LCC
Overview
The X- ray diffraction laboratory offers single crystal structure and powder diffraction analyses and an advice on general problems dealing with crystallography. Four X-ray automatic diffractometers are available: three single crystal diffratometers with low temperature devices (Agilent Gemini, Bruker Nonius and Bruker Kappa Apex II), and one powder diffractometer (Panalytical MPD Pro). For single crystal analyses, the X-ray diffraction staffs take care of the manipulation of air.
Four X-ray automatic diffractometers are available: three single crystal diffratometers with low temperature devices (Agilent Gemini, Bruker Nonius and Bruker Kappa Apex II), and one powder diffractometer (Panalytical MPD Pro).
For single crystal analyses, the X-ray diffraction staffs take care of the manipulation of air sensitive crystals, recording of diffracted intensities, data reduction, solution and refinement of the structures, graphical representation and edition of the crystallographic part of the manuscripts.
The powder diffractometer is a multi-purpose X-ray diffraction system, allowing standard reflection measurements, at variable temperature (- 90 to + 450 °C), on non air-sensitive samples (with an average volume of 100 mm3), and room temperature transmission measurements on air-sensitive samples in capillary tubes. The powder diffraction analyses lead to phase identification, cell search and refinement, Rietveld structure refinement, variable temperature studies and quantitative analysis.
Service members
VENDIER Laure
DUHAYON Carine
MALLET-LADEIRA Sonia
No Results Found
Facilities
Powder diffractometers
Three powder diffractometers are part of the structural analysis service using X-ray diffraction (a Panalytical MPDPro, a Miniflex600 from Rigaku and a SmartLab 3kW Multipurpose by Rigaku).
SmartLab 3kW Multipurpose Powder Diffractometer by Rigaku
Theta/theta diffractometer equipped with a fast linear detector D/Tex Ultra250: OD and 1D detector “High Energy” version.
Multi-configurations:
- capillary transmission,
- reflection with a 6-position sample changer,
- variable temperature chamber coupled with a DSC (from ambient to +350°C),
- research on thin layers by shaving
Tabletop powder diffractometer, Rigaku's Miniflex600
Theta /2 theta geometry is included on this benchtop powder diffractometer, which was installed in October 2020.
It has a Cu anode, a rapid 1D detector with energy selection, a 6-position sample changer, and a dome-type sample holder for air-sensitive powders.
Panalytical MPDPro Powder Diffractometer
Multi-configuration theta/theta diffractometer (transmission, reflection, variable temperature) with a fast linear detector.
Single crystal diffractometers
The X-ray diffraction structural analysis service includes three single crystal diffractometers equipped with low temperature liquid nitrogen and helium devices (a Gemini, a Synergy from Rigaku Oxford Diffraction, and a Kappa Apex II from Bruker AXS).
Single Crystal Diffractometer XtaLAB Synergy-S by Rigaku
This diffractometer, which was installed in the lab in September 2021, consists of two micro-focus X-ray sources (Mo and Cu radiation), a Hypix6000 hybrid pixel Si detector, and an Oxford Cryosystems 800 liquid nitrogen cryogenic system that allows the crystal temperature to be varied from 90 K to 400 K.
It combines the advantages of micro-sources (high diffracted intensity) with the outstanding signal/noise ratio of a pixel matrix detector with semi-conductors, allowing direct photon detection and counting by X-rays.
The choice of anode enables for adaptation to the materials under investigation.
Gemini diffractometer by Rigaku
Four-circle diffractometer (Kappa geometry) with two-dimensional CCD (EOS) type detector, Cu and Mo double anode. Low-temperature liquid nitrogen equipment: Cryojet (Oxford Instruments) capable of reaching 90 K. Low-temperature helium equipment: Helijet (Oxford Instruments) allowing to go down to 15K.
Bruker Kappa APEX II Diffractometer
Four-circle diffractometer (Kappa geometry) with two-dimensional CCD-type detector (APEX II).
Low-temperature liquid nitrogen equipment: Cryostream (Oxford Cryosystems) to reach 90 K.
Services
Reach us:
Carine Duhayon: carine.duhayon@lcc-toulouse.fr
Sonia Mallet-Ladeira: ladeira@chimie.ups-tlse.fr
Laure Vendier: laure.vendier@lcc-toulouse.fr
Phone: +33 5 61 33 31 18
Fax: +33 5 61 55 30 03
Publications
2024
2023
An orbitally adapted push-pull template for N2 activation and reduction to diazene-diide
Specklin D., Boegli M.-C., Coffinet A., Escomel L., Vendier L., Grellier M., Simonneau A.
Chemical Science 2023, 14(48), 14262-14270.
http://dx.doi.org/10.1039/D3SC04390H
https://hal.science/hal-04299114
Two different compounds in one crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)
Sasaki I., Mallet-Ladeira S.
Journal of Chemical Crystallography 2023, 53, 293–298.
https://doi.org/10.1007/s10870-022-00970-0
https://hal.archives-ouvertes.fr/hal-03846487
Protonation behavior of a tetrahydrido molybdenum(IV) complex with organic and inorganic acids
Queyriaux N., Durvin N., Leon D., Boegli M.-C., Vendier L., Simonneau A.
European Journal of Inorganic Chemistry 2023, 26(33), e202300426/1-7.
https://doi.org/10.1002/ejic.202300426
https://hal.science/hal-04209769
Phosphonium ylides vs iminophosphoranes: The role of the coordinating ylidic atom in cis-[phosphine-ylide Rh(CO)2] complexes
Popovici I., Barthes C., Tannoux T., Duhayon C., Casaretto N., Monari A., Auffrant A., Canac Y.
Inorganic Chemistry 2023, 62(5), 2376-2388.
https://doi.org/10.1021/acs.inorgchem.2c04151
https://hal.science/hal-03962127
Elastic properties of the iron(II)–triazole spin crossover complexes [Fe(Htrz)2trz]BF4 and [Fe(NH2trz)3]SO4
Paliwoda D., Vendier L., Getzner L., Alabarse F., Comboni D., Martin B., Alavi S. E., Piedrahita Bello M., Salmon L., Nicolazzi W., Molnár G., Bousseksou A.
Crystal Growth & Design 2023, 23(3), 1903-1914.
https://doi.org/10.1021/acs.cgd.2c01396
https://hal.science/hal-04008004
Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C–H silylation
Manguin R., Galiana-Cameo M., Kittikool T., Barthes C., Thongpaen J., Bancal E., Mallet-Ladeira S., Yotphan S., Castarlenas R., Mauduit M., Sortais J.-B., Baslé O.
Chemical Communications 2023, 59(28), 4193-4196.
http://dx.doi.org/10.1039/D2CC06865F
https://hal.science/hal-04061785
Syntheses of N2-bridged heterobimetallic complexes, their structural and qualitative bonding analyses
Le Dé Q., Orbay F., Vendier L., Simonneau A.
Journal of Organometallic Chemistry 2023, 986, 122604/1-7.
https://doi.org/10.1016/j.jorganchem.2022.122604
https://hal.science/hal-03955433
An experimental and computational investigation rules out direct nucleophilic addition on the N2 ligand in manganese dinitrogen complex [Cp(CO)2Mn(N2)]
Le Dé Q., Bouammali A., Bijani C., Vendier L., Del Rosal I., Valyaev D. A., Dinoi C., Simonneau A.
Angewandte Chemie, International Edition 2023, 62(40), e202305235/1-10.
https://doi.org/10.1002/anie.202305235
https://hal.science/hal-04159061
A Trojan horse approach for enhancing the cellular uptake of a ruthenium nitrosyl complex
Labra-Vázquez P., Rocha E., Xiao Y., Tassé M., Duhayon C., Farfán N., Santillan R., Gibot L., Lacroix P. G., Malfant I.
Dalton Transactions 2023, 52(48), 18177-18193.
http://dx.doi.org/10.1039/D3DT03480A
https://hal.science/hal-04346306
Acetylacetonate ruthenium nitrosyls: A gateway to nitric oxide release in water under near-infrared excitation by two-photon absorption
Labra-Vázquez P., Mudrak V., Tassé M., Mallet-Ladeira S., Sournia-Saquet A., Malval J.-P., Lacroix P. G., Malfant I.
Inorganic Chemistry 2023, 62(49), 20349-20363.
https://doi.org/10.1021/acs.inorgchem.3c03355
https://hal.science/hal-04284209
Mechanochemical studies on coupling of hydrazines and hydrazine amides with phenolic and furanyl aldehydes-hydrazones with antileishmanial and antibacterial activities
Kapusterynska A., Bijani C., Paliwoda D., Vendier L., Bourdon V., Imbert N., Cojean S., Loiseau P. M., Recchia D., Scoffone V. C., Degiacomi G., Akhir A., Saxena D., Chopra S., Lubenets V., Baltas M.
Molecules 2023, 28(13), 5284/1-26.
https://doi.org/10.3390/molecules28135284
https://hal.science/hal-04157067
Homochiral SCM built of tetrahedral and pentagonal bipyramidal Fe(II) units bridged by chlorine
Jubault V., Pradines B., Pichon C., Suaud N., Duhayon C., Guihéry N., Sutter J.-P.
Crystal Growth & Design 2023, 23(2), 1229-1237.
https://doi.org/10.1021/acs.cgd.2c01360
https://hal.science/hal-03981782
Pentagonal bipyramidal 3 d-metal complexes derived from a dimethylcarbamoyl-substituted pentadentate-[N3O2] ligand: Aiming for increased solubility
Jubault V., Genevois F., Pradines B., Cahier B., Jbeli W., Suaud N., Guihéry N., Duhayon C., Pichon C., Sutter J.-P.
ChemistrySelect 2023, 8(4), e202204935/1-10.
https://doi.org/10.1002/slct.202204935
https://hal.science/hal-03955461
Crystal structures and conformational effects in bis-fluorenyl based ligands and related ruthenium nitrosyl complexes
Juarez-Martinez Y., Labra-Vázquez P., Lacroix P. G., Tassé M., Bocé M., Mallet-Ladeira S., Malfant I.
Polyhedron 2023, 246, 116690/1-10.
https://doi.org/10.1016/j.poly.2023.116690
https://hal.science/hal-04283893
Towards (C,C)-cyclometalated N-(9-alkylfluorenyl)NHC ruthenium complexes for Z-selective olefin metathesis
Gajda K., Sytniczuk A., Vendier L., Trzaskowski B., Lugan N., Kajetanowicz A., Bastin S., Grela K., César V.
European Journal of Inorganic Chemistry 2023, 26(20), e202300169/1-15.
https://doi.org/10.1002/ejic.202300169
https://hal.science/hal-04155197
CO2 hydroboration: Impact of the boryl moieties on the reactivity of four bis(boryl)acetal compounds toward 2,6-diisopropylaniline
Desmons S., Zhou Y., Zhang D., Jarava-Barrera C., Coffinet A., Simonneau A., Vendier L., Luo G., Bontemps S.
European Journal of Organic Chemistry 2023, 26(30), e202300525/1-8.
https://doi.org/10.1002/ejoc.202300525
https://hal.science/hal-04169288
Structural determinations of homo and heterodi- or tetra-nuclear lanthanide complexes and their characterization by μ-Squid experiments
Costes J.-P., Duhayon C., Vendier L., Wernsdorfer W.
Polyhedron 2023, 246, 116699/1-8.
https://doi.org/10.1016/j.poly.2023.116699
https://hal.science/hal-04304533
Assessing combinations of B(C6F5)3 and N2-derived molybdenum nitrido complexes for heterolytic bond activation
Coffinet A., Specklin D., Le Dé Q., Bennaamane S., Muñoz L., Vendier L., Clot E., Mézailles N., Simonneau A.
Chemistry – A European Journal 2023, 29(26), e202203774/1-8.
https://doi.org/10.1002/chem.202203774
https://hal.science/hal-04007916
Mapping out the role of σ-silane complexes in the ruthenium-catalyzed hydrosilylation of nitriles
Chandran A., Ravel-Massol R., Vendier L., Slattery J. M., Lynam J. M., Grellier M.
Organometallics 2023, 42(21), 3153-3163.
https://doi.org/10.1021/acs.organomet.3c00397
https://hal.science/hal-04321916
Synthesis and coordination of a bisphosphine-[NHC-borane] compound: A ligand framework for bimetallic structure featuring a boron-bridging moiety
Camy A., Vendier L., Bijani C., Fernández I., Bontemps S.
Inorganic Chemistry 2023, 62(23), 9035-9043.
https://doi.org/10.1021/acs.inorgchem.3c00785
https://hal.science/hal-04169429
Hydrogenation of carboxylic esters catalyzed by phosphine-free bis-N-heterocyclic carbene manganese complexes
Azouzi K., Pedussaut L., Pointis R., Bonfiglio A., Kumari Riddhi R., Duhayon C., Bastin S., Sortais J.-B.
Organometallics 2023, 42(14), 1832-1838.
https://doi.org/10.1021/acs.organomet.3c00137
https://hal.science/hal-04174553
Combined B–H and Si–H bond activations at ruthenium
Ayyappan R., Saha K., Kaur U., Gayen S., Vendier L., Sabo-Etienne S., Ghosh S., Bontemps S.
Organometallics 2023, 42(9), 752-756.
https://doi.org/10.1021/acs.organomet.3c00109
https://hal.science/hal-04169506
Phosphine-NHC-phosphonium ylide pincer Ligand: Complexation with Pd(II) and unconventional P-coordination of the ylide moiety
Ameskal M., Taakili R., Gulyaeva E. S., Duhayon C., Willot J., Lugan N., Lepetit C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2023, 62(49), 20129-20141.
https://doi.org/10.1021/acs.inorgchem.3c03025
https://hal.science/hal-04284085
2022
Cu-Ln complexes involving non-symmetrical ligands able to introduce asymmetric centres in the vicinity of Ln ions
Zohra Chiboub Fellah F., Duhayon C., Mallet-Ladeira S., Vendier L., Costes J.-P.
Polyhedron 2022, 224, 116015/1-9.
https://doi.org/10.1016/j.poly.2022.116015
https://hal.archives-ouvertes.fr/hal-03813018
Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
Sutter J.-P., Béreau V., Jubault V., Bretosh K., Pichon C., Duhayon C.
Chemical Society Reviews 2022, 51(8), 3280-3313.
http://dx.doi.org/10.1039/D2CS00028H
https://hal.archives-ouvertes.fr/hal-03673750
Redox-switchable behavior of transition-metal complexes supported by amino-decorated N-heterocyclic carbenes
Ruamps M., Bastin S., Rechignat L., Sournia-Saquet A., Vendier L., Lugan N., Mouesca J.-M., Valyaev D. A., Maurel V., César V.
Molecules 2022, 27(12), 3776/1-17.
https://doi.org/10.3390/molecules27123776
https://hal.archives-ouvertes.fr/hal-03709012
Modulation of the sorption characteristics for an H-bonded porous architecture by varying the chemical functionalization of the channel walls
Roques N., Tovar-Molle A., Duhayon C., Brandès S., Spieß A., Janiak C., Sutter J.-P.
Chemistry – A European Journal 2022, 28(61), e202201935/1-10.
https://doi.org/10.1002/chem.202201935
https://hal.archives-ouvertes.fr/hal-03767128
Shvo-type metal–ligand cooperative catalysts: Tethered η5-oxocyclohexadienyl ruthenium complexes
Puig E., Verron R., Kechaou-Perrot M., Vendier L., Gornitzka H., Miqueu K., Sotiropoulos J.-M., Fischmeister C., Sutra P., Igau A.
Organometallics 2022, 41(11), 1391-1402.
https://doi.org/10.1021/acs.organomet.2c00123
https://hal.archives-ouvertes.fr/hal-03715383
Helical chiral N-heterocyclic carbene ligands in enantioselective gold catalysis
Pallova L., Abella L., Jean M., Vanthuyne N., Barthes C., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2022, 28(17), e202200166/1-5.
https://doi.org/10.1002/chem.202200166
https://hal.archives-ouvertes.fr/hal-03575284
Pressure tuning of coupled structural and spin state transitions in the molecular complex [Fe(H2B(pz)2)2(phen)]
Paliwoda D., Vendier L., Nicolazzi W., Molnár G., Bousseksou A.
Inorganic Chemistry 2022, 61(40), 15991-16002.
https://doi.org/10.1021/acs.inorgchem.2c02286
https://hal.archives-ouvertes.fr/hal-03790163
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-heterocyclic carbene bearing two N-cationic substituents
Padunnappattu A., Duhayon C., César V., Canac Y.
Organometallics 2022, 41(20), 2868-2878.
https://doi.org/10.1021/acs.organomet.2c00429
https://hal.archives-ouvertes.fr/hal-03818692
A masked form of an O-borylated Breslow intermediate for the diastereoselective FLP-type activation of aldehydes
Mejia Fajardo A., Queyriaux N., Camy A., Vendier L., Grellier M., Del Rosal I., Maron L., Bontemps S.
Chemistry – A European Journal 2022, 28(10), e202104122/1-5.
https://doi.org/10.1002/chem.202104122
https://hal.archives-ouvertes.fr/hal-03669849
X-Ray diffraction structure of Cu(II) and Zn(II) complexes of 8-aminoquinoline derivatives (TDMQ), related to the activity of these chelators as potential drugs against Alzheimer’s disease
Li Y., Nguyen M., Vendier L., Robert A., Liu Y., Meunier B.
Journal of Molecular Structure 2022, 1251, 132078/1-6.
https://doi.org/10.1016/j.molstruc.2021.132078
https://hal.archives-ouvertes.fr/hal-03509314
Design of anti-infectious agents from lawsone in a three-component reaction with aldehydes and isocyanides
Koumpoura C. L., Nguyen M., Bijani C., Vendier L., Salina E. G., Buroni S., Degiacomi G., Cojean S., Loiseau P. M., Benoit-Vical F., García-Sosa A. T., Robert A., Baltas M.
ACS Omega 2022, 7(40), 35635-35655.
https://doi.org/10.1021/acsomega.2c03421
https://hal.archives-ouvertes.fr/hal-03818601
Bimetallic ruthenium nitrosyl complexes with enhanced two-photon absorption properties for nitric oxide delivery
Juarez-Martinez Y., Labra-Vázquez P., Enríquez-Cabrera A., Leon-Rojas A. F., Martínez-Bourget D., Lacroix P. G., Tassé M., Mallet-Ladeira S., Farfán N., Santillan R., Ramos-Ortiz G., Malval J.-P., Malfant I.
Chemistry – A European Journal 2022, 28(62), e202201692/1-14.
https://doi.org/10.1002/chem.202201692
https://hal.archives-ouvertes.fr/hal-03796799
Diverse C-coordination modes of NHC-tricyclohexylphosphonium ylide ligands in palladium(II) complexes
El Kadiri M., Chihab A., Taakili R., Duhayon C., Valyaev D. A., Canac Y.
Organometallics 2022, 41(4), 456-466.
https://doi.org/10.1021/acs.organomet.1c00700
https://hal.archives-ouvertes.fr/hal-03579686
Characterisation by X-ray diffraction of bidentate and tridentate PCP and PCN NHC core pincer-type Mn(I) complexes
Duhayon C., Buhaibeh R., Valyaev D., Sortais J.-B., Canac Y.
Acta Crystallographica Section A 2022, 78(a2), e487.
https://doi.org/10.1107/S2053273322092610
https://hal.science/hal-04288540
Structural determinations and magnetic properties of a “chiral at metal” complex and its resulting [Cu–Ln]2 compounds
Costes J.-P., Duhayon C., Vendier L., Wernsdorfer W.
Dalton Transactions 2022, 51(7), 2805-2814.
http://dx.doi.org/10.1039/D1DT04249A
https://hal.archives-ouvertes.fr/hal-03592049
Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation
Bouammali A., Coffinet A., Vendier L., Simonneau A.
Dalton Transactions 2022, 51(28), 10697-10701.
http://dx.doi.org/10.1039/D1DT03905A
https://hal.archives-ouvertes.fr/hal-03474760
2021
Carbo-mer of barrelene: a rigid 3D-carbon-expanded molecular barrel
Zhu C., Poater A., Duhayon C., Kauffmann B., Saquet A., Rives A., Maraval V., Chauvin R.
Chemistry – A European Journal 2021, 27(36), 9286-9291.
https://doi.org/10.1002/chem.202100670
https://hal.archives-ouvertes.fr/hal-03228886v1
Quasilinear 3d-metal(i) complexes [KM(N(Dipp)SiR3)2] (M = Cr–Co) – structural diversity, solution state behaviour and reactivity
Weller R., Müller I., Duhayon C., Sabo-Etienne S., Bontemps S., Werncke C. G.
Dalton Transactions 2021, 50(14), 4890-4903.
http://dx.doi.org/10.1039/D1DT00121C
https://hal.archives-ouvertes.fr/hal-03219725
Dendrimers functionalized with palladium complexes of N-, N,N-, and N,N,N-ligands
Vanbellingen Q., Servin P., Coinaud A., Mallet-Ladeira S., Laurent R., Caminade A.-M.
Molecules 2021, 26(8), 2333/1-19.
https://doi.org/10.3390/molecules26082333
https://hal.archives-ouvertes.fr/hal-03275902
Direct access to palladium(II) complexes based on anionic C,C,C-phosphonium ylide core pincer ligand
Taakili R., Barthes C., Lepetit C., Duhayon C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2021, 60(16), 12116-12128.
https://doi.org/10.1021/acs.inorgchem.1c01316
https://hal.archives-ouvertes.fr/hal-03357270
Synthesis, characterization, and comparative theoretical investigation of dinitrogen-bridged group 6-gold heterobimetallic complexes
Specklin D., Coffinet A., Vendier L., Del Rosal I., Dinoi C., Simonneau A.
Inorganic Chemistry 2021, 60(8), 5545–5562.
https://doi.org/10.1021/acs.inorgchem.0c03271
https://hal.archives-ouvertes.fr/hal-03176320
Electrochemical, spectroscopic, and computational investigation of a series of polypyridyl ruthenium(II) complexes: Characterization of reduced states
Queyriaux N., Esmieu C., Gupta A. K., Vendier L., Ott S., Orio M., Hammarström L.
European Journal of Inorganic Chemistry 2021, 2021(13), 1263-1270.
https://doi.org/10.1002/ejic.202001165
https://hal.archives-ouvertes.fr/hal-03202765
Trinuclear cyanido-bridged [Cr2Fe] complexes: To be or not to be a single-molecule magnet, a matter of straightness
Pichon C., Suaud N., Jubault V., Duhayon C., Guihéry N., Sutter J.-P.
Chemistry – A European Journal 2021, 27(62), 15484-15495.
https://doi.org/10.1002/chem.202102571
https://hal.archives-ouvertes.fr/hal-03424346
Discrete versus 1D compounds based on pentagonal bipyramid coordination geometries: A matter of solubility?
Pichon C., Duhayon C., Delahaye E., Sutter J.-P.
European Journal of Inorganic Chemistry 2021, 2021(48), 5112-5118.
https://doi.org/10.1002/ejic.202100834
https://hal.archives-ouvertes.fr/hal-03510193
Vanadium-catalyzed terpolymerization of α,ω-dienes with ethylene and cyclic olefins: Ready access to polar-functionalized polyolefins
Palucci B., Zanchin G., Ricci G., Vendier L., Lorber C., Leone G.
Macromolecules 2021, 54(23), 10700-10711.
https://doi.org/10.1021/acs.macromol.1c02142
https://hal.archives-ouvertes.fr/hal-03518735
Synthesis and properties of partially saturated fluorenyl-derived [n]helicenes featuring an overcrowded alkene
Pallova L., Gauthier E., Abella L., Jean M., Vanthuyne N., Dorcet V., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2021, 27(28), 7722-7730.
https://doi.org/10.1002/chem.202100150
https://hal.archives-ouvertes.fr/hal-03194360
Crystal structure of 1,1′-(pyridine-2,6-diyl)bis[N-(pyridin-2-ylmethyl)methanaminium] dichloride dihydrate
Merabet L., Tassé M., Mallet-Ladeira S., Kaboub L., Malfant I.
Acta Crystallographica Section E 2021, 77(12), 1296-1298.
https://doi.org/10.1107/S205698902101183X
https://hal.archives-ouvertes.fr/hal-03600453
Cyclooctadiene Rh(I) bis- and tris(pyrazolyl)aluminate complexes and their catalytic activity on the polymerization of phenylacetylene
Garcia O. J., Vendier L., Etienne M., Gwaltney S., Ressler A., Muñoz-Hernández M.-Á.
Inorganic Chemistry 2021, 60(14), 10757-10763.
https://doi.org/10.1021/acs.inorgchem.1c01434
https://hal.archives-ouvertes.fr/hal-03292668
Enantioselective reductive oligomerization of carbon dioxide into L-erythrulose via a chemoenzymatic catalysis
Desmons S., Grayson-Steel K., Nuñez-Dallos N., Vendier L., Hurtado J., Clapés P., Fauré R., Dumon C., Bontemps S.
Journal of the American Chemical Society 2021, 143(39), 16274–16283.
https://doi.org/10.1021/jacs.1c07872
https://hal.archives-ouvertes.fr/hal-03358019
Further insights into the oxidative pathway of thiocarbonyl-type antitubercular prodrugs: Ethionamide, thioacetazone, and isoxyl
de Freitas Paulo T., Duhayon C., de França Lopes L. G., Silva Sousa E. H., Chauvin R., Bernardes-Génisson V.
Chemical Research in Toxicology 2021, 34(8), 1879-1889.
https://doi.org/10.1021/acs.chemrestox.1c00164
https://hal.archives-ouvertes.fr/hal-03669331
Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition
Coffinet A., Zhang D., Vendier L., Bontemps S., Simonneau A.
Dalton Transactions 2021, 50(16), 5582-5589.
https://dx.doi.org/10.1039/D1DT00317H
https://hal.archives-ouvertes.fr/hal-03176261
Oxidation-promoted synthesis of ferrocenyl planar chiral rhodium(III) complexes for C–H functionalization catalysis
Cabanes J., Odnoroh M., Duhayon C., Bijani C., Sournia-Saquet A., Polia R., Labande A.
Mendeleev Communications 2021, 31(5), 620-623.
https://doi.org/10.1016/j.mencom.2021.09.010
https://hal.archives-ouvertes.fr/hal-03412564
Cationic PCP and PCN NHC core pincer-type Mn(I) complexes: From synthesis to catalysis
Buhaibeh R., Duhayon C., Valyaev D. A., Sortais J.-B., Canac Y.
Organometallics 2021, 40(2), 231-241.
https://doi.org/10.1021/acs.organomet.0c00717
https://hal.archives-ouvertes.fr/hal-03128901
Solid-state and solution characterizations of [(TMPA)Cu(II)(SO3)] and [(TMPA)Cu(II)(S2O3)] complexes: Application to sulfite and thiosulfate fast detection
Berthonnaud L., Esmieu C., Mallet-Ladeira S., Hureau C.
Journal of Inorganic Biochemistry 2021, 225, 111601/1-9.
https://doi.org/10.1016/j.jinorgbio.2021.111601
https://hal.archives-ouvertes.fr/hal-03394471
An anionic, chelating C(sp3)/NHC ligand from the combination of an N-heterobicyclic carbene and barbituric heterocycle
Benaissa I., Gajda K., Vendier L., Lugan N., Kajetanowicz A., Grela K., Michelet V., César V., Bastin S.
Organometallics 2021, 40(18), 3223-3234.
https://doi.org/10.1021/acs.organomet.1c00458
https://hal.archives-ouvertes.fr/hal-03356487
Linear and nonlinear optical properties of a quadrupolar carbo-benzene and its benzenic parent: The carbo-merization effect
Barba-Barba R. M., Chammam M., Ramos-Ortiz G., Listunov D., Velusamy J., Rodriguez M., Carriles R., Silva C. G., Duhayon C., Kauffmann B., Maraval V., Chauvin R.
Dyes and Pigments 2021, 188, 109133/1-12.
https://doi.org/10.1016/j.dyepig.2021.109133
https://hal.archives-ouvertes.fr/hal-03202845v1
Impact of the alkali metal on the structural and dynamic properties of the anionic pentahydride ruthenium complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na, K)
Ayyappan R., Saha K., Grellier M., Clot E., Vendier L., Ghosh S., Sabo-Etienne S., Bontemps S.
Organometallics 2021, 40(17), 3024-3032.
https://doi.org/10.1021/acs.organomet.1c00384
https://hal.archives-ouvertes.fr/hal-03357901
Synthesis and reactivity of phosphine borohydride compounds
Ayyappan R., Coppel Y., Vendier L., Ghosh S., Sabo-Etienne S., Bontemps S.
Chemical Communications 2021, 57(3), 375-378.
http://dx.doi.org/10.1039/D0CC07072F
https://hal.archives-ouvertes.fr/hal-03149993
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