. DOI: 10.1002/ijch.201100125 (special issue dedicated to the Wolf prize of Krzysztof Matyjaszewski).
  306. A. Dub, A. Béthegnies, J.-C. Daran, R. Poli*: “Formation and Structure of a Platinum(II) Complex Containing two trans Nonstabilized Phosphorus Ylide Ligands: Evidence for Reversible Ylide Dissociation”, Organometallics, 2012, 31, 3081–3086. DOI: 10.1021/om2012453.
  307. Taban-Çalışkan, D. M. Fernandes, J.-C. Daran, D. Agustin*, F. Demirhan, R. Poli*: “Rational synthesis and characterization of the mixed-metal organometallic polyoxometalates [Cp*MoxW6-xO18] (x = 0, 1, 5, 6)”, Inorg. Chem., 2012, 51, 5931–5940. DOI: 10.1021/ic300578g.
  308. Morlot, N. Uyttebroeck, D. Agustin*, R. Poli*: “Solvent-free epoxidation of olefins catalyzed by “[MoO2(SAP)]”: a new mode of TBHP activation”, ChemCatChem. 2013, 5, 601-611. DOI: 10.1002/cctc.201200068 (invited contribution to a thematic issue on the occasion of the XIII Netherlands Catalysis and Chemistry Conference).
  309. M. Kozinets, O. Koniev, O. A. Filippov, J.-C. Daran, R. Poli, E. S. Shubina, N. V. Belkova*, E. Manoury*: “Coordination chemistry of diphenylphosphinoferrocenylthioethers on cyclooctadiene and norbornadiene rhodium(I) platforms”, Dalton Trans., 2012, 41, 11849-11859. DOI: 10.1039/C2DT30993A.
  310. Debuigne*, A. Morin, A. Kermagoret, Y. Piette, C. Detrembleur, C. Jérôme, R. Poli*: “Key Role of Intramolecular Metal Chelation and Hydrogen Bonding in the Cobalt-Mediated Radical Polymerization of N-Vinyl amides”, Chem. Eur. J. 2012, 18, 12834–12844. DOI: 10.1002/chem.201201456.
  311. Piette, A. Debuigne, C. Jérôme, V. Bodart, R. Poli, C. Detrembleur*: “Cobalt-Mediated Radical (Co)polymerization of Vinyl Chloride and Vinyl Acetate”, Polym. Chem. 2012, 3, 2880-2891. DOI: 10.1039/C2PY20413D.
  312. -M. Wei, M. García-Melchor, J.-C. Daran, C. Audin, A. Lledós, R. Poli, E. Deydier*, E. Manoury*: “Coordination chemistry of new chiral P,N ferrocenyl ligands with half-sandwich Ruthenium(II), Rhodium(III) and Iridium(III) complexes”, Organometallics, 2012, 31, 6669-6680. DOI: 10.1021/om300738q.
  313. Schröder, D. Konkolewicz, R. Poli, K. Matyjaszewski*: “Formation and Possible Reactions of an Organometallic Intermediate with Active Copper(I) Catalysts in an ATRP”, Organometallics 2012, 31, 7994-7999. DOI: 10.1021/om3006883.
  314. Béthegnies, R. Poli*: “Convenient high-pressure syntheses of [PtX3(C2H4)] (X = Cl, Br) salts with a variety of organic cations from PtX2”, J. Organometal. Chem., 2013, 730, 165-167. DOI: 10.1016/j.jorganchem.2012.12.017.
  315. Béthegnies, J.-C. Daran, R. Poli*: “Platinum-catalyzed hydroamination of ethylene: study of the catalyst decomposition mechanism”, Organometallics, 2013, 32, 673-681. DOI: 10.1021/om301182x.
  316. F. Cardozo, E. Manoury, C. Julcour, J.-F. Blanco, H. Delmas, F. Gayet, R. Poli*: “Preparation of Polymer Supported Phosphine Ligands by Metal Catalyzed Living Radical Copolymerization and Their Application to Hydroformylation Catalysis”, ChemCatChem, 2013, 5, 1161–1169. DOI: 10.1002/cctc.201200446 (special issue dedicated to the 18th International Symposium on Homogeneous Catalysis).
  317. Sözen-Aktaş, I. Del Rosal, E. Manoury, F. Demirhan, A. Lledos*, R. Poli*: “Speciation of [Cp*2M2O5] in polar and donor solvents”, Chem. Eur. J., 2013, 19, 3969–3985. DOI: 10.1002/chem.201203075.
  318. Béthegnies, P. A. Dub, R. Poli*: “Platinum-catalyzed assembly of quinaldine from aniline and ethylene”, Organometallics, 2013, 32, 1882–1891. DOI: 10.1021/om400020k.
  319. Labande*, N. Debono, A. Sournia-Saquet, J.-C. Daran, R. Poli: “Oxidation-Promoted Activation of a Ferrocene C-H Bond by a Rhodium Complex”, Dalton Trans., 2013, 42, 6531-6537. DOI: 10.1039/c3dt50240f.
  320. F. Cardozo, E. Manoury, C. Julcour, J.-F. Blanco, H. Delmas, F. Gayet, R. Poli*: “Preparation of Phosphine-Functionalized Polystyrene Stars by Metal Catalyzed Controlled Radical Copolymerization and Their Application to Hydroformylation Catalysis”, Dalton Trans., 2013, 42, 9148-9156. DOI: 10.1039/c3dt33082f (special thematic issue on “Advances in Metal-Catalysed Polymerisation and Related Transformations”).
  321. Sözen-Aktaş, E. Manoury, F. Demirhan, R. Poli*: “Molybdenum versus Tungsten for the epoxidation of cyclooctene catalyzed by [Cp*2M2O5]”, Eur. J. Inorg. Chem. 2013, 2728–2735. DOI: 10.1002/ejic.201300260.
  322. Malacea, J.-C. Daran, R. Poli and E. Manoury*: “Combining planar and central chirality in ferrocene phosphine sulfoxide ligands”, Tetrahedron Asymm. 2013, 24, 612-620. DOI: 10.1016/j.tetasy.2013.04.002.
  323. N. Morin, C. Detrembleur, C. Jérôme, P. D. Tullio, R. Poli*, A. Debuigne*: “Effect of head-to-head addition in vinyl acetate controlled radical polymerization: why is Co(acac)2-mediated polymerization so much better?”, Macromolecules 2013, 46, 4303–4312. DOI: 10.1021/ma400651a.
  324. Dayan, N. Ozpozan Kalaycioglu*, J.-C. Daran, A. Labande, R. Poli: “Synthesis and characterization of half-sandwich ruthenium complexes containing aromatic sulfonamides bearing pyridinyl rings: catalysts for transfer hydrogenation of acetophenone derivatives”, Eur. J. Inorg. Chem. 2013, 3224–3232. DOI: 10.1002/ejic.201300266.
  325. M. Kozinets, N. V. Belkova*, E. S. Shubina, R. Poli, E. Manoury*: “Iridium and rhodium complexes with the chiral planar phosphine-thioether ligands in asymmetric hydrogenation of ketones and imines”, Russ. Chem. Bull. 2013, 750-756. DOI: 10.1007/s11172-013-0102-5 (special issue dedicated to Prof. Irina P. Beletskaya’s 80th birthday).
  326. Xue, R. Poli*: “Organometallic Mediated Radical Polymerization of Vinyl Acetate with Fe(acac)2”, J. Polym. Sci. Polym. Chem. 2013, 51,3494–3504. DOI: 10.1002/pola.26751.
  327. M. Kozinets, M. Fekete, O. A. Filippov, N. V. Belkova*, E. S. Shubina, R. Poli*, S. B. Duckett*, E. Manoury*: “Activation of a (cyclooctadiene)rhodium(I) complex supported by a chiral ferrocenyl phosphine thioether ligand for hydrogenation catalysis: a parahydrogen NMR study”, Dalton Trans. 2013, 42, 11720-11730. DOI: 10.1039/c3dt51429c.
  328. Guérin, D. Mesquita Fernandes, J.-C. Daran, D. Agustin*, R. Poli*: “Investigation of induction times, activity, selectivity, interface and mass transport in solvent-free epoxidation by H2O2 and TBHP: a study with organic salts of the [PMo12O40]3- anion”, New. J. Chem. 2013, 37, 3466-3475. DOI: 10.1039/c3nj00523b (special issue dedicated to the retirement of Bernard Meunier).
  329. Zhang, K. Schröder, Y. Kwak, P. Krys, A. N. Morin, T. Pintauer, R. Poli, K. Matyjaszewski*: “Reversible-Deactivation Radical Polymerization of Methyl Methacrylate and Styrene Mediated by Alkyl Dithiocarbamates and Copper Acetylacetonates”, Macromolecules 2013, 46, 5512–5519. DOI: 10.1021/ma400539s.
  330. Loxq, N. Debono, S. Gülcemal, J.-C. Daran, E. Manoury, A. Labande*, R. Poli, B. Çetinkaya: “Palladium(II) complexes with planar chiral ferrocenyl phosphane–(benz)imidazol-2-ylidene ligands”, New J. Chem. 2014, 38, 338-347. DOI: 10.1039/c3nj00863k.
  331. Bhaumik, E. Manoury, J.-C. Daran, P. Sözen-Atkaş, F. Demirhan and R. Poli*: “Investigation of the reaction of [Cp*2M2O5] (M = Mo, W) with hydrogen peroxide and tert-butylhydroperoxide in MeCN; implications for olefin epoxidation catalyzed by organomolybdenum and organotungsten compounds”, J. Organomet. Chem. 2014, 760, 115-123. DOI: 10.1016/j.jorganchem.2013.11.029 (special issue dedicated to the 65th birthday of Maria-José Calhorda).
  332. Poli*, S. Maria: “Ether Complexes of Molybdenum(III) and Molybdenum(IV) Chloride”, Inorg. Synth. 2014, 36, 16-19. DOI: 10.1002/9781118744994.ch03.
  333. Loubidi, D. Agustin*, A. Benharref, R. Poli: “Solvent free epoxidation of himachalenes and their derivatives by TBHP using [MoO2(SAP)]2 as catalyst”, C. R. Chim. 2014, 17, 549–556. DOI: 10.1016/j.crci.2014.01.023.
  334. Poli*, M. P. Shaver: “ATRP and OMRP of Styrene Mediated by Diaminobis(phenolato)iron(II) Complexes: A DFT Study”, Inorg. Chem. 2014, 53, 7580–7590. DOI: 10.1021/ic5009347.
  335. Poli*, L. E. N. Allan, M. P. Shaver*: “Iron-Mediated Reversible Deactivation Radical Polymerisation”, Prog. Polym. Sci. 2014, 39, 1827–1845. DOI: 10.1016/j.progpolymsci.2014.06.003.
  336. Wang, T. Vanderbeeken, D. Agustin* R. Poli*: “Tridentate ONS vs ONO salicylideneamino(thio)phenolato [MoO2L] complexes for catalytic solvent-free epoxidation with aqueous TBHP”, Catal. Commun. 2015, 63, 26-30. DOI: 10.1016/j.catcom.2014.08.018 (invited contribution to a thematic issue dedicated to catalysis in alternative solvents and neoteric media).
  337. Debono, J.-C. Daran, R. Poli, A. Labande*: “A rhodium(I) dicarbonyl complex with a redox-active ferrocenyl phosphine-NHC ligand: enhanced reactivity of the metal centre through ferrocene oxidation, Polyhedron, 2015, 86, 57-63. DOI: 10.1016/j.poly.2014.04.050 (special issue dedicated to the retirement of Claude Lapinte).
  338. Zhang, A.F. Cardozo, S. Chen, W. Zhang, C. Julcour, M. Lansalot, J.-F. Blanco, F. Gayet, H. Delmas, B. Charleux, E. Manoury*, F. D’Agosto*, R. Poli*: “Core-​Shell Nanoreactors for Efficient Aqueous Biphasic Catalysis”, Chem. Eur. J. 2014, 20, 15505-15517. DOI: 10.1002/chem.201403819.
  339. Chen, E. Manoury, R. Poli*: “Slow exchange of bidentate ligands between rhodium(I) complexes: evidence of both neutral and anionic ligand exchange”, Eur. J. Inorg. Chem., 2014, 5820–5826. DOI: 10.1002/ejic.201402810.
  340. Bayda, A. Cassen, J.-C. Daran, C. Audin, R. Poli, E. Manoury, E. Deydier*: “Synthesis and characterization of new chiral P,O ferrocenyl ligands and catalytic application to asymmetric Suzuki-Miyaura coupling”, J. Organomet. Chem. 2014, 772-773, 258-264. DOI: 10.1016/j.jorganchem.2014.09.027.
  341. Poli*, M. P. Shaver: “ATRP/OMRP/CCT Interplay in Styrene Polymerization Mediated by Iron(II) Complexes: a DFT Study of the α-Diimine System”, Chem. Eur. J. 2014, 20, 17530–17540. DOI: 10.1002/chem.201404208.
  342. Loxq, J.-C. Daran, E. Manoury, R. Poli, A. Labande*: “Bifunctional N-Heterocyclic Carbene/Amine Ferrocenyl Ligands: Synthesis and Palladium(II) Complexes”, Eur. J. Inorg. Chem. 2015, 609-616. DOI: 10.1002/ejic.201403001.
  343. Wang, T. Guerrero, S. R. Merecias, H. García-Ortega, R. Santillan, J.-C. Daran, N. Farfán*, D. Agustin*, R. Poli*: “Substituent effects on solvent-free epoxidation catalyzed by dioxomolybdenum(VI) complexes supported by ONO Schiff base ligands”, Inorg. Chim. Acta 2015, 431, 176-183. DOI: 10.1016/j.ica.2014.12.022 (special issue entitled “Advances in transition metals catalysis”).
  344. F. Cardozo, C. Julcour*, L. Barthe, J.-F. Blanco, S. Chen, F. Gayet, E. Manoury, X. Zhang, M. Lansalot, B. Charleux, F. D’Agosto, R. Poli, H. Delmas: “Aqueous phase homogeneous catalysis using core-shell nanoreactors: application to rhodium catalyzed hydroformylation of 1-octene”, J. Catal., 2015, 324, 1-8. DOI: 10.1016/j.jcat.2015.01.009.
  345. Chen, A. F. Cardozo, C. Julcour, J.-F. Blanco, L. Barthe, F. Gayet, B. Charleux, M. Lansalot, F. D’Agosto, H. Delmas, E. Manoury*, R. Poli*: “Amphiphilic Core-Cross-linked Micelles functionalized with Bis(4-methoxyphenyl)phenylphosphine as catalytic nanoreactors for biphasic hydroformylation”, Polymer 2015, 72, 327-335. DOI: 10.1016/j.polymer.2015.02.024 (special issue on the occasion of Krzysztof Matyjaszewski’s 65th birthday).
  346. Poli*: “New phenomena in organometallic-mediated radical polymerization (OMRP) and perspectives for control of less active monomers”, Chem. Eur. J. 2015, 21, 6988-7001. DOI: 10.1002/chem.201500015 (invited Concept article).
  347. Pisk, J.-C. Daran, R. Poli, D. Agustin*: “Pyridoxal based ONS and ONO vanadium(V) complexes: structural analysis and catalytic application in solvent free epoxidation”, J. Mol. Catal. A 2015, 403, 52-63. DOI: 10.1016/j.molcata.2015.03.016.
  348. Biosca, M. Coll, F. Lagarde, E. Brémond, L. Routaboul, E. Manoury*, O. Pàmies, R. Poli, M. Diéguez*: “Ferrocene-based P-S ligands for Ir-catalyzed hydrogenation of minimally functionalized olefins. Scope and limitations”, Tetrahedron, 2016, 72, 2623-2631. DOI: 10.1016/j.tet.2015.01.047.
  349. M. Hayes, E. Deydier, G. Ujaque, A. Lledós*, R. Malacea-Kabbara, E. Manoury, S. Vincendeau, R. Poli*: “Ketone Hydrogenation with Iridium Complexes with “non N-H” Ligands: the Key Role of the Strong Base”, ACS Catal., 2015, 5, 4368–4376. DOI: 10.1021/acscatal.5b00613.
  350. Laborde, M.-M. Wei, A. van der Lee, E. Deydier, J.-C. Daran, J.-N. Volle, R. Poli, J.-L. Pirat, E. Manoury*, D. Virieux*: “Double [3+2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes”, Dalton Trans., 2015, 44, 12539-12545. DOI: 10.1039/C5DT02197A.
  351. Michelot, S. Sarda*, C. Audin, E. Deydier, E. Manoury, R. Poli, C. Rey: “Spectroscopic characterisation of hydroxyapatite and nanocrystalline apatite with grafted aminopropyltriethoxysilane: nature of silane-surface interaction”, J. Mater. Sci. 2015, 50, 5746-5757. DOI: 10.1007/s10853-015-9122-x.
  352. Loxq, E. Manoury, R. Poli, E. Deydier*, A. Labande*: “Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals”, Coord. Chem. Rev., 2016, 308, 131–190. DOI: 10.1016/j.ccr.2015.07.006 (special volume dedicated to the 40th anniversary of LCC).
  353. Labande*, E. Deydier*, E. Manoury*, J.-C. Daran, C. Audin, R. Poli: “Contribution of heterobifunctional ligands to transition metal-catalyzed C-C coupling reactions”, Turk. J. Chem. 2015, 39, 1158-1170. DOI: 10.3906/kim-1507-73.
  354. M. W. Rahaman, K. Matyjaszewski, R. Poli*: “Comparison of cobalt(III) and copper(II) hydrides at the crossroad of catalyzed chain transfer and catalyzed radical termination: a DFT study”, Polym. Chem. 2016, 7, 1079-1087. DOI: 10.1039/C5PY01837D.
  355. Chen, E. Manoury, F. Gayet, R. Poli*: “Coordination chemistry inside polymeric nanoreactors: metal migration and cross-exchange in amphiphilic core-shell polymer latexes”, Polymers 2016, 8, 26/1-18. DOI: 10.3390/polym8020026.
  356. Wang, J.-C. Daran, R. Poli, D. Agustin*: “OH-Substituted Tridentate ONO Schiff base ligands and related molybdenum(VI) complexes for solvent-free (ep)oxidation catalysis with TBHP as oxidant”, J. Mol. Catal. A, 2016, 416, 117-126. DOI: 10.1016/j.molcata.2016.02.021.
  357. Chen, F. Gayet, E. Manoury, A. Joumaa, M. Lansalot, F. D’Agosto, R. Poli*: “Coordination chemistry inside polymeric nanoreactors: interparticle metal exchange and ionic compound vectorization in phosphine-functionalized amphiphilic polymer latexes”, Chem. Eur. J. 2016, 22, 6302-6313. DOI: 10.1002/chem.201504923.
  358. Karpus, O. Yesypenko, V. Boiko, R. Poli, J.-C. Daran, Z. Voitenko*, V. Kalchenko*, E. Manoury*: “Chiral Phosphinoferrocenyl‐Calixarenes”, Eur. J. Org. Chem. 2016, 3386–3394. DOI: 10.1002/ejoc.201600208.
  359. Guerre, S. M. W. Rahaman, B. Améduri, R. Poli,* V. Ladmiral*: “The Limits of Vinylidene Fluoride RAFT Polymerization”, Macromolecules, 2016, 49, 5386-5396. DOI: 10.1021/acs.macromol.6b01087.
  360. Lobry, A. F. Cardozo, L. Barthe, J.-F. Blanco, H. Delmas, S. Chen, F. Gayet, X. Zhang, M. Lansalot, F. D’Agosto, R. Poli*, E. Manoury*, C. Julcour*: “Core phosphine-functionalized amphiphilic nanogels as catalytic nanoreactors for aqueous biphasic hydroformylation”, J. Catal. 2016, 342, 164-172. DOI: 10.1016/j.jcat.2016.07.023.
  361. Bhaumik, D. Stein, S. Vincendeau, R. Poli*, E. Manoury*: “Oxidation of alcohols by TBHP in the presence of sub-stoichiometric amounts of MnO2”, C. R. Chim. 2016, 19, 566-570. DOI: 10.1016/j.crci.2016.02.012.
  362. G. Ribelli, S. M. W. Rahaman, K. Matyjaszewski*, R. Poli*: “Effect of Ligand Structure on CuII‐R Dormant Species and its Consequences for Catalytic Radical Termination and ATRP”, Macromolecules, 2016, 49, 7749-7757. DOI: 10.1021/acs.macromol.6b01334.
  363. M. W. Rahaman, J.-C. Daran, E. Manoury, R. Poli*: “The cyclooctadiene ligand in [IrCl(COD)]2 is hydrogenated under transfer hydrogenation conditions: a study in the presence of PPh3 and a strong base in isopropanol”, J. Organometal. Chem., 2017, 829, 14-21. DOI: 10.1016/j.jorganchem.2016.10.009 (“Frontiers in Organometallic Chemistry” special issue).
  364. Guerre, S. M. W. Rahaman, B. Améduri, R. Poli,* V. Ladmiral*: “RAFT synthesis of PVDF-b-PVAc block copolymers”, Polym. Chem. 2016, 7, 6918-6933. DOI: 10.1039/C6PY01247G.
  365. M. Titova, S. M. W. Rahaman, E. S. Shubina, R. Poli, N. V. Belkova*, E. Manoury*: “Catalytic redox isomerization of allylic alcohols with rhodium and iridium complexes with ferrocene phosphine-thioether ligands”, J. Mol. Catal. A 2017, 426, 376-380. DOI: 10.1016/j.molcata.2016.08.014.
  366. Guillo,* J.-C. Daran, E. Manoury, R. Poli: “Synthesis and characterization of first row metal complexes derived from a pyridinophane ligand functionalized by fluoroalcohol”, ChemistrySelect, 2017, 2, 2574–2577. DOI: 10.1002/slct.201700404.
  367. Banerjee, V. Ladmiral, A. Debuigne, C. Detrembleur, S. M. W. Rahaman, R. Poli, B. Améduri*: “Organometallic-Mediated Alternating Radical Copolymerization of tert-Butyl-2-Trifluoromethacrylate with Vinyl Acetate and Synthesis of Block Copolymers Thereof”, Macromol. Rapid Commun. 2017, 426, 1700203/1-7. DOI: 10.1002/marc.201700203.
  368. Joumaa, S. Chen, S. Vincendeau, F. Gayet, R. Poli*, E. Manoury*: “Rhodium-catalyzed aqueous biphasic hydrogenation of alkenes with amphiphilic phosphine-containing core-shell polymers”, J. Mol. Cat. A. 2017, 438, 267-271. DOI: 10.1016/j.mcat.2017.06.005.
  369. Bouchène, J.-C. Daran, R. Poli, E. Deydier, S. Bouacida, E. Manoury*: “Staigthforward synthesis of ferrocenyl allylic thioethers”, Inorg. Chim. Acta 2018, 470, 365-372. DOI: 10.1016/j.ica.2017.06.039 (special issue in honor of Carlo Mealli).
  370. V. Bellan, L. Thevenin, F. Gayet, C. Fliedel, R. Poli*: “Catalyzed Chain Transfer in Vinyl Acetate Polymerization mediated by 9-Oxyphenalenone Cobalt(II) complexes”, ACS Macro Lett. 2017, 6, 959-962. DOI: 10.1021/acsmacrolett.7b00551.
  371. G. Ribelli, S. M. W. Rahaman, K. Matyjaszewski*, R. Poli*: “Catalyzed Radical Termination in the Presence of Tellanyl Radicals”, Chem. Eur. J. 2017, 23, 13879–13882. DOI: 10.1002/chem.201703064.
  372. Fliedel,* R. Poli: “Coordination chemistry of neutral mono-oxide, sulfide and selenide bis(diphenylphosphino)amine (DPPA)-based ligands and their N-substituted/func­tionali­zed derivatives”, Coord. Chem. Rev. 2018, 355, 1-26. DOI: 10.1016/j.ccr.2017.07.010 (special issue on the occasion of Pierre Braunstein’s 70th birthday).
  373. S. Sinopalnikova, T. A. Peganova, V. V. Novikov, I. V. Fedyanin, O. A. Filippov, N. V. Belkova, E. S. Shubina, R. Poli, A. M. Kalsin*: “Coordinatively labile 18-electron arene ruthenium iminophosphonamide complexes”, Chem. Eur. J. 2017, 23, 15424–15435. DOI: 10.1002/chem.201702862.
  374. G. Ribelli, K. F. Augustine, M. Fantin, P. Krys, R. Poli*, K. Matyjaszewski*: “Disproportionation or Combination? The Termination of Acrylate Radicals in ATRP, Macromolecules 2017, 50, 7920–7929. DOI: 10.1021/acs.macromol.7b01552.
  375. Wang, D. Agustin*, R. Poli: “Influence of ligand substitution on molybdenum catalysts with tridentate Schiff base ligands for the organic solvent-free oxidation of limonene using aqueous TBHP as oxidant”, Mol. Cat. 2017, 443, 52-59. DOI: 10.1016/j.mcat.2017.09.033.
  376. Banerjee, E. V. Bellan, F. Gayet, A. Debuigne, C. Detrembleur, R. Poli*, B. Améduri and V. Ladmiral*: “Bis(formylphenolato)cobalt(II)-Mediated Alternating Radical Copolymerization of tert-Butyl-2-trifluoromethacrylate with Vinyl Acetate”, Polymers 2017, 9, 702/1-11. DOI: 10.3390/polym9120702 (highlighted by B.V.K.J. Schmidt, Polymers, 2020, 12(1), 39).
  377. Poli*, S.M.W. Rahaman, V. Ladmiral, B. Ameduri: “Effect of α- and β-H/F substitution on the homolytic bond strength in dormant species of controlled radical polymerization: OMRP vs. ITP and RAFT”. J. Organomet. Chem. 2018, 864, 12-18. DOI: 10.1016/j.jorganchem.2017.12.020 (special issue on computa­tional chemistry).
  378. S. Sinopalnikova, T. A. Peganova, N. V. Belkova, E. Deydier, J.-C. Daran, E. S. Shubina, A. M. Kalsin and R. Poli*: “Ruthenium p-cymene iminophosphonamide complexes: activation under basic conditions and transfer hydrogenation catalysis”, Eur. J. Inorg. Chem. 2018, 2285-2299. DOI: 10.1002/ejic.201701344 (special 20th anniversary issue).
  379. Banerjee, V. Ladmiral, A. Debuigne, C. Detrembleur, R. Poli*, B. Ameduri*: “Organometallic Mediated Radical Polymerization of Vinylidene Fluoride”, Angew. Chem. Int. Ed., 2018, 57, 2934–2937. DOI: 10.1002/ange.201712347.
  380. G. Ribelli, M. Fantin, J.-C. Daran, K. F. Augustine, R. Poli, K. Matyjaszewski*: “Synthesis and Characterization of the Most Active Copper-based ATRP Catalyst based on tris[(4-dimethylaminopyridyl)methyl]amine”, J. Am. Chem. Soc. 2018, 140, 1525–1534. DOI: 10.1021/jacs.7b12180.
  381. L. Gushchin*, N. Y. Shmelev, S. F. Malysheva, A. V. Artem’ev, N. A. Belogorlova, P. A. Abramov, N. Kompan’kov, E. Manoury, R. Poli, R. Llusar, M. N. Sokolov: “Hemilability of phosphine-thioether ligands coordinated to trinuclear Mo3S4 clusters and its effect on hydrogenation catalysis”, New J. Chem., 2018, 42, 17708-17717. DOI: 10.1039/c8nj03720e.
  382. G. Ribelli, K. Matyjaszewski, R. Poli*: “The interaction of carbon-centered radicals with copper(I) and copper(II) complexes”, J. Coord. Chem. 2018, 71, 1641-1668. DOI: 10.1080/00958972.2018.1490416 (special issue dedicated to Dan Meyerstein’s 80th birthday).
  383. K. Redjel, L. Thevenin, J.-C. Daran, M. Benslimane, R. Poli, C. Fliedel*: “Acetylacetonato cobalt(III) and iron(III) complexes of picolylamine- and aminopropylamine-bis(phenolate) ligands: Synthesis, characterization and crystal structures”, Polyhedron 2019, 158, 83-90. DOI: 10.1016/j.poly.2018.09.021 (special issue dedicated to Professor William D. Jones on the occasion of his 65th birthday).
  384. Fliedel, R. Poli*: “Homolytically weak metal-carbon bonds make robust controlled radical polymerizations systems for ‘less-activated monomers’”, J. Organomet. Chem., 2019, 880, 241-252. DOI: 10.1016/j.jorganchem.2018.11.012 (invited review in connection with a keynote presentation at the 28th ICOMC, Florence, sponsored by Elsevier).
  385. Morales-Cerrada, C. Fliedel, J.-C. Daran, F. Gayet, V. Ladmiral, B. Améduri, R. Poli*: “Fluoroalkyl radical generation by homolytic bond dissociation in pentacarbonyl­manganese derivatives”, Chem. Eur. J. 2019, 25, 296-308. DOI: 10.1002/chem.201804007.
  386. Kulai, A. Karpus, L. Soroka, D. A. Valyaev, E. Manoury*, R. Poli, M. Destarac*, S. Mazières*: “Manganese Phosphinocarbodithioate for RAFT Polymerization with Sunlight-Induced Chain End Post-Treatment”, Polym. Chem. 2019, 10, 267-277. DOI: 10.1039/C8PY01279B.
  387. Morales-Cerrada, C. Fliedel, F. Gayet, V. Ladmiral, B. Améduri*, R. Poli*: “Thermal decomposition of fluoroalkyl pentacarbonylmanganese(I) derivatives by α-fluorine elimination”, Organometallics 2019, 38, 1021-1030. DOI: 10.1021/acs.organomet.8b00721 (invited journal cover page).
  388. G. Falireas, V. Ladmiral, A. Debuigne, C. Detrembleur, R. Poli*, B. Améduri*: “Straightforward synthesis of well-defined poly(vinylidene fluoride) and its block copolymers by cobalt-mediated radical polymerization”, Macromolecules 2019, 52, 1266-1276. DOI: 10.1021/acs.macromol.8b02252.
  389. Karpus, O. Yesypenko*, S. Cherenok, V. Boiko, O. Kalchenko, Z. Voitenko, O. Tribrat, R. Poli, J.-C. Daran, E. Manoury, V. Kalchenko: “Chiral phosphorus-containing calixarenes”, Phosphorus, Sulfur, and Silicon and the Related Elements, 2019, 471-475, DOI: 10.1080/10426507.2018.1539994.
  390. Emayavaramban, P. Chakraborty, E. Manoury, R. Poli, B. Sundararaju*: “Cp*Co(III)-Catalyzed Direct Amination of Secondary Alcohols”, Org. Chem. Front. 2019, 6, 852-857. DOI: 10.1039/C8QO01389F.
  391. Pisk,* D. Agustin,* R. Poli: “Organic Salts and Merrifield Resin Supported [PM12O40]3- (M = Mo or W) as Catalysts for Adipic Acid Synthesis”, Molecules 2019, 24, 783/1-15. DOI: 10.3390/molecules24040783.
  392. Wang, J. Han, H. Peng, X. Tang, J. Zhu, R.-Z. Liao, X. Xie, Z. Xue*, C. Fliedel, R. Poli*: “Activation of a bromoalkyl ATRP initiator by a variety of inorganic salts: experiments and computations”, Polym. Chem. 2019, 10, 2376-2386. DOI: 10.1039/C9PY00113A.
  393. -C. Daran*, R. Morales-Cerrada, C. Fliedel, F. Gayet, V. Ladmiral, B. Améduri, R. Poli: “Crystal structure of pentacarbonyl(2,2-difluoropropanethioato-κS)manganese(I)”, Acta Cryst. E 2019, 75, 529-532. DOI: 10.1107/S2056989019004134.
  394. Thevenin, C. Fliedel, M. Fantin, T. G. Ribelli, K. Matyjaszewski, R. Poli*: “Reductive termination of cyanoisopropyl radicals by copper(I) complexes and proton donors: organometallic intermediates or coupled proton-electron transfer?”, Inorg. Chem. 2019, 58, 6445–6457, DOI: 10.1021/acs.inorgchem.9b00660.
  395. D. Lahneche, A. Lachguar, C. Mouton, J.-C. Daran, E. Manoury, R. Poli, M. Benslimane, A. Labande*, E. Deydier*: “Phosphine/N-heterocyclic carbene palladium complex for Suzuki-Miyaura cross-coupling reactions: The role of water on activity”, Inorg. Chim. Acta 2019, 492, 91-97. DOI: 10.1016/j.ica.2019.04.021.
  396. Kim, S. M. W. Rahaman, B. Q. Mercado, R. Poli*, P. L. Holland*: “The Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling”, J. Am. Chem. Soc. 2019, 141, 7473–7485. DOI: 10.1021/jacs.9b02117 (Highlighted in Science, 2019, 364, 747-748).
  397. L. Coward, B. R. M. Lake, R. Poli, M. P. Shaver*: “Radically-initiated group transfer polymerization of methacrylates by titanium amino-phenolate complexes”, Macromolecules 2019, 52, 3252–3256. DOI: 10.1021/acs.macromol.9b00182.
  398. Ibrahim, M. M. Wei, E. Deydier*, E. Manoury*, R. Poli, P. Lecante, K. Philippot*: “Rhodium nanoparticles stabilized by ferrocenyl-phosphine ligands: synthesis and catalytic styrene hydrogenation”, Dalton Trans. 2019, 48, 6777-6786. DOI: 10.1039/C9DT01006H.
  399. Fantin, F. Lorandi, T. G. Ribelli, C. Fliedel, L. Thevenin, A. A. Isse, R. Poli and K. Matyjaszewski*: “The Impact of Organometallic Intermediates on Copper-Catalyzed Atom Transfer Radical Polymerization”, Macromolecules, 2019, 52, 4079-4090. DOI: 10.1021/acs.macromol.9b00870.
  400. Labande*, E. Manoury, R. Poli, C. Fliedel*: “Chiral N-heterocyclic carbene ligands with additional chelating group(s) applied to homogeneous metal-mediated asymmetric catalysis”, Coord. Chem. Rev. 2019, 394, 65-103. DOI: 10.1016/j.ccr.2019.05.003 (special issue dedicated to Prof. Armando J. L. Pombeiro).
  401. Morales-Cerrada, C. Fliedel, F. Gayet, V. Ladmiral, B. Améduri, R. Poli*: “Homolytic bond strength and radical generation from (1-carbomethoxyethyl)­pentacarbonyl­manganese(I)”, Eur. J. Inorg. Chem. 2019, 4228–4233. DOI: 10.1002/ejic.201900429.
  402. Zhao, Y. Wang*, X. Zhou, Z. Xue, X. Wang, X. Xie, R. Poli: “Oxygen Triggered Switchable Polymerization for One-Pot Synthesis of CO2-Based Block Copolymers from Monomer Mixtures”, Angew. Chem. Int. Ed. 2019, 58, 14311-14318. DOI: 10.1002/anie.201906140.
  403. Wang, J. Han, X. Xie, Z. Xue*, C. Fliedel, R. Poli*: “FeBr2-catalyzed bulk ATRP of methyl methacrylate promoted by simple inorganic salts”, Macromolecules 2019, 52, 5366-5376. DOI: 10.1021/acs.macromol.9b01015.
  404. Karpus, J.-C. Daran, R. Poli, S. Mazières*, M. A. Destarac, E. Manoury*: “Synthesis of S-alkyl phosphinocarbodithioates with switch between P(III) and P(V) derivatives”, J. Org. Chem. 2019, 84, 9446-9453. DOI: 10.1021/acs.joc.9b00590.
  405. Chakraborty, M. K. Gangwar, B. Emayavaramban, E. Manoury, R. Poli, B. Sundararaju*: “Well-defined Cp*Co(III)-Catalyzed α-Alkylation of Ketones with Secondary Alcohols”, ChemSusChem 2019, 12, 3463-3467. DOI: 10.1002/cssc.201900990.
  406. Thevenin, C. Fliedel, K. Matyjaszewski, R. Poli*: “Impact of catalyzed radical termination (CRT) and reductive radical termination (RRT) in metal-mediated radical polymerization processes”, Eur. J. Inorg. Chem. 2019, 4489–4499. DOI: 10.1002/ejic.201900901.
  407. Wang, R. Poli, C. Detrembleur, A. Debuigne*: “Organometallic-Mediated Radical (Co)Polymerization of γ-Methylene-γ-Butyrolactone: Access to pH-Responsive Poly(vinyl alcohol) Derivatives” Macromolecules 2019, 52, 8976-8988. DOI: 10.1021/acs.macromol.9b01838.
  408. S. Fomenko, S. Vincendeau, E. Manoury, R. Poli, P. A. Abramov, V. A. Nadolinny, M. N. Sokolov, A. L. Gushchin*: “An oxidovanadium(IV) complex with 4,4’-di-tert-butyl-2,2’-bipyridine ligand: synthesis, structure and catalyzed cyclooctene epoxidation”, Polyhedron 2020, 177, 114305. DOI: 10.1016/j.poly.2019.114305.
  409. M. Kalsin*, T. A. Peganova, I. S. Sinopalnikova, I. V. Fedyanin, N. V. Belkova, E. Deydier, R. Poli*: “Mechanistic diversity in acetophenone transfer hydrogenation catalyzed by ruthenium iminophosphonamide complexes”, Dalton Trans. 2020, 49, 1473-1484. DOI: 10.1039/C9DT04532E (invited contribution to the “Inorganic Reaction Mechanisms” issue; selected as a Dalton Transactions HOT Article).
  410. Wang, X. Xie, Z. Xue*, C. Fliedel, R. Poli*: “Ligand- and solvent-free ATRP of MMA with FeBr3 and inorganic salts”, Polym. Chem. 2020, 11, 1375-1385. DOI: 10.1039/C9PY01840A.
  411. Morales-Cerrada, V. Ladmiral, F. Gayet, C. Fliedel, R. Poli,* B. Améduri*: “Fluoroalkyl Pentacarbonylmanganese(I) Complexes as Initiators for the Radical (co)Polymerization of Fluoromonomers”, Polymers 2020, 12, 384/1-17. DOI: 10.3390/polym12020384.
  412. Wang,* Y. Zhao, S. Zhu, X. Zhou,* J. Xu, X. Xie, R. Poli*: “Switchable Polymerization Triggered by Fast and Quantitative Insertion of Carbon Monoxide into Cobalt-Oxygen Bonds”, Angew. Chem. Int. Ed. 2020, 15, 5988-5994. DOI: 10.1002/anie.201914216.
  413. Wang, L. Vendrame, C. Fliedel, S. Chen, F. Gayet, E. Manoury, X. Zhang, M. Lansalot, F. D’Agosto, R. Poli*: “Core-cross-linked micelles made by RAFT polymerization with a poly-cationic outer shell based on poly(1-methyl-4-vinylpyridinium)” Macromolecules 2020, 53, 2198-2208. DOI: 10.1021/acs.macromol.9b02582.
  414. Joumaa, F. Gayet, E. J. Garcia-Suarez, J. Himmelstrup, A. Riisager, R. Poli*, E. Manoury*: “Synthesis of Nixantphos core-functionalized amphiphilic nanoreactors and application to rhodium-catalyzed aqueous biphasic 1-octene hydroformylation”, Polymers, 2020, 12, 1107/1-18. DOI: 10.3390/polym12051107.
  415. Chakraborty, N. Garg, E. Manoury, R. Poli,* B. Sundararaju*: “C-Alkylation of Various Carbonucleophiles with Secondary Alcohols Under Co(III)-Catalysis”, ACS Catal. 2020, 10, 8023–8031. DOI: 10.1021/acscatal.0c01728.
  416. Wang, K. Jiang, C. Zuo, S. Li, S. Li, D. He, H. Peng, X. Xie, R. Poli*, Z. Xue*: “Facile Fabrication of Polymer Electrolytes via Lithium Salt-Accelerated Thiol-Michael Addition for Lithium-Ion Batteries”, Macromolecules, 2021,  DOI: 10.1021/acs.macromol.0c01302.
  417. Wang, L. Vendrame, C. Fliedel, S. Chen, F. Gayet, F. D’Agosto, M. Lansalot, E. Manoury, R. Poli*: “Triphenylphosphine-functionalized core-cross-linked micelles and nanogels with a polycationic outer shell: synthesis and application in rhodium-catalyzed biphasic hydrogenations”, Chem. Eur. J., 2021, 27, 5205–5214. DOI: 10.1002/chem.202004689.
  418. Thevenin, J.-C. Daran, R. Poli*, C. Fliedel*: “Cobalt complexes of an OSNSO-tetrapodal pentadentate ligand: Synthesis, structures and reactivity”, Inorg. Chim. Acta, 2021, 518, 120215/1-8. DOI: 10.1016/j.ica.2020.120215.
  419. Quienne, R. Poli*, J. Pinaud, S. Caillol*: “Enhanced aminolysis of cyclic carbonates by β-hydroxylamines for fully biobased polyhydroxyurethanes”, Green Chem. 2021, 23, 1678-1690. DOI: 10.1039/D0GC04120C.
  420. Karpus, S. Harrisson, R. Poli, S. Mazières,* E. Manoury*, M. Destarac*: “Well-defined PIII-terminated polymers from phosphorylated carbodithioate RAFT agents”, Macromolecules 2021, 54, 2627–2636. DOI: 10.1021/acs.macromol.0c02805.
  421. Wang, A. M. Fiore, C. Fliedel, E. Manoury, K. Philippot*, M. M. Dell’Anna, P. Mastrorilli, R. Poli*: “Rhodium nanoparticles inside well-defined unimolecular amphiphilic polymeric nanoreactors: synthesis and biphasic hydrogenation catalysis”, Nanoscale Advances 2021, 3, 2554 – 2566. DOI: 10.1039/D1NA00028D.
  422. Bouad, M. Guerre, C. Totée, G. Silly, O. Gimello, B. Améduri, J.-F. Tahon, R. Poli, S. Barrau, V. Ladmiral*: “RAFT Polymerization of Trifluoroethylene: the importance of understanding reverse additions”, Polym. Chem. 2021, 12, 2271-2281. DOI: 10.1039/D0PY01754J.
  423. Bouad, M. Guerre, S. Zeliouche, C. Totée, G. Silly, B. Améduri, R. Poli, V. Ladmiral*: “NMR investigations of Polytrifluoroethylene (PTrFE) made by RAFT”, Polym. Chem. 2021, 12, 2293-2304. DOI: 10.1039/D0PY01753A.
  424. Poli*: “A journey into metal-carbon bond homolysis”, C. R. Chimie 2021, 24, 147-175. DOI: 10.5802/crchim.73.
  425. Bandyopadhyay, B. Sundararaju, R. Poli, E. Manoury, J.-C. Daran*: “Synthesis and crystallographic studies of 2-(diphenylphosphinothioyl)-2-(3-oxobut-1-en-yl)ferrocene”, Acta Cryst. E, 2021, E77, 853-856. DOI: 10.1107/S205698902100760X.
  426. Chakraborty, B. Sundararaju*, E. Manoury, R. Poli*: “New borrowing hydrogen mechanism for redox-active metals”, ACS Catal. 2021, DOI: 10.1021/acscatal.1c02616.
  427. S. Sambou, R. Hromov, I. Ruzhylo, H. Wang, A. Allandrieu, C. Sabatier, Y. Coppel, J.-C. Daran, F. Gayet, A. Labande,* E. Manoury,* R. Poli*: “Amphiphilic Polymeric Nanoreactors Containing Rh(I)-NHC Complexes for the Aqueous Biphasic Hydrogenation of Alkenes”, Catal. Sci. Techn. 2021, 11, 6811-6824. DOI: 10.1039/d1cy00554e.
  428. Cabanes, C. Duhayon, C. Bijani, A. Sournia-Saquet, R. Poli, A. Labande*: “Oxidation-promoted synthesis of ferrocenyl planar chiral rhodium(III) complexes for C–H functionalization catalysis”, Mendeleev Commun. 2021, 31, 620–623. DOI: 10.1016/j.mencom.2021.09.010.


  1. Recent Advances in Hydride Chemistry, R. Poli and M. Peruzzini, Editors; Elsevier Science, 2001, ISBN 9780444507334.
  2. Catalysis within Nanoconfined Spaces, R. Poli, Editor; Springer International Publishing (Series “Fundamental and Applied Catalysis”), 2017, ISBN 978-3-319-50205-2.


Book Chapters

  1. Six syntheses for Herrmann/Brauer “Synthetic methods of Organometallic and Inorganic Chemistry”, W. A. Herrmann, Volume Editor; C. Zybill, Chapter Editor; Thieme Verlag: Stuttgart, 1997; Vol. 8 (Transition Metals, Part 2), pp 96-103.
           J.C. Gordon and R. Poli*: “Cyclopentadienylmolybdenum Tetrachloride”
           D.W. Keogh and R. Poli*: “Pentamethylcyclopentadienylmolybdenum Tetrachloride”
           D.W. Keogh and R. Poli*: “Cyclopentadienylmolybdenum Trichloride”
           J.U. Desai, J. C. Gordon and R. Poli*: “Pentamethylcyclopentadienylmolybdenum Trichloride”
           R.Poli*: “Cyclopentadienylmolybdenum Dichloride”
           F.Abugideiri and R. Poli*: “Pentamethylcyclopentadienylmolybdenum Dichloride”
  2. Poli*: “Paramagnetic mono- and polyhydrides of the transition metals”, Recent Advances in Hydride Chemistry, R. Poli and M. Peruzzini, Editors; Elsevier: Amsterdam, 2001; Chapter 6, pp 139-188. DOI: 10.1016/B978-044450733-4/50006-1.
  3. Poli*, K. M. Smith: “Organometallic Compounds of Chromium, Molybdenum and Tungsten Without Carbonyl Ligands”, in “Science of Synthesis, Houben-Weyl Methods of Molecular Transformations”, Editors: D. Bellus, S. V. Ley, R. Noyori, M. Regitz, E. Schaumann, I. Shinkai, E. J. Thomas, B. M. Trost. Volume Editor: R. Noyori.  Guest Editor: T. Imamoto.  Publisher: Georg Thieme Verlag, Stuttgarg, Germany. 2003, Vol. 2, Category 1, Product Class 6, pp. 283-332. DOI: 10.1055/sos-SD-002-00315.
  4. Collange, F. Demirhan, J. Gun, O. Lev, A. Modestov, R. Poli*, P. Richard, D. Saurenz: “Results and Perspectives of High Oxidation State Organomolybdenum Chemistry in Water”, Perspectives in Organometallic Chemistry, C. G. Screttas and B. R. Steele, Eds., Royal Society of Chemistry, 2003, 287, 167-182. ISBN: 0854048766. DOI: 10.1039/9781847551641-00167.
  5. Debuigne*, R. Poli*, R. Jérôme, C. Jérôme, C. Detrembleur: “Key Role of Metal-Coordination in Cobalt-Mediated Radical Polymerization of Vinyl Acetate”, in “Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP, K. Matyjaszewski, Editor; ACS Symp. Ser., 1024, 131-148, 2009. DOI: 10.1021/bk-2009-1024.ch009.
  6. Manoury*, R. Poli*: “Phosphine-Containing Planar Chiral ferrocenes: Synthesis, Coordination Chemistry and Applications to Asymmetric Catalysis”, in Phosphorus compounds: advanced tools in catalysis and material sciences, L. Gonsalvi and M. Peruzzini, Editors; Springer Verlag: London, Chapt. 5, pp 129-159, 2011. DOI: 10.1007/978-90-481-3817-3_5.
  7. Poli*: “Organometallic Mediated Radical Polymerization” (Chapter 3.11), in Polymer Science: A Comprehensive Reference, (Editors-in-Chief: Krzysztof Matyjaszewski and Martin Möller; Volume Editors: Geoffrey Coates and Mitsuo Sawamoto), Amsterdam: Elsevier BV, Vol 3, pp. 351–375, 2012. DOI: 10.1016/B978-0-444-53349-4.00070-4.
  8. Poli*, Z. Xue: “Investigation of Bis(acetylacetonato)iron(II) as a Moderator for the Radical Polymerization of Vinyl Acetate”, in “Progress in Controlled Radical Polymerization: Mechanisms and Techniques”, N. Tsarevsky and R. Hauserman, Editors; ACS Symp. Ser., 1100, 231-242, 2012. DOI: 10.1021/bk-2012-1100.ch015.
  9. Poli*: “Spin Crossover Reactivity” (Chapter 9.19), in Comprehensive Inorganic Chemistry II, (Editors-in-Chief: Jan Reedijk and Ken Poeppelmeier; Volume Editor: Santiago Alvarez), Amsterdam: Elsevier BV, Vol 9, pp. 481–500, 2013. DOI: 10.1016/B978-0-08-097774-4.00919-0.
  10. Poli*, S. Chen, X. Zhang, A. Cardozo, M. Lansalot, F. D’Agosto, B. Charleux, E. Manoury, F. Gayet, C. Julcour, J.-F. Blanco, L. Barthe, H. Delmas: “One-pot RAFT synthesis of triphenylphosphine-functionalized amphiphilic core-shell polymers and application as catalytic nanoreactors in aqueous biphasic hydroformylation”, in “Controlled Radical Polymerization”, K. Matyjaszewski, Editor; ACS Symp. Ser., 1188, 203-220, 2015. DOI: 10.1021/bk-2015-1188.ch014.
  11. Poli*: “Organometallic Mediated Radical Polymerization”, in “Reference Module in Materials Science and Engineering”, (Editor: S. Hashmi), Elsevier, 2016 (update of book chapter #7: 3.11 – “Organometallic-Mediated Radical Polymerization”, in “Polymer Science: A Comprehensive Reference”, 3, 351-375, 2012). DOI: 10.1016/B978-0-12-803581-8.01353-9.
  12. Manoury, F. Gayet, F. D’Agosto, M. Lansalot, H. Delmas, C. Julcour, J.-F. Blanco, L. Barthe, R. Poli*: “Core-cross-linked micelles and amphiphilic nanogels as unimolecular nanoreactors for micellar-type, metal-based aqueous biphasic catalysis”, in “Effects of Nanoconfinement on Catalysis”, R. Poli, Editor; Springer International Publishing, 2017, pp 147-172. DOI: 10.1007/978-3-319-50207-6_7.
  13. Poli*: “Site isolation for non-orthogonal tandem catalysis in confined nanospaces”, in “Effects of Nanoconfinement on Catalysis”, R. Poli, Editor; Springer International Publishing, 2017, pp 209-258. DOI: 10.1007/978-3-319-50207-6_9.
  14. G. Ribelli, S.M.W. Rahaman, K. Matyjaszewski, R. Poli*: “Catalyzed radical termination (CRT) in the metal-mediated polymerization of acrylates: experimental and computational studies”, in “Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies”; N. Tsarevsky, H. Gao, K. Matyjaszewski, B. Sumerlin, Editors; ACS Symp. Ser., 1284, 135-159, 2018. DOI: 10.1021/bk-2018-1284.ch006.
  15. Poli*: “Contribution of computations to metal-mediated radical polymerization” (Chapter 7), in “Computational Quantum Chemistry. Insights into Polymerization Reactions”; M. Soroush, Editor; Elsevier, 2019, pp 219-267. DOI: 10.1016/B978-0-12-815983-5.00007-6.
  16. Bandyopadhyay, B. Sundararaju, R. Poli, E. Manoury*: “Chiral tridentate based ligands”, in “Chiral Ligands: Evolution of Ligand Libraries for Asymmetric Catalysis”, M. Diéguez, Editor, CRC Press, Boca Raton, USA, 2021, pp 167-194, DOI: 10.1201/9780367855734.
  17. Michelas, C. Fliedel, R. Poli*: “Reversible Homolysis of Metal-Carbon Bonds”, in “Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2021. DOI: 10.1016/B978-0-12-820206-7.00075-5.


Cliquez pour voir nos collaborations

Collaborations (depuis 2015)

Dr. Bruno Améduri, Dr. Vincent Ladmiral
Institut Charles Gerhardt (UMR 5253 CNRS)
Ingénierie et Architectures Macromoléculaires,
ENSCM, Place Eugène Bataillon,
34095 Montpellier, Cedex 5 (France)

Controlled radical polymerization of fluorinated monomers
Publ. No. 359, 364, 367, 376, 377, 379, 385, 387, 388, 393, 401, 411, 422, 423


Prof. Ahmed Benharref
Laboratoire de chimie biomoléculaire, substances naturelles et réactivité,
Unité associée au CNRST (URAC16)
Université Cadi-Ayyad
Faculté des sciences Semlalia
BP 2390, boulevard My Abdellah
40000 Marrakech (Morocco)

Catalytic transformations of Moroccan natural products
Publ. No. 333


Dr. Stéphane Caillol
Université Montpellier
Montpellier (France)
Tel: +1-33-467144327

Aminolysis of cyclic carbonates for polyhydroxyurethane synthesis
Publ. No. 419


Prof. Jérôme Claverie
Département de Chimie
Université de Sherbrooke
2500, Blvd de l’Université
Faculté des sciences Semlalia
J1K2R1, Sherbrooke, Qc (Canada)
Tel: +1-819-821-7246

Coordination polymerization of polar monomers
Publ. No. 287


Dr. Franck D’Agosto, Dr. Muriel Lansalot
Chimie Catalyse Polymères et Procédés (C2P2)
Equipe LCPP (UMR 5265 CNRS/ESCPE/UCBLyon1)
CPE Lyon – 43, boulevard du 11 Novembre 1918
BP 2077
69616 Villeurbanne Cedex
Tel: +33-(0)472431770

Synthesis of catalytic polymeric nanoreactors by “polymerization-induced self-assembly” (PISA) in emulsion
Publ. No. 338, 344, 345, 357, 360, 413, 417


Prof. Henri Delmas, Dr. Carine Julcour , Dr. Jean-François Blanco
CNRS, LGC (Laboratoire de Génie Chimique
4 Allée Emile Monso
BP 84234
31030 Toulouse Cedex 4 (France)

Mass transport in hydroformylation catalysis using polymer-supported phosphine ligands
Publ. No. 316, 320, 338, 344, 345, 360


Prof. Mathias Destarac, Dr. Stéphane Mazières
Université Paul Sabatier
118 route de Narbonne, 31062 Toulouse (France)

Metal-induced reactivity switch in RAFT polymrization
Publ. No. 386, 404, 420


Dr. Christophe Detrembleur, Dr. Antoine Debuigne
Center for Education and Research on Macromolecules
University of Liege
Sart-Tilman B6
4000 Liege (Belgium)
Tel. +32 4 3663465
Fax. +32 4 3663497

Cobalt-mediated radical polymerization
Publ. No. 246, 254, 259, 273, 279, 310, 311, 323, 367, 376, 379, 388, 407


Prof. Montserrat Diéguez
Universitat Rovira i Virgili
Campus Sescelades
Marcel·lí Domingo s/n
43007 Tarragona (Spain)
Tel. +34-977-558046 / 558627
Fax. +34-977-559563

Enantioselective hydrogenation catalysis
Publ. No. 348


Prof. Simon Duckett
Department of Chemistry
University of York
York YO10 5DD (UK)
Tel. +44-1904-432564
Fax. +34-977-559563

Parahydrogen NMR studies
Publ. No. 196, 197, 219, 218, 222, 327


Prof. Norberto Farfán
Facultad de Química
Depto. de Química Orgánica
Universidad Nacional Autónoma de México
04510 México D.F., (Mexico)

Ligands for epoxidation catalysis
Publ. No. 343


Dr. Artem Guschchin
Nikolaev Institute of Inorganic Chemistry,
Siberian Branch of the Russian Academy
of Sciences,
3 Lavrentiev av., Novosibirsk, 630090 (Russia)

Catalysis with inorganic compounds and clusters
Publ. No. 381, 408


Prof. Patrick Holland
Department of Chemistry,
Yale University,
New Haven, Connecticut 06511 (USA)

Catalysis with base metals
Publ. No. 396


Prof. Agustí Lledós
Departament de Química
Universitat Autònoma de Barcelona
Edifici Cn
08193 Bellaterra (Spain)
Tel: +34-935811716
Fax: +34-935812920

Theoretical study of the structure and reactivity of transition metal hydrides.
Theoretical study of reaction mechanisms.
Design of ligands for enantioselective catalysis with hydrides.
Publ. No. 188, 201, 221, 227, 236, 270, 274, 312, 317, 349


Dr. Alexandr M. Kal’sin
A.N. Nesmeyanov Labratory for Organometallic Chemistry
A.N. Nesmeyanov Institute of Organoelement Compounds
RAS 28 Vavilov Str.
Moscow (Russia)

Hydrogen transfer catalysis with para-cymene ruthenium  complexes supported by iminophosphonamide ligands
Publ. No. 373, 378, 409


Prof. Piero Mastrorilli
Politecnico di Bari
via Orabona, 4
70125 Bari (Italy)
Tel: +39-080-5963605

Polymer-supported metallic nanoparticles
Publ. No. 421


Prof. Krzysztof Matyjaszewski
Department of Chemistry
Carnegie Mellon University
4400 Fifth Ave.
Pittsburgh, PA 15213 (USA)
Tel: +1-412-268-3209
Fax: +1-412-268-6897

Transition metal chemistry of relevance to controlled radical polymerization
Publ. No. 187, 192, 209, 230, 241, 243, 313, 329, 354, 362, 371, 374, 380, 382, 394, 399, 406


Prof. Jean-Luc Pirat, Prof. David Virieux
Ecole Nationale Supérieure de Chimie de Montpellier
8 rue de l’Ecole Normale
34296 Montpellier Cedex 5 (France)
Tel. +33-(0)467147243

Synthesis of and catalysis with axially chiral bis(triazolyl)bisphosphine ligands
Publ. No. 350


Dr. Karine Philippot
Laboratoire de Chimie de Coordination
205 Route de Narbonne
31077 Toulouse (France)
Tel: +39-561333230

Chemistry and catalysis with metallic nanoparticles
Publ. No. 398, 421


Prof. Anders Riisager
Technical University of Denmark
Building 206, room 144
2800 Kgs. Lyngby (Denmark)
Tel: +45 45 25 22 33

Catalytic application of functionalized polymeric nanoreactors
Publ. No. 414


Prof. Michael P. Shaver
School of Chemistry
University of Edinburgh
West Mains Road
Edinburgh, EH9 3JJ (UK)
Tel: +44 (0)131-6504726

Fe-mediated radical polymerization
Publ. No. 334, 335, 341, 397


Prof. Elena S. Shubina, Prof. Natalia V. Belkova
Laboratory of Metal Hydrides
A.N. Nesmeyanov Institute of Organoelement Compounds
RAS 28 Vavilov Str.
Moscow (Russia)
Tel: +7-095-1356448
Fax: +7-095-1355085

Infrared studies of nonclassical hydrogen bonding in hydride complexes
Publ. No. 185, 188, 201, 221, 227, 235, 251, 256, 258, 270, 275, 277, 365

Spectroscopic studies of Rh and Pt-based hydroamination catalysts
Publ. No. 262, 288, 290, 300

Spectroscopic studies of Rh-based hydrogenation catalysts
Publ. No. 309, 325, 327


Prof. Basker Sundararaju
Department of Chemistry,
Indian Institute of Technology Kanpur,
Kanpur, 208016 (India)

Catalysis with base metals
Publ. No. 390, 405, 415


Prof. Zoia Voitenko
Taras Shevchenko National University of Kyiv
Kyiv 01033 (Ukraine)

Phosphorus-containing calixarenes: coordination chemistry and catalytic applications
Publ. No. 358, 389


Dr. Yong Wang
Key Laboratory for Material Chemistry of Energy Conversion and Storage,
Ministry of Education, School of Chemistry and
Chemical Engineering,
Huazhong University of Science and Technology, Wuhan 430074 (P. R. China)

Switching polymerization mechanisms with cobalt complexes
Publ. No. 402, 412


Prof. Zhigang Xue
Key Laboratory for Material Chemistry of Energy Conversion and Storage,
Ministry of Education, School of Chemistry and
Chemical Engineering,
Huazhong University of Science and Technology, Wuhan 430074 (P. R. China)

Atom transfer radical polymerization with Fe complexes
Publ. No. 392, 403, 410, 416


Financements (since 2015)


  • Agence Nationale de la Recherche. 2015-2018 (4 years). « Stimulate Industrial Renewal Challenge » No. ANR-14-CE07-0012 (FLUPOL) Improved fluorinated polymers through organometallic mediated radical polymerization”. Rinaldo Poli (Coordinator), Bruno Ameduri (ICG Montpellier, PI) (430 000 € total; 273 909 € for the team).

  • European Commission, Horizon2020, Marie Curie action “IIF”. Contract No. 2015-17 (2 years). Post-doctoral Fellowship for Dr. Wahidur Rahaman: “Mechanism of hydrogenation and transfer hydrogenation of polar unsaturations catalyzed by non N-H systemsMetal-mediated controlled radical polymerization (NONNH)” (185 076 €)

  • CNRS-PICS06782. 2015-17 (3 years). International program of scientific cooperation (foreign partners: Krzysztof Matyjaszewski, Carnegie Mellon University; Tomislav Pintauer, Duquesne University). “Enhancing control in ATRP via detailed mechanistic and structural studies” (21 000 €)

  • Agence Nationale de la Recherche. 2017-2020 (4 years). « Stimulate Industrial Renewal Challenge » No. ANR-16-CE29-0014-02 (RAFTSWITCH) “Switchable RAFT Transfer Agents for Controlled Radical Polymerization”. Stéphane Mazière (IMRCP Toulouse, Coordinator), Rinaldo Poli (PI) (395 184 € total; 200 005 € for the team).

  • CNRS-Laboratoire International Associé (LIA CNRS No. 1240). 2018-2021 (4 years). “Laboratory of coordination chemistry for controlled radical polymerization”. LIA No. 1240. (60 000 €).

  • 2017-2020 (3 years). Project No. 5805-B/2017/432 “Novel Chiral First row Transition Complexes for Asymmetric Catalysis via Activation of inert C-H and C-Heteroatom Bonds” (84 351 € for French side).

  • Agence Nationale de la Recherche. 2020-2024 (4 years). AAP générique 2019 No. ANR-19-CE06-0014-02. “Additive-Free Covalent Adaptable Networks (AFCAN)”. Sylvain Caillol (ICG Montpellier, Coordinator), Rinaldo Poli (PI) (449 813 € total; 178 740 € for the team).

  • Agence Nationale de la Recherche. 2019-2023 (4 years). AAP générique 2019 No. ANR-19-CE07-0043. “Redox modulation of dirhodium(II)-catalyzed nitrene insertions into C(sp3)-H bonds (CHamRhOx)”. Agnès Labande (LCC Toulouse, Coordinator), Rinaldo Poli (participant) (360 439 € total; 179 388 € for the team).

  • Agence Nationale de la Recherche. 2020-2022 (3 years). AAP générique 2019 No. Contract No. ANR-19-CE07-0031-01. “Metal complexes for polymerization mechanism switching (POLYSWITCH)”. Christophe Fliedel (LCC Toulouse, Coordinator), Rinaldo Poli (participant) (187 164 €).

  • European Commission, Horizon2020, Marie Curie action “ITN-EJD”. Contract No. 2020-24 (4 years). European Joint Doctorate Training Network: “Coordination Chemistry Inspires Molecular Catalysis (CCIMC)” (3 977 588.16 €). Rinaldo Poli (Coordinator). Beneficiary institutions: CNRS-LCC, University of York, Universitat Autònoma Barcelona, Universitatea din Bucuresti, Universidad Rovira i Virgili, Uniwersytet Warszawski, Friedrich Schiller Universität Jena, Universität Leipzig, Danmarks Tekniske Univ. Partner institutions: IFP Energies nouvelles, Tecnalia, Henkel KGaA, Johnson Matthey PLC, Elkem Silicones France, Solvay, BASF.


Laboratoire de chimie de coordination du CNRS

205 route de Narbonne, BP 44099
31077 Toulouse cedex 4

+ 33 5 61 33 31 00