Exploring the chemistry of ruthenium complexes with a bidentate barbiturate-imidazo[1,5-a]pyridinylidene ligand
Krzesiński P., Gajda K., Vendier L., Kajetanowicz A., Grela K., Bastin S., César V.
Zeitschrift fur Anorganische und Allgemeine Chemie 2024, e202400199.
https://doi.org/10.1002/zaac.202400199
https://hal.science/hal-04785126

Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)₂MnH] on their kinetic hydricity
Kovalenko S. A., Gulyaeva E. S., Osipova E. S., Filippov O. A., Danshina A. A., Vendier L., Kireev N. V., Godovikov I. A., Canac Y., Valyaev D. A., Belkova N., Shubina E. S.
Dalton Transactions 2024,
http://dx.doi.org/10.1039/D4DT02496F
https://hal.science/hal-04769905

A Pd(II) complex exhibiting tetradentate NHC-phosphine ligand: On route to unconventional phosphonium ylide derivatives
Willot J., Taakili R., Ameskal M., Duhayon C., Lugan N., Canac Y., Valyaev D. A.
European Journal of Inorganic Chemistry 2024, e202400489/1-6.
https://doi.org/10.1002/ejic.202400489
https://hal.science/hal-04769823

Photoluminescent ruthenium(ii) bipyridyl complexes containing phosphonium ylide ligands
Fayafrou O., Lognon E., Duhayon C., Sortais J.-B., Monari A., Baslé O., Canac Y.
Chemical Communications 2024, 60(92), 13602-13605.
http://dx.doi.org/10.1039/D4CC05050A
https://hal.science/hal-04765484

Substituents’ effect on the photophysics of trinuclear copper(I) and silver(I) pyrazolate–phosphine cages
Baranova K. F., Titov A. A., Shakirova J. R., Baigildin V. A., Smol’yakov A. F., Valyaev D. A., Ning G. H., Filippov O. A., Tunik S. P., Shubina E. S.
Inorganic Chemistry 2024, 63(36), 16610-16621.
https://doi.org/10.1021/acs.inorgchem.4c00751
https://hal.science/hal-04696643

Counterion effects in [Ru(bpy)₃](X)₂-photocatalyzed energy transfer reactions
Zanzi J., Pastorel Z., Duhayon C., Lognon E., Coudret C., Monari A., Dixon I. M., Canac Y., Smietana M., Baslé O.
JACS Au 2024, 4(8), 3049-3057.
https://doi.org/10.1021/jacsau.4c00384
https://hal.science/hal-04687774

Transition-metal-catalysed transfer hydrogenation reactions with glycerol and carbohydrates as hydrogen donors
Ansari M. F., Anshika, Sortais J.-B., Elangovan S.
European Journal of Organic Chemistry 2024, 27(12), e202301278/1-30.
https://doi.org/10.1002/ejoc.202301278
https://hal.science/hal-04669393

3d-Metal Catalyzed C–C Bond Formation Through α-Alkylation of Ketones
Pointis R., Fayafrou O., Canac Y., Bastin S., Sortais J.-B.
in Topics in Organometallic Chemistry n°73: Dehydrogenation Reactions with 3d Metals, B. Sundararaju (Ed.), Springer Nature Switzerland: Cham, 2024, pp. 33-62. (978-3-031-48952-5).
https://doi.org/10.1007/3418_2023_110
https://hal.science/hal-04669452

Impact of the methylene bridge substitution in chelating NHC-phosphine Mn(I) catalyst for ketone hydrogenation
Gulyaeva E. S., Buhaibeh R., Boundor M., Azouzi K., Willot J., Bastin S., Duhayon C., Lugan N., Filippov O. A., Sortais J.-B., Valyaev D. A., Canac Y.
Chemistry – A European Journal 2024, 30(22), e202304201/1-11.
https://doi.org/10.1002/chem.202304201
https://hal.science/hal-04522874

Manganese-mediated synthesis of NHC-phosphine ligand precursors
Willot J., Fatima S., Duhayon C., Lugan N., Canac Y., Valyaev D. A.
Helvetica Chimica Acta 2024, 107(4), e202400009/1-11.
https://doi.org/10.1002/hlca.202400009
https://hal.science/hal-04522796

A photocatalytic approach for the synthesis of L-shape bicyclic NHC ligands
Kittikool T., Phakdeeyothin K., Morales A., Barthes C., Vendier L., Yotphan S., Bontemps S., Bastin S., Lledós A., Baslé O., César V.
ChemistryEurope 2024, 2 (2), e202300083.
https://doi.org/10.1002/ceur.202300083
https://hal.science/hal-04522291

Single electron reduction of NHC–CO₂–borane compounds
Morales A., Gonçalves C., Sournia-Saquet A., Vendier L., Lledós A., Baslé O., Bontemps S.
Chemical Science 2024, 15 (9), 3165-3173.
http://dx.doi.org/10.1039/D3SC06325A
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Hydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands
Azouzi K., Pointis R., Buhaibeh R., Fernández P. H., Pedussaut L., Boundor M., Bonfiglio A., Bruneau-Voisine A., Wei D., Roisnel T., Duhayon C., Casado M. Á., Valyaev D. A., Canac Y., Bastin S., Raynaud C., Sortais J.-B.
Journal of Catalysis 2024, 430, 115334/1-10.
https://doi.org/10.1016/j.jcat.2024.115334
https://hal.science/hal-04432103

NHC ligands in organometallic chemistry and catalysis
Poyatos M., César V.
European Journal of Inorganic Chemistry 2024, 27 (5), e202300729/1-2.
https://doi.org/10.1002/ejic.202300729
https://hal.science/hal-04501642

Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
Gulyaeva E. S., Osipova E. S., Kovalenko S. A., Filippov O. A., Belkova N. V., Vendier L., Canac Y., Shubina E. S., Valyaev D. A.
Chemical Science 2024, 15 (4), 1409-1417.
http://dx.doi.org/10.1039/D3SC05356C
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Phosphine-NHC-phosphonium ylide pincer Ligand: Complexation with Pd(II) and unconventional P-coordination of the ylide moiety
Ameskal M., Taakili R., Gulyaeva E. S., Duhayon C., Willot J., Lugan N., Lepetit C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2023, 62(49), 20129-20141.
https://doi.org/10.1021/acs.inorgchem.3c03025
https://hal.science/hal-04284085

EurJOC fête ses 25 ans : l’occasion de découvrir le métier d’éditeur
Crassous J., Baslé O., Schulz E.
Actualité Chimique 2023, 486, 5-8.
https://new.societechimiquedefrance.fr/numero/eurjoc-fete-ses-25-ans-loccasion-de-decouvrir-le-metier-dediteur-p5-n486/
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Cross-metathesis of technical grade methyl oleate for the synthesis of bio-based polyesters and polyamides
Krzesiński P., César V., Grela K., Santos S., Ortiz P.
RSC Sustainability 2023, 1(8), 2033-2037.
http://dx.doi.org/10.1039/D3SU00305A
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Hydrogenation of carboxylic esters catalyzed by phosphine-free bis-N-heterocyclic carbene manganese complexes
Azouzi K., Pedussaut L., Pointis R., Bonfiglio A., Kumari Riddhi R., Duhayon C., Bastin S., Sortais J.-B.
Organometallics 2023, 42(14), 1832-1838.
https://doi.org/10.1021/acs.organomet.3c00137
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Carbon-phosphorus ligands with extreme donating character
Canac Y.
Chemical Record 2023, 23(11), e202300187/1-19.
https://doi.org/10.1002/tcr.202300187
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Fused polycyclic NHC ligands in gold catalysis: Recent advances
Teixeira P., Bastin S., César V.
Israel Journal of Chemistry 2023, 63(9), e202200051/1-12.
https://doi.org/10.1002/ijch.202200051
https://hal.archives-ouvertes.fr/hal-03826206

An experimental and computational investigation rules out direct nucleophilic addition on the N2 ligand in manganese dinitrogen complex [Cp(CO)₂Mn(N₂)]
Le Dé Q., Bouammali A., Bijani C., Vendier L., Del Rosal I., Valyaev D. A., Dinoi C., Simonneau A.
Angewandte Chemie, International Edition 2023, 62(40), e202305235/1-10.
https://doi.org/10.1002/anie.202305235
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Towards (C,C)-cyclometalated N-(9-alkylfluorenyl)NHC ruthenium complexes for Z-selective olefin metathesis
Gajda K., Sytniczuk A., Vendier L., Trzaskowski B., Lugan N., Kajetanowicz A., Bastin S., Grela K., César V.
European Journal of Inorganic Chemistry 2023, 26(20), e202300169/1-15.
https://doi.org/10.1002/ejic.202300169
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Half-sandwich manganese complex bearing fused oxazoline-NHC ligand: Conformational analysis and evaluation in asymmetric ketone hydrosilylation
Cavailles M., Filippov O. A., César V., Lugan N., Valyaev D. A.
European Journal of Inorganic Chemistry 2023, 26(18), e202300143/1-6.
https://doi.org/10.1002/ejic.202300143
https://hal.science/hal-04142519

The dichotomy of Mn–H bond cleavage and kinetic hydricity of tricarbonyl manganese hydride complexes
Osipova E. S., Kovalenko S. A., Gulyaeva E. S., Kireev N. V., Pavlov A. A., Filippov O. A., Danshina A. A., Valyaev D. A., Canac Y., Shubina E. S., Belkova N. V.
Molecules 2023, 28(8), 3368/1-14.
https://doi.com/10.3390/molecules28083368
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Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C–H silylation
Manguin R., Galiana-Cameo M., Kittikool T., Barthes C., Thongpaen J., Bancal E., Mallet-Ladeira S., Yotphan S., Castarlenas R., Mauduit M., Sortais J.-B., Baslé O.
Chemical Communications 2023, 59(28), 4193-4196.
http://dx.doi.org/10.1039/D2CC06865F
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Phosphonium ylides vs iminophosphoranes: The role of the coordinating ylidic atom in cis-[phosphine-ylide Rh(CO)₂] complexes
Popovici I., Barthes C., Tannoux T., Duhayon C., Casaretto N., Monari A., Auffrant A., Canac Y.
Inorganic Chemistry 2023, 62(5), 2376-2388.
https://doi.org/10.1021/acs.inorgchem.2c04151
https://hal.science/hal-03962127

Characterisation by X-ray diffraction of bidentate and tridentate PCP and PCN NHC core pincer-type Mn(I) complexes
Duhayon C., Buhaibeh R., Valyaev D., Sortais J.-B., Canac Y.
Acta Crystallographica Section A 2022, 78(a2), e487.
https://doi.org/10.1107/S2053273322092610
https://hal.science/hal-04288540

Ruthenium–NHC complex-catalyzed P(iii)-directed C–H borylation of arylphosphines
Thongpaen J., Manguin R., Kittikool T., Camy A., Roisnel T., Dorcet V., Yotphan S., Canac Y., Mauduit M., Baslé O.
Chemical Communications 2022, 58, 12082-12085.
http://dx.doi.org/10.1039/D2CC03909E
https://hal.archives-ouvertes.fr/hal-03829956

Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-heterocyclic carbene bearing two N-cationic substituents
Padunnappattu A., Duhayon C., César V., Canac Y.
Organometallics 2022, 41(20), 2868–2878.
https://doi.org/10.1021/acs.organomet.2c00429
https://hal.archives-ouvertes.fr/hal-03818692

Chiral oxazolidines acting as transient hydroxyalkyl-functionalized N-heterocyclic carbenes: An efficient route to air stable copper and gold complexes for asymmetric catalysis
Pichon-Barré D., Zhang Z., Cador A., Vives T., Roisnel T., Baslé O., Jarrige L., Cavallo L., Falivene L., Mauduit M.
Chemical Science 2022, 13(30), 8773-8780.
http://dx.doi.org/10.1039/D2SC02908A
https://hal.archives-ouvertes.fr/hal-03772727

Highly emissive red heterobimetallic Ir^III/M^I (M^I = Cu^I and Au^I) complexes for efficient light-emitting electrochemical cells
Bonfiglio A., Hsiao P.-W., Chen Y., Gourlaouen C., Marchand Q., César V., Bellemin-Laponnaz S., Wang Y.-X., Lu C.-W., Daniel C., Polo F., Su H.-C., Mauro M.
Chemistry of Materials 2022, 34(4), 1756-1769.
https://doi.org/10.1021/acs.chemmater.1c03972
https://hal.archives-ouvertes.fr/hal-03789493

Redox-switchable behavior of transition-metal complexes supported by amino-decorated N-heterocyclic carbenes
Ruamps M., Bastin S., Rechignat L., Sournia-Saquet A., Vendier L., Lugan N., Mouesca J.-M., Valyaev D. A., Maurel V., César V.
Molecules 2022, 27(12), 3776/1-17.
https://doi.org/10.3390/molecules27123776
https://hal.archives-ouvertes.fr/hal-03709012

Helical chiral N-heterocyclic carbene ligands in enantioselective gold catalysis
Pallova L., Abella L., Jean M., Vanthuyne N., Barthes C., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2022, 28(17), e202200166/1-5.
https://doi.org/10.1002/chem.202200166
https://hal.archives-ouvertes.fr/hal-03575284

Fac-to-mer isomerization triggers hydride transfer from Mn(I) complex fac-[(dppm)Mn(CO)₃H]
Osipova E. S., Gulyaeva E. S., Kireev N. V., Kovalenko S. A., Bijani C., Canac Y., Valyaev D. A., Filippov O. A., Belkova N. V., Shubina E. S.
Chemical Communications 2022, 58(32), 5017-5020.
http://dx.doi.org/10.1039/D2CC00999D
https://hal.archives-ouvertes.fr/hal-03652224

Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Gulyaeva E. S., Osipova E. S., Buhaibeh R., Canac Y., Sortais J.-B., Valyaev D. A.
Coordination Chemistry Reviews 2022, 458, 214421/1-36.
https://doi.org/10.1016/j.ccr.2022.214421
https://hal.archives-ouvertes.fr/hal-03566299

Diverse C-coordination modes of NHC-tricyclohexylphosphonium ylide ligands in palladium(II) complexes
El Kadiri M., Chihab A., Taakili R., Duhayon C., Valyaev D. A., Canac Y.
Organometallics 2022, 41(4), 456-466.
https://doi.org/10.1021/acs.organomet.1c00700
https://hal.archives-ouvertes.fr/hal-03579686

Hydrosilylation reactions catalyzed by rhenium
Wei D., Buhaibeh R., Canac Y., Sortais J.-B.
Molecules 2021, 26(9), 2598/1-15.
https://doi.org/10.3390/molecules26092598
https://hal.archives-ouvertes.fr/hal-03230574

Carbenes and phosphonium ylides: A fruitful association in coordination chemistry
Valyaev D. A., Canac Y.
Dalton Transactions 2021, 50(45), 16434-16442
http://dx.doi.org/10.1039/D1DT03155D
https://hal.archives-ouvertes.fr/hal-03404061

Editorial overview: Smart use of metal reagents unlocks greener organic synthesis
Valyaev D. A.
Current Opinion in Green and Sustainable Chemistry 2021, 32, 100551/1-3.
https://doi.org/10.1016/j.cogsc.2021.100551
https://hal.archives-ouvertes.fr/hal-03361826

Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window
Tarrieu R., Delgado I. H., Zinna F., Dorcet V., Colombel-Rouen S., Crévisy C., Baslé O., Bosson J., Lacour J.
Chemical Communications 2021, 57(31), 3793-3796.
https://doi.org/10.1039/d1cc00898f
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Direct access to palladium(II) complexes based on anionic C,C,C-phosphonium ylide core pincer ligand
Taakili R., Barthes C., Lepetit C., Duhayon C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2021, 60(16), 12116-12128.
https://doi.org/10.1021/acs.inorgchem.1c01316
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Manganese-Catalyzed Hydrogenation and Hydrogen Transfer Reactions
Sortais J.-B., Buhaibeh R., Canac Y.
in Manganese Catalysis in Organic Synthesis, Sortais J.-B. (Ed.). Wiley-VCH: Weinheim, 2021, pp. 39-66. (978-3-527-34730-8).
https://doi.org/10.1002/9783527826131.ch2
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Manganese Catalysis in Organic Synthesis
Sortais J.-B. (Ed.)
Wiley‐VCH: Weinheim, 2021. (978-3-527-34730-8).
https://doi.org/10.1002/9783527826131
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Synthesis and properties of partially saturated fluorenyl-derived [n]helicenes featuring an overcrowded alkene
Pallova L., Gauthier E., Abella L., Jean M., Vanthuyne N., Dorcet V., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2021, 27(28), 7722-7730.
https://doi.org/10.1002/chem.202100150
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Organometallic Manganese Compounds in Organic Synthesis
Grineva A. A., Lugan N., Valyaev D. A.
in Manganese Catalysis in Organic Synthesis, Sortais J.-B. (Ed.). Wiley-VCH: Weinheim, 2021, pp. 1-37. (978-3-527-34730-8).
https://doi.org/10.1002/9783527826131.ch1
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Experimental and theoretical insights into the electronic properties of anionic n-heterocyclic dicarbenes through the rational synthesis of their transition metal complexes
Grineva A. A., Filippov O. A., Canac Y., Sortais J.-B., Nefedov S. E., Lugan N., César V., Valyaev D. A.
Inorganic Chemistry 2021, 60(6), 4015-4025.
https://doi.org/10.1021/acs.inorgchem.1c00073
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Chiral N-Heterocyclic Carbene-Based Ligands
César V., Fliedel C., Labande A.
in New Directions in Organic & Biological Chemistry Series. Chiral Ligands : Evolution of Ligand Libraries for Asymmetric Catalysis, Diéguez M. (Ed.). CRC Press: Boca Raton, 2021, pp. 195-232. (978-0-367-4-28488).
https://doi.org/10.1201/9780367855734-6
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Carbon ligands: From fundamental aspects to applications
Canac Y.
Molecules 2021, 26(8), 2132/1-3.
https://doi.org/10.3390/molecules26082132
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Cationic PCP and PCN NHC core pincer-type Mn(I) complexes: From synthesis to catalysis
Buhaibeh R., Duhayon C., Valyaev D. A., Sortais J.-B., Canac Y.
Organometallics 2021, 40(2), 231-241.
https://doi.org/10.1021/acs.organomet.0c00717
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Half-sandwich manganese complexes Cp(CO)₂Mn(NHC) as redox-active organometallic fragments
Brousses R., Maurel V., Mouesca J.-M., César V., Lugan N., Valyaev D. A.
Dalton Transactions 2021, 50(40), 14264-14272.
http://dx.doi.org/10.1039/D1DT02182F
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An anionic, chelating C(sp³)/NHC ligand from the combination of an N-heterobicyclic carbene and barbituric heterocycle
Benaissa I., Gajda K., Vendier L., Lugan N., Kajetanowicz A., Grela K., Michelet V., César V., Bastin S.
Organometallics 2021, 40(18), 3223-3234.
https://doi.org/10.1021/acs.organomet.1c00458
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Visible-light-induced ruthenium-catalyzed alkylation of activated C(sp³)−H bonds
Baslé O.
Chem Catalysis 2021, 1(2), 256-257.
https://doi.org/10.1016/j.checat.2021.05.015
https://hal.archives-ouvertes.fr/hal-03421540

Visible-light-induced 3d transition metal-catalysis: A focus on C–H bond functionalization
Baslé O.
Current Opinion in Green and Sustainable Chemistry 2021, 32, 100539/1-6.
https://doi.org/10.1016/j.cogsc.2021.100539
https://hal.archives-ouvertes.fr/hal-03421356

Manganese—New prominent actor in transfer hydrogenation catalysis
Azouzi K., Valyaev D. A., Bastin S., Sortais J.-B.
Current Opinion in Green and Sustainable Chemistry 2021, 31, 100511/1-7.
https://doi.org/10.1016/j.cogsc.2021.100511
https://hal.archives-ouvertes.fr/hal-03230650