LCC
Activités de l’équipe
L’équipe développe des recherches fondamentales à visée appliquée dans le domaine de la catalyse. Les recherches menées visent à développer/étudier de nouveaux concepts en catalyse (effets de confinements, catalyse bimétalliques, catalyse sur atome unique), à mettre au point de nouveaux systèmes catalytiques et plus récemment à développer au travers de collaborations des outils spécifiques pour la catalyse (chimie en flux).
L’activation de petites molécules, en particulier pour l’énergie, et la fonctionnalisation de molécules biosourcées constituent les cibles privilégiées de l’équipe.
Membres de l’équipe
SERP Philippe
VOLKMAN Jérôme
BENDEHIBA Kamar
CASTILLOBALTAZAR Alejandro
CHECK-MOIDINE Moifica
DECHY-CABARET Odile
DURAND Jérôme
DURUPT Aurélien
EL HARAKE Abbas
GHEZLAOUI Katia
GOGOI Neelam
GREGORY Joseph
HAIDAR-AHMAD Zainab
IMLYHEN Nora
JIJI Alina-elza
KALCK Philippe
KANDWAL Kenya
LEAL Edgardo
MAHFOUDI Abderraouf
MARCHAND Quentin
MUTHUMUNIYANDI Nishanthan
PASINI Edoardo
POINTIS Romane
RASAMINIRINA Toky
ROBERTSON Haley
ROMANA Idaline
ROPIQUET Laurent
SARMA Bidyut Bikash
SHAFIQ Seema
SORTAIS Jean-Baptiste
URRUTIGOÏTY Martine
VIDAL Mathieu
Thèmes de recherche
Catalyseurs hétérogènes pour la chimie fine et l’énergie
Il s’agit de développer des stratégies novatrices (catalyse en milieu confiné, cocktail de catalyseurs, catalyse interfaciale de «Pickering», catalyseur par auto-assemblage) pour la mise au point de (nano)catalyseurs hétérogènes performants pour des réactions de la chimie fine (hydrogénation sélective) ou liées à l’énergie (synthèse Fischer-Tropsch, activation du CO2, ORR).
Catalyseurs single-site
Les projets de ce thème sont basés sur des systèmes catalytiques dits single site (catalyseurs moléculaires supportés et atomes uniques) immobilisés sur des supports carbonés comme le graphène ou les nanotubes de carbone, visant au développement de processus à faible impact environnemental (économie d’atome, recyclage des catalyseurs, mise en œuvre dans des procédés en continu et/ou sans solvant).
Catalyseurs homogènes pour la chimie fine et l’énergie
Nous développons de nouveaux catalyseurs organométalliques et supramoléculaires (complexes {hôte-invité}) pour des réactions cascades énantiosélectives comme la réaction d’hydroaminométhylation asymétrique.
Actualités de l’équipe
Participation marquante du LCC à l’ISGC, rendez-vous international de la chimie verte
Le LCC a contribué avec six communications orales, reflétant l’implication du laboratoire dans les enjeux de transition écologique et de son rayonnement au sein de la communauté scientifique internationale.
Philippe Serp nommé membre senior de l’Institut universitaire de France
Lauréat au titre de la chaire fondamentale
3ème école d’été « Catalysis: from understanding to application » à Albi : un grand succès !
Eric Manoury (équipe G) et Philippe Serp (équipe C) font partie du comité d’organisation de cette école : réseau catalyse à Toulouse
Publications
2025
Minuscule amounts of Pt single atoms selectively loaded on minor (101) facet of anatase crystallites enables outstanding utilization efficiency for photocatalytic H2 production
Qin S., Denisov N., Osuagwu B., Kolařík J., Sarma B. B., Baďura Z., Schmuki P.
Adv. Funct. Mater. 2025, 35(24), 2423088/1-9.
10.1002/adfm.202423088 – hal-05141811
Cyclometallated phosphonium ylide-based iridium(III) photocatalysts
Fayafrou O., Zanzi J., Duhayon C., Sortais J.-B., Baslé O., Canac Y.
Chem Commun. 2025, 61(54), 9932-9935.
10.1039/D5CC02320C – hal-05111236
Supported Co-based catalytic systems for the epoxidation of terpenes using O2 as oxidant
Rais M., Soulié J., Tendero C., Durand J.
Eur. J. Inorg. Chem. 2025, 28(5), e202400293/1-14.
10.1002/ejic.202400293 – hal-04836205
From Co to Co@Co2P and CoP nanorods: synthesis and performances in selective hydrogenation of phenylacetylene
Azeredo B., Nguyen-Cong J., Vidal M., Shafiq S., Vu T. T., Muzzi B., Marty A., Min Y., Ferrari F., Delpech F., Nayral C., Fazzini P.-F., Blon T., Serp P., Viau G., Soulantica K.
Nanoscale 2025, 17(23), 14248-14262.
10.1039/D5NR00618J – hal-05111297
Highly efficient palladium-catalyzed carbonylation reactions of terpenes
Oukhrib A., Kalck P., Urrutigoïty M.
Coord. Chem. Rev. 2025, 531, 216453/1-10.
10.1016/j.ccr.2025.216453 – hal-05068408
Fischer-Tropsch synthesis on carbon-supported Co catalysts coated on metallic foams
Ghogia A. C., Durupt A., Guicheret B., Cayez S., Machado B. F., Soulantica K., Serp P., Philippe R., Pham Minh D.
Int. J. Hydrogen Energy 2025, 114, 452-461.
10.1016/j.ijhydene.2025.02.470 – hal-04998344
Pd single atoms on g-C3N4photocatalysts: minimum loading for maximum activity
Jeyalakshmi V., Wu S., Qin S., Zhou X., Sarma B. B., Doronkin D. E., Kolařík J., Šoóš M., Schmuki P.
Chem. Sci. 2025, 16(11), 4788-4795.
10.1039/D4SC08589B – hal-05064320
Toward decorrelation of surface oxygen groups from metal dispersion effects in Pd/C hydrogenation catalysts
Leal Villarroel E. A., Marcelot C., Torres C. C., Soulantica K., Campos C. H., Serp P.
Catal. Sci. Technol. 2025, 15(6), 2034-2048.
10.1039/D4CY01562B – hal-05057511
High pressure equilibrium data of CO2/cyclohexene oxide and CO2/limonene oxide systems in the context of polycarbonate synthesis using CO2 as a co-monomer
Pasini E. V., Durand J., Camy S.
Fluid Phase Equilib. 2025, 595, 114406/1-11.
10.1016/j.fluid.2025.114406 – hal-04996728
Generation of electronically unsaturated carbon sites on carbon materials and study of their magnetic and chemical properties
Vidal M., Dehaghani M. S., Navarro-Ruiz J., Yoshii T., Wakabayashi K., Nishihara H., Barreau M., Bournel F., Volkman J., Clet G., Zafeiratos S., Le Breton N., Puech P., Gerber I. C., Boudalis A. K., Blon T., Serp P.
J. Phys. Chem. C 2025, 129(7), 3539-3560.
10.1021/acs.jpcc.4c07975 – hal-04975505
Single-atom catalysts on C3N4: Minimizing single atom Pt loading for maximized photocatalytic hydrogen production efficiency
Lazaar N., Wu S., Qin S., Hamrouni A., Sarma B. B., Doronkin D. E., Denisov N., Lachheb H., Schmuki P.
Angew. Chem., Int. Ed. 2025, 64(6), e202416453/1-8.
10.1002/anie.202416453 – hal-04927966
Weakly-activated phenol derivatives as new green electrophilic partners in Suzuki–Miyaura and related C-C couplings
Perney J., Humblot-Negri A., Vaca-Garcia C., Lemouzy S., Urrutigoïty M.
Molecules 2025, 30(1), 51/1-25.
10.3390/molecules30010051 – hal-04869377
Efficient solid-phase RNA extraction using carbon nanomaterials
Videira A. M., Ferreira P. L., Sampaio M. J., Serp P., Faria J. L., Silva C. G., Sousa F.
Colloids Surf., A 2025, 704, 135532/1-12.
10.1016/j.colsurfa.2024.135532 – hal-04759694
Alternative Routes to Chemical Methanol Products
Kalck P.
in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, J. Reedijk (Ed.), Elsevier: 2025, pp. 525-534. (978-0-12-409547-2).
10.1016/B978-0-443-15740-0.00142-7 – hal-04933027
Non-covalent immobilization of chiral rhodium catalysts on carbon nanotubes for asymmetric hydrogenation
Arora Z., Rais M., Pârvulescu V. I., Philippot K., Durand J., Gouygou M.
ChemNanoMat 2025, 11(2), e202400125/1-11.
10.1002/cnma.202400125 – hal-04931851
2024
Low temperature Sabatier CO2 methanation
Molinet-Chinaglia C., Shafiq S., Serp P.
ChemCatChem 2024, 16(24), e202401213/1-39.
https://doi.org/10.1002/cctc.202401213
https://hal.science/hal-04844107
Probing prismatic/basal surfaces of carbon materials upon graphitization by gas adsorption, TPD, and XPS
Vidal M., Dehaghani M. S., Yoshii T., Wakabayashi K., Cameán I., Barreau M., Le Breton N., Gerber I. C., Puech P., Boudalis A. K., Blon T., Placke T., Nishihara H., Zafeiratos S., Serp P.
The Journal of Physical Chemistry C 2024, 128(44), 18993-19012.
https://doi.org/10.1021/acs.jpcc.4c06100
https://hal.science/hal-04778412
Understanding the role of supported Rh atoms and clusters during hydroformylation and CO hydrogenation reactions with in situ/operando XAS and DRIFT spectroscopy
Sarma B. B., Neukum D., Doronkin D. E., Lakshmi Nilayam A. R., Baumgarten L., Krause B., Grunwaldt J.-D.
Chemical Science 2024, 15(31), 12369-12379.
http://dx.doi.org/10.1039/D4SC02907K
https://hal.science/hal-04692606
Probing basal and prismatic planes of graphitic materials for metal single atom and subnanometer cluster stabilization
Vidal M., Pandey J., Navarro-Ruiz J., Langlois J., Tison Y., Yoshii T., Wakabayashi K., Nishihara H., Frenkel A. I., Stavitski E., Urrutigoïty M., Campos C. H., Godard C., Placke T., del Rosal I., Gerber I. C., Petkov V., Serp P.
Chemistry – A European Journal 2024, 30(50), e202400669/1-18.
https://doi.org/10.1002/chem.202400669
https://hal.science/hal-04677240
Synthesis, characterization, and inhibition effects of a novel eugenol derivative bearing pyrrole functionalities on the corrosion of mild steel in a HCl acid solution
Rebbah B., El Haib A., Lahmady S., Forsal I., Gouygou M., Mallet-ladeira S., Medaghri-alaoui A., Rakib E. M., Hannioui A.
RSC Advances 2024, 14(20), 14152-14160.
http://dx.doi.org/10.1039/D4RA01337A
https://hal.science/hal-04669077
Olefins Hydrofunctionnalization; Hydroformylation and Hydrocarboxyamination
Langlois J., Urrutigoïty M., Godard C.
in Comprehensive Chirality, J. Cossi (Ed.), Elsevier: Amsterdam, 2024, pp. 74-118. (978-0-323-90645-6).
https://doi.org/10.1016/B978-0-32-390644-9.00019-6
https://hal.science/hal-04543415
Operando spectroscopy to understand dynamic structural changes of solid catalysts
Sarma B. B., Grunwaldt J.-D.
CHIMIA 2024, 78(5), 288-296.
https://doi.org/10.2533/chimia.2024.288
https://hal.science/hal-04593870
Mechanism of hydrogen spillover on metal-doped carbon materials: surface carboxylic groups are key
Navarro-Ruiz J., Audevard J., Vidal M., Campos C. H., Del Rosal I., Serp P., Gerber I. C.
ACS Catalysis 2024, 14(9), 7111-7126.
https://doi.org/10.1021/acscatal.4c00293
https://hal.science/hal-04587084
Effects of Pd and Co intimacy in Pd-modified Co/TiO2 catalysts for direct CO2 hydrogenation to fuels: the closer not the better
Scarfiello C., Durupt A., Tison Y., Pham Minh D., Soulantica K., Serp P.
Catalysis Science & Technology 2024, 14(10), 2896-2907.
https://doi.org/10.1039/d4cy00324a
https://hal.science/hal-04552701
A generic hybrid method combining rules and machine learning to automate domain independent ontology population
Chasseray Y., Barthe-Delanoë A.-M., Volkman J., Négny S., Le Lann J.-M.
Engineering Applications of Artificial Intelligence 2024, 133(Part F), 108571/1-14.
https://doi.org/10.1016/j.engappai.2024.108571
https://hal.science/hal-04574327
Confinement Effects in Catalysis with Molecular Complexes Immobilized into Porous Materials
Gouygou M., Serp P., Durand J.
in Catalysis in Confined Frameworks: Synthesis, Characterization, and Applications, H. Garcia, A. Dhakshinamoorthy (Eds). Wiley-VCH: Weinheim, 2024, pp. 273-314. (978-3-52735-089-6).
https://doi.org/10.1002/9783527839278.ch8
https://hal.science/hal-04269946
2023
Modified Co/TiO2 catalysts for CO2 hydrogenation to fuels
Scarfiello C., Soulantica K., Cayez S., Durupt A., Viau G., Le Breton N., Boudalis A. K., Meunier F., Clet G., Barreau M., Salusso D., Zafeiratos S., Pham Minh D., Serp P.
Journal of Catalysis 2023, 428, 115202/1-19.
https://doi.org/10.1016/j.jcat.2023.115202
https://hal.science/hal-04284797
Direct evidence of dynamic metal support interactions in Co/TiO2 catalysts by near-ambient pressure X-ray photoelectron spectroscopy
Salusso D., Scarfiello C., Efimenko A., Pham Minh D., Serp P., Soulantica K., Zafeiratos S.
Nanomaterials 2023, 13(19), 2672/1-16.
https://doi.org/10.3390/nano13192672
https://hal.science/hal-04224403
Synergy between supported metal single atoms and nanoparticles and their relevance in catalysis
Serp P.
ChemCatChem 2023, 15(15), e202300545/1-12.
https://doi.org/10.1002/cctc.202300545
https://hal.science/hal-04174631
“Cocktail”-type catalysis on bimetallic systems for cinnamaldehyde selective hydrogenation: Role of isolated single atoms, nanoparticles and single atom alloys
Audevard J., Navarro-Ruiz J., Bernardin V., Philippe R., Corrias A., Tison Y., Favre-Réguillon A., Del Rosal I., Gerber I. C., Serp P.
Journal of Catalysis 2023, 425, 245-259.
https://doi.org/10.1016/j.jcat.2023.06.023
https://hal.science/hal-04139552
Deactivation of Pd/C catalysts by irreversible loss of hydrogen spillover ability of the carbon support
Vanoye L., Guicheret B., Rivera-Cárcamo C., Audevard J., Navarro-Ruiz J., del Rosal I., Gerber I. C., Campos C. H., Machado B., Volkman J., Philippe R., Serp P., Favre-Réguillon A.
Journal of Catalysis 2023, 424, 173-188.
https://doi.org/10.1016/j.jcat.2023.05.006
https://hal.science/hal-04113228
Acetophenone hydrogenation and consecutive hydrogenolysis with Pd/CNT catalysts: Highlighting the synergy between single atoms and nanoparticles by kinetic modeling
Bernardin V., Vanoye L., Rivera-Cárcamo C., Serp P., Favre-Réguillon A., Philippe R.
Catalysis Today 2023, 422, 114196/1-9.
https://doi.org/10.1016/j.cattod.2023.114196
https://hal.science/hal-04107663
Selective denitrification of simulated oily wastewater by oxidation using Janus-structured carbon nanotubes
Roman F. F., Diaz de Tuesta J. L., Sanches F. K. K., Santos Silva A., Marin P., Machado B. F., Serp P., Pedrosa M., Silva A. M. T., Faria J. L., Gomes H. T.
Catalysis Today 2023, 420, 114001/1-13.
https://doi.org/10.1016/j.cattod.2023.01.008
https://hal.science/hal-04107573
Adjustment of the single atom/nanoparticle ratio in Pd/CNT catalysts for phenylacetylene selective hydrogenation
Audevard J., Navarro-Ruiz J., Bernardin V., Tison Y., Corrias A., Del Rosal I., Favre-Réguillon A., Philippe R., Gerber I. C., Serp P.
ChemCatChem 2023, 15(11), e202300036/1-18.
https://doi.org/10.1002/cctc.202300036
https://hal.science/hal-04102599
Oxide supported cobalt catalysts for CO2 hydrogenation to hydrocarbons: recent progress
Scarfiello C., Pham Minh D., Soulantica K., Serp P.
Advanced Materials Interfaces 2023, 10(15), 2202516/1-15.
https://doi.org/10.1002/admi.202202516
https://hal.science/hal-04078884
Ecodesigned formulations with tomato pomace extracts
Jamaleddine A., Urrutigoïty M., Bouajila J., Merah O., Evon P., de Caro P.
Cosmetics 2023, 10(1), 7/1-16.
https://doi.org/10.3390/cosmetics10010007
https://hal.science/hal-03921276
Etching suppression as a means to Pt dendritic ultrathin nanosheets by seeded growth
Yi D., Marcelot C., Romana I., Tassé M., Fazzini P.-F., Peres L., Ratel-Ramond N., Decorse P., Warot-Fonrose B., Viau G., Serp P., Soulantica K.
Nanoscale 2023, 15(4), 1739-1753.
http://dx.doi.org/10.1039/D2NR05105B
https://hal.science/hal-03923275
2022
Tuning CO2 hydrogenation selectivity on Ni/TiO2 catalysts via sulfur addition
Le Berre C., Falqui A., Casu A., Debela T. T., Barreau M., Hendon C. H., Serp P.
Catalysis Science & Technology 2022, 12(22), 6856-6864.
http://dx.doi.org/10.1039/D2CY01280D
https://hal.archives-ouvertes.fr/hal-03854711
Carbonylative Suzuki coupling catalyzed by Pd complexes based on [N,P]-pyrrole ligands: Direct access to 2-hydroxybenzophenones
Cortés-Mendoza S., Adamczyk D., Badillo-Goméz J. I., Urrutigoïty M., Ortega-Alfaro M. C., López-Cortés J. G.
Advanced Synthesis & Catalysis 2022, 364(16), 2837-2845.
https://doi.org/10.1002/adsc.202200456
https://hal.archives-ouvertes.fr/hal-03790205
Amaranth oilseed composition and cosmetic applications
Sayed-Ahmad B., Urrutigoïty M., Hijazi A., Saad Z., Cerny M., Evon P., Talou T., Merah O.
Separations 2022, 9(7), 181/1-15.
https://doi.org/10.3390/separations9070181
https://hal.archives-ouvertes.fr/hal-03737807
Solvent-free hydrogenation of squalene using parts per million levels of palladium supported on carbon nanotubes: Shift from batch reactor to continuous-flow system
Guicheret B., Vanoye L., Rivera-Cárcamo C., de Bellefon C., Serp P., Philippe R., Favre-Réguillon A.
ChemSusChem 2022, 15(19), e202200916/1-11.
https://doi.org/10.1002/cssc.202200916
https://hal.archives-ouvertes.fr/hal-03759560
Graphitic carbon nitride/few-layer graphene heterostructures for enhanced visible-LED photocatalytic hydrogen generation
Boumeriame H., Machado B. F., Moura N. M. M., Serp P., Andrade L., Lopes T., Mendes A., Chafik T., Da Silva E. S., Faria J. L.
International Journal of Hydrogen Energy 2022, 47(61), 25555-25570.
https://doi.org/10.1016/j.ijhydene.2022.05.285
https://hal.archives-ouvertes.fr/hal-03765847
Epsilon cobalt nanoparticles as highly performant catalysts in cinnamaldehyde selective hydrogenation
Yi D., Min Y., Muzzi B., Marty A., Romana I., Fazzini P.-F., Blon T., Viau G., Serp P., Soulantica K.
ACS Applied Nano Materials 2022, 5(4), 5498-5507.
https://doi.org/10.1021/acsanm.1c04444
https://hal.archives-ouvertes.fr/hal-03648853
Process intensification of the catalytic hydrogenation of squalene using a Pd/CNT catalyst combining nanoparticles and single atoms in a continuous flow reactor
Vanoye L., Guicheret B., Rivera-Cárcamo C., Castro Contreras R., de Bellefon C., Meille V., Serp P., Philippe R., Favre-Réguillon A.
Chemical Engineering Journal 2022, 441, 135951/1-10.
https://doi.org/10.1016/j.cej.2022.135951
https://hal.archives-ouvertes.fr/hal-03622463
Supported Metal Single Atom Catalysis
Serp P., Pham Minh D. (Eds.)
Wiley‐VCH: Weinheim, 2022. (978-3-527-34844-2).
https://doi.org/10.1002/9783527830169
https://hal.archives-ouvertes.fr/hal-03585648
Introduction to Supported Metal Single Atom Catalysis
Pham Minh D., Serp P.
in Supported Metal Single Atom Catalysis, Serp P., Pham Minh D. (Eds.). Wiley‐VCH: Weinheim, 2022, pp. 1-49. (978-3-527-34844-2).
https://doi.org/10.1002/9783527830169.ch1
https://hal.archives-ouvertes.fr/hal-03585679
Preparation of Supported Metal Single-Atom Catalysts on Metal Oxides and Hydroxides
Scarfiello C., Audevard J., Le Berre C., Soulantica K., Serp P., Pham Minh D.
in Supported Metal Single Atom Catalysis, Serp P., Pham Minh D. (Eds.). Wiley-VCH: Weinheim, 2022, pp. 51-99. (978-3-527-34844-2).
https://doi.org/10.1002/9783527830169.ch2
https://hal.archives-ouvertes.fr/hal-03585699
Preparation of Supported Metal Single-Atom Catalysts on Carbon Supports
Rivera-Cárcamo C., Serp P.
in Supported Metal Single Atom Catalysis, Serp P., Pham Minh D. (Eds.). Wiley-VCH: Weinheim, 2022, pp. 101-144. (978-3-527-34844-2).
https://doi.org/10.1002/9783527830169.ch3
https://hal.archives-ouvertes.fr/hal-03644355
Interrupted intramolecular hydroaminomethylation of N-protected-2-vinyl anilines: Novel access to 3-substitued indoles or indoline-2-ols
Hochberger-Roa F., García-Ríos P. H., López-Cortés J. G., Ortega-Alfaro M. C., Daran J.-C., Gouygou M., Urrutigoïty M.
Molecules 2022, 27(3), 1074/1-12.
https://doi.org/10.3390/molecules27031074
https://hal.archives-ouvertes.fr/hal-03592301
Multifunctional catalytic properties of Pd/CNT catalysts for 4-nitrophenol reduction
Audevard J., Benyounes A., Castro Contreras R., Abou Oualid H., Kacimi M., Serp P.
ChemCatChem 2022, 14(4), e202101783/1-13.
https://doi.org/10.1002/cctc.202101783
https://hal.archives-ouvertes.fr/hal-03585165
2021
Photocatalytic and biocidal activities of ZnTiO2 oxynitride heterojunction with MOF-5 and g-C3N4: A case study for textile wastewater treatment under direct sunlight
Younis S. A., Serp P., Nassar H. N.
Journal of Hazardous Materials 2021, 410, 124562/1-16.
https://doi.org/10.1016/j.jhazmat.2020.124562
https://hal.archives-ouvertes.fr/hal-03188836
Potential applicability of Zn0.05TiOxNy@MOF-5 nanocomposite for adsorption and electrochemical detection of Zn(II) in saline wastewater
Younis S. A., Ali T. A., Serp P.
Journal of Environmental Chemical Engineering 2021, 9(5), 106186/1-16.
https://doi.org/10.1016/j.jece.2021.106186
https://hal.archives-ouvertes.fr/hal-03329117
Cobalt-catalyzed carbonylations
Volkman J., Kalck P.
in Carbon Monoxide in Organic Synthesis. Carbonylation Chemistry, Gabriele B. (Ed.). Wiley-VCH: Weinheim, 2021, pp. 13-49. (978-3-527-34795-7).
https://doi.org/10.1002/9783527829354.ch2
https://hal.archives-ouvertes.fr/hal-03412623
Cooperativity in supported metal single atom catalysis
Serp P.
Nanoscale 2021, 13(12), 5985-6004.
http://dx.doi.org/10.1039/D1NR00465D
https://hal.archives-ouvertes.fr/hal-03188844
Supported catalysts for induction-heated steam reforming of methane
Scarfiello C., Bellusci M., Pilloni L., Pietrogiacomi D., La Barbera A., Varsano F.
International Journal of Hydrogen Energy 2021, 46(1), 134-145.
https://doi.org/10.1016/j.ijhydene.2020.09.262
https://hal.archives-ouvertes.fr/hal-03138948
Phospholylmethano P-chirogenic-phosphine-borane as P-(η2-BH3)-chelating ligands of rhodium (I): Synthesis, characterization and asymmetric hydrogenation
Salomon-Bertrand C., Bayardon J., Lauréano H., Jugé S., Daran J.-C., Gouygou M.
Journal of Organometallic Chemistry 2021, 938, 121753/1-7.
https://doi.org/10.1016/j.jorganchem.2021.121753
https://hal.archives-ouvertes.fr/hal-03202816v1
Stabilization of metal single atoms on carbon and TiO2 supports for CO2 hydrogenation: The importance of regulating charge transfer
Rivera-Cárcamo C., Scarfiello C., García A. B., Tison Y., Martinez H., Baaziz W., Ersen O., Le Berre C., Serp P.
Advanced Materials Interfaces 2021, 8(8), 2001777/1-17.
https://doi.org/10.1002/admi.202001777
https://hal.archives-ouvertes.fr/hal-03043523
Control of the single atom/nanoparticle ratio in Pd/C catalysts to optimize the cooperative hydrogenation of alkenes
Rivera-Cárcamo C., Gerber I. C., del Rosal I., Guicheret B., Castro Contreras R., Vanoye L., Favre-Réguillon A., Machado B. F., Audevard J., de Bellefon C., Philippe R., Serp P.
Catalysis Science & Technology 2021, 11(3), 984-999.
http://dx.doi.org/10.1039/D0CY01938K
https://hal.archives-ouvertes.fr/hal-03148510
Computational design of Pd nanoclusters and Pd single-atom catalysts supported on O-functionalized graphene
Navarro-Ruiz J., Rivera-Cárcamo C., Machado B., Serp P., Del Rosal I., Gerber I. C.
ACS Applied Nano Materials 2021, 4(11), 12235-12249.
https://doi.org/10.1021/acsanm.1c02743
https://hal.archives-ouvertes.fr/hal-03454499
Nanocatalysts for high selectivity enyne cyclization: Oxidative surface reorganization of gold sub-2-nm nanoparticle networks
Nasrallah H. O., Min Y., Lerayer E., Nguyen T.-A., Poinsot D., Roger J., Brandès S., Heintz O., Roblin P., Jolibois F., Poteau R., Coppel Y., Kahn M. L., Gerber I. C., Axet M. R., Serp P., Hierso J.-C.
JACS Au 2021, 1(2), 187–200.
https://doi.org/10.1021/jacsau.0c00062
https://hal.archives-ouvertes.fr/hal-03129914
Origin of the synergistic effect between TiO2 crystalline phases in the Ni/TiO2-catalyzed CO2 methanation reaction
Messou D., Bernardin V., Meunier F., Borges Ordoño M., Urakawa A., Machado B. F., Collière V., Philippe R., Serp P., Le Berre C.
Journal of Catalysis 2021, 398, 14-28.
https://doi.org/10.1016/j.jcat.2021.04.004
https://hal.science/hal-03627539
Cobalt catalysts on carbon-based materials for Fischer-Tropsch synthesis: a review
Ghogia A. C., Nzihou A., Serp P., Soulantica K., Pham Minh D.
Applied Catalysis A: General 2021, 609, 117906/1-50.
https://doi.org/10.1016/j.apcata.2020.117906
https://hal.archives-ouvertes.fr/hal-03000797
Beyond confinement effects in Fischer-Tropsch Co/CNT catalysts
Ghogia A. C., Machado B. F., Cayez S., Nzihou A., Serp P., Soulantica K., Pham Minh D.
Journal of Catalysis 2021, 397, 156-171.
https://doi.org/10.1016/j.jcat.2021.03.027
https://hal.archives-ouvertes.fr/hal-03201678
Transition-Metal-Catalyzed Chiral Amines Synthesis
Cunillera A., Claver C., Godard C., Urrutigoïty M., Kalck P.
in Methodologies in Amine Synthesis: Challenges and Applications, Ricci A., Bernardi L. (Eds.). Wiley-VCH: Weinheim, 2021, pp. 155-185. (978-3-527-34739-1).
https://doi.org/10.1002/9783527826186.ch5
https://hal.archives-ouvertes.fr/hal-03241440
Ruthenium complex based on [N,N,O] tridentate -2-ferrocenyl-2-thiazoline ligand for catalytic transfer hydrogenation
Badillo-Gómez J. I., Sánchez-Rodríguez E. P., Toscano R. A., Gouygou M., Ortega-Alfaro M. C., López-Cortés J. G.
Journal of Organometallic Chemistry 2021, 932, 121630 /1-10.
https://doi.org/10.1016/j.jorganchem.2020.121630
https://hal.archives-ouvertes.fr/hal-03108979
2-Thiazolines: an update on synthetic methods and catalysis
Badillo-Gómez J. I., Gouygou M., Ortega-Alfaro M. C., López-Cortés J. G.
Organic & Biomolecular Chemistry 2021, 19(35), 7497-7517.
http://dx.doi.org/10.1039/D1OB01180D
https://hal.archives-ouvertes.fr/hal-03669255
BF3·OEt2-catalyzed rearrangement of epoxy-himachalenes: Access to new biosourced N-acetamide-based himachalenes
Ait El Had M., Zaki M., Taourirte M., Benharref A., Urrutigoïty M., Oukhrib A.
Synlett 2021, 32(03), 309-315.
https://doi.org/10.1055/s-0040-1706545
https://hal.archives-ouvertes.fr/hal-03237051
Partenariats
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Laboratoire de Génie Chimique, UMR 5503 (Prof. Séverine Camy, Prof. Anne-Marie Billet)
Université de Trieste, Italie (Dr Barbara Milani)
Centre of Catalysis and Catalytic Processes, University of Bucharest, Roumanie (Prof. Vasile I. Parvulescu)
Laboratoire de Physique et Chimie des Nano-objets UMR 5215 (Dr. Katerina Soulantika, Dr. Iann Gerber, Dr. Iker del Rosal)
Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) UMR 6302 (Prof. Dr. Jean-Cyrille Hierso)
Laboratoire Catalyse, Polymérisation, Procédés et Matériaux UMR 5128 (Dr. Régis Philippe)
Recherche d’Albi en génie des Procédés des Solides Divisés, de l’Énergie et de l’Environnement (RAPSODEE) UMR CNRS 5302 (Dr. Doan Pham Minh)
Institut de Recherches sur la Catalyse et l’Environnement de Lyon – UMR5256 (Dr. Frédéric Meunier)
Institut de physique et de chimie des Matériaux de Strasbourg (IPCMS) UMR 7504 (Prof. Dr. Ovidiu Ersen)
Department of Physics, University of Milan, Italie (Prof. Dr. Andrea Falqui)
Nazario Martín Group, University Complutense of Madrid, Espagne (Prof. Dr. Nazario Martin)
Etzoldlab, University of Darmstadt, Allemagne (Prof. Dr. Bastian Etzold)
LSRE-LCM, University of Porto, Portugal (Dr. Joaquim Faria, Dr. Bruno Machado, Dr Cláudia Gomes Silva)
Departamento de Ciencias Químicas Universidad Andrés Bello, Chili (Dr. Cecilia Carolina Torres Muñoz)
Analysis and Evaluation Department Egyptian Petroleum Research Institute (EPRI), Egypte (Dr. Sherif A. Younis)
IFP Energies nouvelles (Dr. Amandine Cabiac)
Université Nationale Autonome de Mexico , Mexique (Dr. J. G. López Cortés et
M. C. Ortega Alfaro)
Financements
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Académiques : ANR, Europe, INPT, NanoX, Région Occitanie, Région Aquitaine, Université Fédérale Toulouse Midi-Pyrénées
Industriels : Arkema, CEA Tech, Celanese, IFPEN
Alumnae
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2005
CORRIAS, Massimiliano – Examinateur brevets à l’Office Européen des Brevets de La Haye (Pays-Bas)
LAMOUROUX, Emmanuel – Maître de Conférences à l’Université de Nancy
HEBRARD, Frédéric
2006
PHILIPPE, Régis – Chargé de Recherche CNRS au Laboratoire Catalyse, Polymérisation, Procédés et Matériaux UMR 5128
LASSAUQUE, Nicolas – Agriculteur à Carros (06)
2007
DIAB, Lisa – Research position by Syngenta, University of Freiburg (Allemagne)
BACHELIER, Alice – Ingénieur, EHS Engineering Wind Turbine- General Electric Renewable- Nantes
COSTES, Philippe – Superviseur qualité chez Santé Publique France pour le compte d’EFOR Healthcare
2009
TEDDY, Jacques – Business Development Manager, TEYOMA SAL (Liban)
RODRIGUEZ PEREZ, Laura – Chercheuse Université Complutense Madrid (Espagne)
2010
BEAUSOLEIL, Julien – Ingénieur R&D Arkema
FUENTE-HERNANDEZ, Ariadna – Researcher, Products and Processes Development chez Enerkem (Canada)
FABRELLO, Amandine – Scientific Project Manager chez Hach (Suisse)
2011
OUBENALI, Mustapha – Enseignant-chercheur University Sultan Moulay Slimane (Maroc)
EL HAIB, Abderrahim – Enseignant-chercheur Faculté polydisciplinaire de Beni Mellal (Maroc)
CROZET, Delphine – Ingénieur R&D Total Energie
ADCOCK, Romain – R&D Project Manager chez Miyoshi Europe
2012
TUNCKOL, Meltem – Chef d’entreprise Mexems Inc. (Turquie)
2013
NGUYEN, Trang Tuyet – Enseignant-chercheur, University of Science and Technology of Hanoi (Vietnam)
FOURMY, Kevin – Responsable R&D MLPC International
ZHANG Liping – Enseignant-chercheur, Jiangnan university, Wuxi (Chine)
2014
LI, Xiaojian – Ingénieur R&D chez Daimler (Chine)
GOGOLIEVA, Ganna – Chef de Marché-Chimie de Spécialité à MLPC International-ARKEMA group
El KARROUMI, Jamal – Enseignant-chercheur, Cadi Ayyad University (Maroc)
BENYOUNES, Anas – Enseignant-chercheur, Faculté des Sciences Rabat (Maroc)
2015
OUKHRIB, Abdelouahd – Enseignant-chercheur, Cadi Ayyad University (Maroc)
2016
HARMEL, Justine – PostDoc Centre Inter-universitaire de Recherche et d’Ingénierie des Matériaux – UMR CNRS 5085
LENG, Faqiang – Enseignant-chercheur, School of pharmaceutical sciences of Capital Medical University, Pekin (Chine).
2017
LOUISIA, Stéphane – Chargé de mission recherche au conseil régional d’Ile-de-France.
2018
GIMENO Nicolas – Consultant AlisPharm Qualification/Validation Actionnaire chez Time for the Planet
2019
RADJAGOBALOU, Robbie – PostDoc Institut de Recherche de Chimie Paris
2020
MIN, Yuayuan – PostDoc Laboratoire de Physique et Chimie des Nano-objets UMR 5215
RIVERA-CARCAMO, Camila – PostDoc Institut de chimie et procédés pour l’énergie, l’environnement et la santé (ICPEES) UMR 7515
2021
GHOGIA, Amel – PostDoc Recherche d’Albi en génie des Procédés des Solides Divisés, de l’Énergie et de l’Environnement (RAPSODEE) UMR CNRS 5302
BADILLO GOMEZ, Joel Iván – PostDoc Université de Rouen
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