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Vincent CESAR

LCC

Vincent CESAR

Directeur de Recherche CNRS
Équipe A

vincent.cesar@lcc-toulouse.fr

+33 (0)5 61 33 31 72

Numéro ORCID : 0000-0002-6203-6434

ResearcherID : E-2877-2016

Publons : 1411259

Vincent César est un ancien élève de l’Ecole Normale Supérieure de Lyon. Il obtient le doctorat de chimie en 2004 à l’université Louis Pasteur (Strasbourg) sous la direction du Prof. L. H. Gade et du Dr S. Bellemin-Laponnaz. Après un séjour post-doctoral avec le Prof. Dr. A. Fürstner au Max Planck Institut für Kohlenforschung (Mülheim/Ruhr, Allemagne), il intègre le CNRS en 2006 au Laboratoire de Chimie de Coordination à Toulouse et est promu Directeur de recherche en 2020.

 

Domaines d’expertise – projets en cours

section en cours de rédaction

Production scientifique



56 documents

Articles dans une revue

  • Mirko Ruamps, Stéphanie Bastin, Lionel Rechignat, Alix Sournia-Saquet, Laure Vendier, et al.. Redox-Switchable Behavior of Transition-Metal Complexes Supported by Amino-Decorated N-Heterocyclic Carbenes. Molecules, MDPI, 2022, 27 (12), pp.3776. ⟨10.3390/molecules27123776⟩. ⟨hal-03709012⟩
  • Lenka Pallova, Laura Abella, Marion Jean, Nicolas Vanthuyne, Cécile Barthes, et al.. Helical chiral N‐heterocyclic carbene ligands in enantioselective gold catalysis. Chemistry - A European Journal, Wiley-VCH Verlag, 2022, 28 (17), pp.e202200166. ⟨10.1002/chem.202200166⟩. ⟨hal-03575284⟩
  • Rémy Brousses, Vincent Maurel, Jean-Marie Mouesca, Vincent César, Noël Lugan, et al.. Half-sandwich manganese complexes Cp(CO) 2 Mn(NHC) as redox-active organometallic fragments. Dalton Transactions, Royal Society of Chemistry, 2021, 50 (40), pp.14264-14272. ⟨10.1039/D1DT02182F⟩. ⟨hal-03403199⟩
  • Lenka Pallova, Etienne Gauthier, Laura Abella, Marion Jean, Nicolas Vanthuyne, et al.. Synthesis and Properties of Partially Saturated Fluorenyl-Derived [n]helicenes Featuring an Overcrowded Alkene. Chemistry - A European Journal, Wiley-VCH Verlag, 2021, 27 (28), pp.7722-7730. ⟨10.1002/chem.202100150⟩. ⟨hal-03194360⟩
  • Alina A Grineva, Oleg A Filippov, Yves Canac, Jean-Baptiste Sortais, Sergei E Nefedov, et al.. Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes. Inorganic Chemistry, American Chemical Society, 2021, 60 (6), pp.4015-4025. ⟨10.1021/acs.inorgchem.1c00073⟩. ⟨hal-03200528⟩
  • Idir Benaissa, Katarzyna Gajda, Laure Vendier, Noël Lugan, Anna Kajetanowicz, et al.. An anionic, chelating C(sp 3 ) / NHC ligand from the combination of N-heterobicyclic carbene and barbituric heterocycle. Organometallics, American Chemical Society, 2021, 40 (18), pp.3223-3234. ⟨10.1021/acs.organomet.1c00458⟩. ⟨hal-03356487⟩
  • Cécile Barthes, Carine Guyard-Duhayon, Yves Canac, Vincent César. N -Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N -cationic substituent. Chemical Communications, Royal Society of Chemistry, 2020, 56 (22), pp.3305-3308. ⟨10.1039/d0cc00477d⟩. ⟨hal-02542504⟩
  • Anna Bonfiglio, Lenka Pallova, Vincent César, Christophe Gourlaouen, Stéphane Bellemin‐laponnaz, et al.. Phosphorescent Cationic Heterodinuclear Ir III /M I Complexes (M=Cu I , Au I ) with a Hybrid Janus‐Type N‐Heterocyclic Carbene Bridge. Chemistry - A European Journal, Wiley-VCH Verlag, 2020, 26 (51), pp.11751-11766. ⟨10.1002/chem.202002767⟩. ⟨hal-02937859⟩
  • Idir Benaissa, Lenka Pallova, Marie‐emilie Morantin, Thomas Lafitte, Mathieu Huynh, et al.. N‐Heterocyclic Carbenes as Key Intermediates in the Synthesis of Fused, Mesoionic, Tricyclic Heterocycles. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, 25 (56), pp.13030-13036. ⟨10.1002/chem.201903242⟩. ⟨hal-02338944⟩
  • Alina A Grineva, Oleg Filippov, Sergei Nefedov, Noël Lugan, Vincent César, et al.. Direct Access to IMes F and IMes F 2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes. Organometallics, American Chemical Society, 2019, 38 (11), pp.2330-2337. ⟨10.1021/acs.organomet.9b00151⟩. ⟨hal-02333068⟩
  • Antoine Bruneau-Voisine, Lenka Pallova, Stéphanie Bastin, Vincent César, Jean-Baptiste Sortais. Manganese catalyzed α-methylation of ketones with methanol as a C1 source. Chemical Communications, Royal Society of Chemistry, 2019, 55 (3), pp.314-317. ⟨10.1039/c8cc08064j⟩. ⟨hal-01976517⟩
  • Yue Tang, Idir Benaissa, Mathieu Huynh, Laure Vendier, Noël Lugan, et al.. An Original L-shape, Tunable N-Heterocyclic Carbene Platform for Efficient Gold(I) Catalysis. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2019, 58 (24), pp.7977-7981. ⟨10.1002/anie.201901090⟩. ⟨hal-02335228⟩
  • Karim Azouzi, Carine Guyard-Duhayon, Idir Benaissa, Noël Lugan, Yves Canac, et al.. Bidentate iminophosphorane-NHC ligand derived from the imidazo[1,5- a ]pyridin-3-ylidene scaffold. Organometallics, American Chemical Society, 2018, 37 (24), pp.4726-4735. ⟨10.1021/acs.organomet.8b00733⟩. ⟨hal-02128330⟩
  • Alina A Grineva, Dmitry A. Valyaev, Vincent César, O. A. Filippov, Victor N. Khrustalev, et al.. Oxidative coupling of anionic abnormal N-Heterocyclic carbenes: Efficient access to Janus-type 4,4′-bis(2H-imidazol-2-ylidene)s. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2018, 57 (27), pp.7986-7991. ⟨10.1002/anie.201801530⟩. ⟨hal-01948415⟩
  • Vincent César, Valentina Mallardo, Adela Nano, Sadie F. Depeter, S. Bastin, et al.. Homo- and heteropolymetallic complexes of the hybrid, ambidentate N-heterocyclic carbene Ligand IMes-acac. ACS Omega, ACS Publications, 2018, 3 (11), pp.15582-15591. ⟨10.1021/acsomega.8b02268⟩. ⟨hal-01948413⟩
  • Mirko Ruamps, S. Bastin, Lionel Rechignat, Alix Sournia-Saquet, Dmitry A. Valyaev, et al.. Unveiling the redox-active character of imidazolin-2-thiones derived from amino-substituted N-heterocyclic carbenes. Chemical Communications, Royal Society of Chemistry, 2018, 54 (55), pp.7653-7656. ⟨10.1039/C8CC03934H⟩. ⟨hal-01948412⟩
  • Mickaël Henrion, Bernardo De P. Cardoso, Vincent César, Michael J. Chetcuti, Vincent Ritleng. Nickel(II) complexes of highly σ-donating cyclic (alkyl)(amino)- and malonate-carbenes: Syntheses and catalytic studies. Organometallics, American Chemical Society, 2017, 36 (6), pp.1113-1121. ⟨10.1021/acs.organomet.6b00906⟩. ⟨hal-01938384⟩
  • Mirko Ruamps, Noël Lugan, Vincent César. Experimental assessment of the π-acidity of anionic and neutral malonate-derived N-heterocyclic carbenes. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2017, pp.4167-4173. ⟨10.1002/ejic.201700883⟩. ⟨hal-01938381⟩
  • Mirko Ruamps, Noël Lugan, Vincent César. A cationic N-heterocyclic carbene containing an ammonium moiety. Organometallics, American Chemical Society, 2017, 36 (5), pp.1049-1055. ⟨10.1021/acs.organomet.7b00017⟩. ⟨hal-01938379⟩
  • Vincent César, Yin Zhang, Wioletta Kosnik, Adam Zielinski, Adam A. Rajkiewicz, et al.. Ruthenium catalysts supported by amino-substituted N-heterocyclic carbene ligands for olefin metathesis of challenging substrates. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (8), pp.1950-1955. ⟨10.1002/chem.201604934⟩. ⟨hal-01938386⟩
  • Yin Zhang, Guy Lavigne, Noël Lugan, Vincent César. Buttressing effect as a key design principle towards highly efficient palladium/N-heterocyclic carbene Buchwald–Hartwig amination catalysts. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (55), pp.13792-13801. ⟨10.1002/chem.201702859⟩. ⟨hal-01938383⟩
  • Dmitry A. Valyaev, Marina A. Uvarova, Alina A Grineva, Vincent César, Sergei N. Nefedov, et al.. Post-coordination backbone functionalization of an imidazol-2-ylidene and its application to synthesize heteropolymetallic complexes incorporating the ambidentate IMes(CO2-) ligand. Dalton Transactions, Royal Society of Chemistry, 2016, 45 (30), pp.11953-11957. ⟨10.1039/c6dt02060g⟩. ⟨hal-01925254⟩
  • Yin Zhang, Guy Lavigne, Vincent César. Buchwald–Hartwig Amination of (Hetero)Aryl Tosylates Using a Well-Defined N-Heterocyclic Carbene/Palladium(II) Precatalyst. Journal of Organic Chemistry, American Chemical Society, 2015, 80 (15), pp.7666-7673. ⟨10.1021/acs.joc.5b01272⟩. ⟨hal-02271027⟩
  • Yin Zhang, Vincent César, Guy Lavigne. Efficient and versatile Buchwald-Hartwig amination of (hetero)aryl chlorides using the Pd-PEPPSI-IPr(NMe2)2 precatalyst in the presence of carbonate base. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2015, pp.2042-2050. ⟨10.1002/ejoc.201500030⟩. ⟨hal-01909387⟩
  • Vincent César, Guy Lavigne. Olefin metathesis: Theory and practice. Edited by Karol Grela. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2015, 54 (13), pp.3856-3857. ⟨10.1002/anie.201501009⟩. ⟨hal-01909559⟩
  • Ludovik Noël-Duchesneau, Noël Lugan, Guy Lavigne, Agnès Labande, Vincent César. Customized Buchwald-type phosphines bearing an "inverted" pyrimidinium betaine as an aryl group surrogate - Synthesis and coordination chemistry with gold(I). European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.1752-1758. ⟨10.1002/ejic.201403205⟩. ⟨hal-01909388⟩
  • Stéphanie Bastin, Cécile Barthes, Noël Lugan, Guy Lavigne, Vincent César. Anionic N-heterocyclic carbene complexes of gold(I) as precatalysts for silver-free cycloisomerization of enynes. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.2216-2221. ⟨10.1002/ejic.201500168⟩. ⟨hal-01909389⟩
  • Vincent César, Guy Lavigne. Décoration du squelette N-hétérocyclique d’un ligand carbénique : effets électroniques associés et application à l’optimisation d’un catalyseur au palladium. L'Actualité Chimique, Société chimique de France, 2015, 392, pp.v-vi. ⟨hal-01909560⟩
  • Vincent César, Valentina Mallardo, Adela Nano, Georges Dahm, Noël Lugan, et al.. IMes-acac: Hybrid combination of diaminocarbene and acetylacetonato sub-units into a new anionic ambidentate NHC ligand. Chemical Communications, Royal Society of Chemistry, 2015, 51 (25), pp.5271-5274. ⟨10.1039/c4cc08641d⟩. ⟨hal-01909558⟩
  • Laure Benhamou, Stéphanie Bastin, Noël Lugan, Guy Lavigne, Vincent César. Metal-assisted conversion of an N-ylide mesomeric betaine into its carbenic tautomer: generation of N-(fluoren-9-yl)imidazol-2-ylidene complexes. Dalton Transactions, Royal Society of Chemistry, 2014, 43 (11), pp.4474-4482. ⟨10.1039/c3dt53089b⟩. ⟨hal-00990940⟩
  • Jianxia Zheng, Saravanakumar Elangovan, Dmitry A. Valyaev, Rémy Brousses, Vincent César, et al.. Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2014, 356 (5), pp.1093-1097. ⟨10.1002/adsc.201300905⟩. ⟨hal-01114930⟩
  • Ludovik Noël-Duchesneau, Noël Lugan, Guy Lavigne, A. Labande, Vincent César. Tailoring Buchwald-type phosphines with pyrimidinium betaines as versatile aryl group surrogates. Organometallics, American Chemical Society, 2014, 33 (19), pp.5085-5088. ⟨10.1021/om5007819⟩. ⟨hal-02023150⟩
  • Y. Zhang, Vincent César, G. Storch, Noël Lugan, Guy Lavigne. Skeleton decoration of NHCs by amino groups and its sequential booster effect on the palladium-catalyzed buchwald–hartwig amination. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2014, 53 (25), pp.6482-6486. ⟨10.1002/anie.201402301⟩. ⟨hal-02023184⟩
  • Vincent César, Stephane Labat, Karinne Miqueu, Jean-Marc Sotiropoulos, Rémy Brousses, et al.. The ambivalent chemistry of a free anionic N-heterocyclic carbene decorated with a malonate backbone: The plus of a negative charge. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19 (50), pp.17113-17124. ⟨10.1002/chem.201303184⟩. ⟨hal-00993532⟩
  • Vincent César, Cécile Barthes, Y.C. Farre, S.V. Cuisiat, B.Y. Vacher, et al.. Anionic and zwitterionic copper(I) complexes incorporating an anionic N-heterocyclic carbene decorated with a malonate backbone: synthesis, structure and catalytic applications. Dalton Transactions, Royal Society of Chemistry, 2013, 42 (20), pp.7373-7385. ⟨10.1039/c3dt32919d⟩. ⟨hal-00993531⟩
  • Vincent César, Luis C. Misal Castro, Thomas Dombray, Jean-Baptiste Sortais, Christophe Darcel, et al.. (Cyclopentadienyl)iron(II) complexes of N-heterocyclic carbenes bearing a malonate or imidate backbone: Synthesis, structure, and catalytic potential in hydrosilylation. Organometallics, American Chemical Society, 2013, 32 (16), pp.4643-4655. ⟨10.1021/om400625q⟩. ⟨hal-00993533⟩
  • Vincent César, Jean-Christophe Tourneux, Nadia Vujkovic, Rémy Brousses, Noël Lugan, et al.. Interplay between an elusive 4-(isopropylamino)imidazol-2-ylidene and its isolable mesoionic tautomer, and associated reactivities. Chemical Communications, Royal Society of Chemistry, 2012, 48 (17), pp.2349. ⟨10.1039/C2CC17870B⟩. ⟨hal-02909453⟩
  • Laure Benhamou, Edith Chardon, Guy Lavigne, Stéphane Bellemin-Laponnaz, Vincent César. Synthetic Routes to N-Heterocyclic Carbene Precursors. Chemical Reviews, American Chemical Society, 2011, 111 (4), pp.2705-2733. ⟨10.1021/cr100328e⟩. ⟨hal-03709046⟩
  • Laure Benhamou, Nadia Vujkovic, Vincent César, Heinz Gornitzka, Noël Lugan, et al.. Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties. Organometallics, American Chemical Society, 2010, 29 (11), pp.2616-2630. ⟨10.1021/om1003607⟩. ⟨hal-03710100⟩
  • Vincent César, Noël Lugan, Guy Lavigne. Reprogramming of a Malonic N‐Heterocyclic Carbene: A Simple Backbone Modification with Dramatic Consequences on the Ligand's Donor Properties. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2010, 2010 (3), pp.361-365. ⟨10.1002/ejic.200901113⟩. ⟨hal-03710153⟩
  • Vincent César, Noël Lugan, Guy Lavigne. Electronic Tuning of a Carbene Center via Remote Chemical Induction, and Relevant Effects in Catalysis. Chemistry - A European Journal, Wiley-VCH Verlag, 2010, 16 (37), pp.11432-11442. ⟨10.1002/chem.201000870⟩. ⟨hal-03709079⟩
  • Laure Benhamou, Joffrey Wolf, Vincent César, Agnès Labande, Rinaldo Poli, et al.. Chelation-Assisted Reactions of Phosphine- and Olefin-Tethered Imidazolium Derivatives and Their Affiliated N-Heterocyclic Carbenes with Roper’s Complex Ru(CO) 2 (PPh3)3. Organometallics, American Chemical Society, 2009, 28 (24), pp.6981-6993. ⟨10.1021/om900813p⟩. ⟨hal-03178363⟩
  • Laure Benhamou, Vincent César, Heinz Gornitzka, Noël Lugan, Guy Lavigne. Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization. Chemical Communications, Royal Society of Chemistry, 2009, pp.4720-4722. ⟨10.1039/B907908D⟩. ⟨hal-03710191⟩
  • Vincent César, Noël Lugan, Guy Lavigne. A Stable Anionic N-Heterocyclic Carbene and Its Zwitterionic Complexes. Journal of the American Chemical Society, American Chemical Society, 2008, 130 (34), pp.11286-11287. ⟨10.1021/ja804296t⟩. ⟨hal-03710216⟩
  • Laure Benhamou, Vincent César, Noël Lugan, Guy Lavigne. Snapshot of a Chelation-Assisted C-H/Alkyne Coupling: A Ruthenium Complex Caught in the Act of C-C Bond Formation. Organometallics, American Chemical Society, 2007, 26 (18), pp.4673-4676. ⟨10.1021/om7005003⟩. ⟨hal-02462875⟩
  • Alois Fürstner, Manuel Alcarazo, Vincent César, Christian Lehmann. Convenient, scalable and flexible method for the preparation of imidazolium salts with previously inaccessible substitution patterns. Chemical Communications, Royal Society of Chemistry, 2006, 20, pp.2176-2178. ⟨10.1039/B604236H⟩. ⟨hal-03710251⟩
  • Nathanaelle Schneider, Vincent César, Stéphane Bellemin-Laponnaz, Lutz Gade. Synthesis and structural chemistry of oxazolinyl-carbene copper(I) complexes. Journal of Organometallic Chemistry, Elsevier, 2005, 690 (24-25), pp.5556-5561. ⟨10.1016/j.jorganchem.2005.06.044⟩. ⟨hal-02123138⟩
  • Nathanaelle Schneider, Vincent César, Stéphane Bellemin-Laponnaz, Lutz Gade. Modular Assembly of a Chiral Bis(oxazolinyl)carbene: A New Meridionally Coordinating Tridentate Spectator Ligand. Organometallics, American Chemical Society, 2005, 24 (21), pp.4886-4888. ⟨10.1021/om0506769⟩. ⟨hal-02148631⟩
  • Vincent César, Stéphane Bellemin-Laponnaz, Hubert Wadepohl, Lutz Gade. Designing the “Search Pathway” in the Development of a New Class of Highly Efficient Stereoselective Hydrosilylation Catalysts. Chemistry - A European Journal, Wiley-VCH Verlag, 2005, 11 (9), pp.2862-2873. ⟨10.1002/chem.200500132⟩. ⟨hal-03710277⟩
  • Vincent César, Stéphane Bellemin-Laponnaz, Lutz H. Gade. Cationic and Neutral Rhodium( I ) Oxazolinylcarbene Complexes. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2004, 2004 (17), pp.3436-3444. ⟨10.1002/ejic.200400182⟩. ⟨hal-03710310⟩
  • Lutz Gade, Vincent César, Stéphane Bellemin-Laponnaz. A Modular Assembly of Chiral Oxazolinylcarbene–Rhodium Complexes: Efficient Phosphane-Free Catalysts for the Asymmetric Hydrosilylation of Dialkyl Ketones. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2004, 43 (8), pp.1014-1017. ⟨10.1002/anie.200353133⟩. ⟨hal-03710297⟩
  • Vincent César, Stéphane Bellemin-Laponnaz, Lutz Gade. Chiral N-heterocyclic carbenes as stereodirecting ligands in asymmetric catalysis. Chemical Society Reviews, Royal Society of Chemistry, 2004, 33 (9), pp.619-636. ⟨10.1039/B406802P⟩. ⟨hal-03710320⟩
  • Vincent César, Stéphane Bellemin-Laponnaz, Lutz Gade. Direct Coupling of Oxazolines and N-Heterocyclic Carbenes: A Modular Approach to a New Class of C−N Donor Ligands for Homogeneous Catalysis. Organometallics, American Chemical Society, 2002, 21 (24), pp.5204-5208. ⟨10.1021/om020608b⟩. ⟨hal-03710337⟩

Chapitres d'ouvrage

  • Vincent César, Christophe Fliedel, Agnès Labande. Chiral N-Heterocyclic Carbene-Based Ligands. Montserrat Diéguez. Chiral Ligands: Evolution of Ligand Libraries for Asymmetric Catalysis, CRC Press, pp.195-232, 2021, 978-0-367-4-28488. ⟨10.1201/9780367855734-6⟩. ⟨hal-03230806⟩
  • Vincent César, L. H. Gade, S. Bellemin-Laponnaz. NHC-Cobalt, -Rhodium, and -Iridium Complexes in Catalysis. Diez-Gonzalez, S. N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, 8, RSC Publishing, pp.302-335, 2017, Catalysis Series, 978-1-78262-423-3. ⟨hal-02042478⟩
  • Mirko Ruamps, Guy Lavigne, Vincent César. Synthesis of N-Heterocyclic Carbene Complexes. Nolan, S. P. and Cazin, C. S. J. N-Heterocyclic Carbenes in Catalytic Organic Synthesis, 1.1.4, Georg Thieme Verlag KG, pp.47-53, 2017, Science of Synthesis, 978-3-132-01281-3. ⟨hal-02042510⟩

Adresse

Laboratoire de chimie de coordination du CNRS

205 route de Narbonne, BP 44099
31077 Toulouse cedex 4
France