LCC
Overview
The X- ray diffraction laboratory offers single crystal structure and powder diffraction analyses and an advice on general problems dealing with crystallography. Four X-ray automatic diffractometers are available: three single crystal diffratometers with low temperature devices (Agilent Gemini, Bruker Nonius and Bruker Kappa Apex II), and one powder diffractometer (Panalytical MPD Pro). For single crystal analyses, the X-ray diffraction staffs take care of the manipulation of air.
Four X-ray automatic diffractometers are available: three single crystal diffratometers with low temperature devices (Agilent Gemini, Bruker Nonius and Bruker Kappa Apex II), and one powder diffractometer (Panalytical MPD Pro).
For single crystal analyses, the X-ray diffraction staffs take care of the manipulation of air sensitive crystals, recording of diffracted intensities, data reduction, solution and refinement of the structures, graphical representation and edition of the crystallographic part of the manuscripts.
The powder diffractometer is a multi-purpose X-ray diffraction system, allowing standard reflection measurements, at variable temperature (- 90 to + 450 °C), on non air-sensitive samples (with an average volume of 100 mm3), and room temperature transmission measurements on air-sensitive samples in capillary tubes. The powder diffraction analyses lead to phase identification, cell search and refinement, Rietveld structure refinement, variable temperature studies and quantitative analysis.
Service members
VENDIER Laure
DUHAYON Carine
MALLET-LADEIRA Sonia
No Results Found
Facilities
Powder diffractometers
Three powder diffractometers are part of the structural analysis service using X-ray diffraction (a Panalytical MPDPro, a Miniflex600 from Rigaku and a SmartLab 3kW Multipurpose by Rigaku).
SmartLab 3kW Multipurpose Powder Diffractometer by Rigaku
Theta/theta diffractometer equipped with a fast linear detector D/Tex Ultra250: OD and 1D detector “High Energy” version.
Multi-configurations:
- capillary transmission,
- reflection with a 6-position sample changer,
- variable temperature chamber coupled with a DSC (from ambient to +350°C),
- research on thin layers by shaving
Tabletop powder diffractometer, Rigaku's Miniflex600
Theta /2 theta geometry is included on this benchtop powder diffractometer, which was installed in October 2020.
It has a Cu anode, a rapid 1D detector with energy selection, a 6-position sample changer, and a dome-type sample holder for air-sensitive powders.
Panalytical MPDPro Powder Diffractometer
Multi-configuration theta/theta diffractometer (transmission, reflection, variable temperature) with a fast linear detector.
Single crystal diffractometers
The X-ray diffraction structural analysis service includes three single crystal diffractometers equipped with low temperature liquid nitrogen and helium devices (a Gemini, a Synergy from Rigaku Oxford Diffraction, and a Kappa Apex II from Bruker AXS).
Single Crystal Diffractometer XtaLAB Synergy-S by Rigaku
This diffractometer, which was installed in the lab in September 2021, consists of two micro-focus X-ray sources (Mo and Cu radiation), a Hypix6000 hybrid pixel Si detector, and an Oxford Cryosystems 800 liquid nitrogen cryogenic system that allows the crystal temperature to be varied from 90 K to 400 K.
It combines the advantages of micro-sources (high diffracted intensity) with the outstanding signal/noise ratio of a pixel matrix detector with semi-conductors, allowing direct photon detection and counting by X-rays.
The choice of anode enables for adaptation to the materials under investigation.
Gemini diffractometer by Rigaku
Four-circle diffractometer (Kappa geometry) with two-dimensional CCD (EOS) type detector, Cu and Mo double anode. Low-temperature liquid nitrogen equipment: Cryojet (Oxford Instruments) capable of reaching 90 K. Low-temperature helium equipment: Helijet (Oxford Instruments) allowing to go down to 15K.
Bruker Kappa APEX II Diffractometer
Four-circle diffractometer (Kappa geometry) with two-dimensional CCD-type detector (APEX II).
Low-temperature liquid nitrogen equipment: Cryostream (Oxford Cryosystems) to reach 90 K.
Services
Reach us:
Carine Duhayon: carine.duhayon@lcc-toulouse.fr
Sonia Mallet-Ladeira: ladeira@chimie.ups-tlse.fr
Laure Vendier: laure.vendier@lcc-toulouse.fr
Phone: +33 5 61 33 31 18
Fax: +33 5 61 55 30 03
Publications
2025
2024
Reactivity of metal hydrides with CO2: going beyond formate with a high-valent cationic pentahydride Mo(vi) complex
Queyriaux N., Cabrera-Trujillo J. J., Durvin N., Vendier L., Miqueu K., Simonneau A.
Chemical Science 2024,
http://dx.doi.org/10.1039/D4SC04345F
https://hal.science/hal-04826899
Colloidal bimetallic RuNi particles and their behaviour in catalytic quinoline hydrogenation
Cardona-Farreny M., Ishikawa H., Odufejo Ogoe A. O., Mallet-Ladeira S., Coppel Y., Lecante P., Esvan J., Philippot K., Axet M. R.
ChemPlusChem 2024, e202400516/1-10.
https://doi.org/10.1002/cplu.202400516
https://hal.science/hal-04703442
Electron-transfer-induced structural modification in a thermochromic Hofmann clathrate derivative
Getzner L., Remili Y., Ziani Z., Vendier L., Molnár G., Cobo S., Bousseksou A.
Inorganic Chemistry 2024,
https://doi.org/10.1021/acs.inorgchem.4c04155
https://hal.science/hal-04816007
Exploring the chemistry of ruthenium complexes with a bidentate barbiturate-imidazo[1,5-a]pyridinylidene ligand
Krzesiński P., Gajda K., Vendier L., Kajetanowicz A., Grela K., Bastin S., César V.
Zeitschrift fur Anorganische und Allgemeine Chemie 2024, e202400199.
https://doi.org/10.1002/zaac.202400199
https://hal.science/hal-04785126
Mechanistic investigations on Cp*CoIII-catalyzed quinoline transfer hydrogenation with formic acid
Garg N., Dahiya P., Mallet-Ladeira S., Poli R., Sundararaju B.
ACS Catalysis 2024, 14(23), 17556-17570.
https://doi.org/10.1021/acscatal.4c05271
https://hal.science/hal-04782211
Chiral 1D cyanide-bridged bimetallic compounds build with enantiomorphic pentagonal bipyrimidal M(II) units
Martinez D., Pichon C., Duhayon C., Béreau V., Yamaguchi H., Sutter J.-P.
European Journal of Inorganic Chemistry 2024, e202400449/1-8.
https://doi.org/10.1002/ejic.202400449
https://hal.science/hal-04771780
A Pd(II) complex exhibiting tetradentate NHC-phosphine ligand: On route to unconventional phosphonium ylide derivatives
Willot J., Taakili R., Ameskal M., Duhayon C., Lugan N., Canac Y., Valyaev D. A.
European Journal of Inorganic Chemistry 2024, e202400489/1-6.
https://doi.org/10.1002/ejic.202400489
https://hal.science/hal-04769823
Influence of triphosphine ligand coordination geometry in Mn(I) hydride complexes [(P∩P∩P)(CO)2MnH] on their kinetic hydricity
Kovalenko S. A., Gulyaeva E. S., Osipova E. S., Filippov O. A., Danshina A. A., Vendier L., Kireev N. V., Godovikov I. A., Canac Y., Valyaev D. A., Belkova N., Shubina E. S.
Dalton Transactions 2024,
http://dx.doi.org/10.1039/D4DT02496F
https://hal.science/hal-04769905
[Rh2(phesp)2]: a bulkier [Rh2(esp)2] analog to tune the site-selectivity in carbene C–H insertion reactions
Labande A., Ruzhylo I., Vorozhbian A., Vincendeau S., Saget T., Mallet-Ladeira S., Dauban P., Manoury E.
ChemCatChem 2024, e202400874/1-12.
https://doi.org/10.1002/cctc.202400874
https://hal.science/hal-04574738
Differences and similarities in two series of MIILnIIIMII complexes
Costes J.-P., Duhayon C., Vendier L., Novitchi G., Wernsdorfer W.
Crystal Growth & Design 2024, 24(22), 9617-9630.
https://doi.org/10.1021/acs.cgd.4c01135
https://hal.science/hal-04818199
Unprecedented linear products by a mechanochemically activated Biginelli reaction using lawsone
Koumpoura C. L., Vendier L., Bijani C., Robert A., Carbonnière P., Sotiropoulos J.-M., Baltas M.
RSC Mechanochemistry 2024, 1(2), 167-175.
http://dx.doi.org/10.1039/D3MR00032J
https://hal.science/hal-04550806
Reaction of a bulky β-diketiminato magnesium hydride with CO2 yielding a polynuclear magnesium cage compound
Huadsai W., Vendier L., Westerhausen M., Bontemps S.
Zeitschrift fur Anorganische und Allgemeine Chemie 2024, 650(17), e202400070/1-8.
https://doi.org/10.1002/zaac.202400070
https://hal.science/hal-04803959
Photoluminescence lifetime stability studies of β-diketonate europium complexes based phenanthroline derivatives in poly(methyl methacrylate) films
Essahili O., Ouafi M., Ilsouk M., Lakbita O., Duhayon C., Mahi L., Moudam O.
ChemistryOpen 2024, 13(5), e202300192/1-15.
https://doi.org/10.1002/open.202300192
https://hal.science/hal-04804690
Enhancement of photostability ageing of samarium complexes in PMMA films
Essahili O., Ilsouk M., Duhayon C., Almaggoussi A., Moudam O.
ChemistrySelect 2024, 9(13), e202303722/1-11.
https://doi.org/10.1002/slct.202303722
https://hal.science/hal-04820637
Borate ligand derived from CS2 unveiling ruthenium dithioformate and trithia-borinane complexes
Ahmad A., Gayen S., Mishra S., Afsan Z., Vendier L., Ghosh S.
Polyhedron 2024, 256, 116986/1-9.
https://doi.org/10.1016/j.poly.2024.116986
https://hal.science/hal-04804664
Photoluminescent ruthenium(ii) bipyridyl complexes containing phosphonium ylide ligands
Fayafrou O., Lognon E., Duhayon C., Sortais J.-B., Monari A., Baslé O., Canac Y.
Chemical Communications 2024, 60(92), 13602-13605
http://dx.doi.org/10.1039/D4CC05050A
https://hal.science/hal-04765484
Hofmann clathrates: A “blue box” approach to modulate spin-crossover properties
Getzner L., Vendier L., Molnár G., Rotaru A., Cobo S., Bousseksou A.
Angewandte Chemie, International Edition 2024, 63(46), e202412525/1-7.
https://doi.org/10.1002/anie.202412525
https://hal.science/hal-04761740
Low-valent group 6 metals/Al(C6F5)3 donor–acceptor systems for CO2 activation and cleavage
Escomel L., Le Dé Q., Benonie M., Vendier L., Simonneau A.
Chemical Communications 2024, 60(90), 13235-13238
http://dx.doi.org/10.1039/D4CC02349H
https://hal.science/hal-04761961
Dinuclear tricarbonylrhenium(i) complexes: impact of regioisomerism on the photoluminescence properties
Le Garrec S., Martins-Bessa D., Wolff M., Delavaux-Nicot B., Mallet-Ladeira S., Serpentini C.-L., Benoist E., Bedos-Belval F., Fery-Forgues S.
Dalton Transactions 2024, 53(40), 16512-16529.
http://dx.doi.org/10.1039/D4DT01907E
https://hal.science/hal-04738983
Gradual spin crossover behavior encompasing room temperature in an iron(ii) complex based on a heteroscorpionate ligand
Horniichuk O. Y., Vendier L., Salmon L., Bousseksou A.
Dalton Transactions 2024, 53(41), 17083-17096.
http://dx.doi.org/10.1039/D4DT02244K
https://hal.science/hal-04761448
Counterion effects in [Ru(bpy)3](X)2-photocatalyzed energy transfer reactions
Zanzi J., Pastorel Z., Duhayon C., Lognon E., Coudret C., Monari A., Dixon I. M., Canac Y., Smietana M., Baslé O.
JACS Au 2024, 4(8), 3049-3057.
https://doi.org/10.1021/jacsau.4c00384
https://hal.science/hal-04687774
A photocatalytic approach for the synthesis of L-shape bicyclic NHC ligands
Kittikool T., Phakdeeyothin K., Morales A., Barthes C., Vendier L., Yotphan S., Bontemps S., Bastin S., Lledós A., Baslé O., César V.
ChemistryEurope 2024, 2(2), e202300083/1-6.
https://doi.org/10.1002/ceur.202300083
https://hal.science/hal-04522291
Synthesis, structural and magnetic properties of cobalt(ii) complexes with pyridine-based macrocyclic ligand containing two pyridine pendant arms
Zahradníková E., Pichon C., Duhayon C., Sutter J.-P., Halaš P., Drahoš B.
RSC Advances 2024, 14(38), 28138-28147.
http://dx.doi.org/10.1039/D4RA02387K
https://hal.science/hal-04693290
Structure and synthesis of vindolicine and derivatives
Yousuf S. A., Vendier L., Massiot G.
Chemistry & Biodiversity 2024, 21(4), e202301928/1-9.
https://doi.org/10.1002/cbdv.202301928
https://hal.science/hal-04479357
Borohydride compounds catalyze the selective 4e– reduction of CO2 with 9-BBN
Jarava-Barrera C., Desmons S., Zhang D., Vendier L., Xu Q., Ma N., Bontemps S.
The Journal of Organic Chemistry 2024, 89(17), 12187-12196.
https://doi.org/10.1021/acs.joc.4c01077
https://hal.science/hal-04693897
Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks
Getzner L., Paliwoda D., Vendier L., Lawson-Daku L. M., Rotaru A., Molnár G., Cobo S., Bousseksou A.
Nature Communications 2024, 15(1), 7192/1-13.
https://doi.org/10.1038/s41467-024-51385-8
https://hal.science/hal-04690598
Carboranylphosphines: B9-substituted derivatives with enhanced reactivity for the anchoring to dendrimers
Milewski M., Caminade A.-M., Mallet-Ladeira S., Lledós A., Lönnecke P., Hey-Hawkins E.
Chemistry – A European Journal 2024, 30(13), e202303867/1-8.
https://doi.org/10.1002/chem.202303867
https://hal.science/hal-04428400
Synthesis, characterization, and inhibition effects of a novel eugenol derivative bearing pyrrole functionalities on the corrosion of mild steel in a HCl acid solution
Rebbah B., El Haib A., Lahmady S., Forsal I., Gouygou M., Mallet-ladeira S., Medaghri-alaoui A., Rakib E. M., Hannioui A.
RSC Advances 2024, 14(20), 14152-14160.
http://dx.doi.org/10.1039/D4RA01337A
https://hal.science/hal-04669077
Photorelease of nitric oxide (NO) in mono- and bimetallic ruthenium nitrosyl complexes: A photokinetic investigation with a two-step model
Juarez-Martinez Y., Labra-Vázquez P., Lacroix P. G., Tassé M., Mallet-Ladeira S., Pimienta V., Malfant I.
Inorganic Chemistry 2024, 63(17), 7665-7677.
https://doi.org/10.1021/acs.inorgchem.3c04496
https://hal.science/hal-04666484
Stoichiometric and catalytic reduction of carbon dioxide by a sterically encumbered amidinato magnesium hydride
Huadsai W., Vendier L., Görls H., Magna L., Bontemps S., Westerhausen M.
European Journal of Inorganic Chemistry 2024, 27(20), e202400128/1-8.
https://doi.org/10.1002/ejic.202400128
https://hal.science/hal-04632394
Coordination of Al(C6F5)3 vs. B(C6F5)3 on group 6 end-on dinitrogen complexes: chemical and structural divergences
Escomel L., Martins F. F., Vendier L., Coffinet A., Queyriaux N., Krewald V., Simonneau A.
Chemical Science 2024, 15(29), 11321-11336.
http://dx.doi.org/10.1039/D4SC02713B
https://hal.science/hal-04633385
1,2,3-Triazol-5-ylidene- vs. 1,2,3-triazole-based tricarbonylrhenium(i) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties
Vanucci-Bacqué C., Wolff M., Delavaux-Nicot B., Abdallah A. M., Mallet-Ladeira S., Serpentini C.-L., Bedos-Belval F., Fong K. W., Ng X. Y., Low M. L., Benoist E., Fery-Forgues S.
Dalton Transactions 2024, 53(27), 11276-11294
http://dx.doi.org/10.1039/D4DT00922C
https://hal.science/hal-04586541
Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna
Mudrak V., Lacroix P. G., Tassé M., Mallet-Ladeira S., Roshal A. D., Malfant I.
Dalton Transactions 2024, 53(23), 9777-9791.
http://dx.doi.org/10.1039/D4DT01154F
https://hal.science/hal-04580926
Single electron reduction of NHC–CO2–borane compounds
Morales A., Gonçalves C., Sournia-Saquet A., Vendier L., Lledós A., Baslé O., Bontemps S.
Chemical Science 2024, 15(9), 3165-3173.
http://dx.doi.org/10.1039/D3SC06325A
https://hal.science/hal-04502219
Impact of the methylene bridge substitution in chelating NHC-phosphine Mn(I) catalyst for ketone hydrogenation
Gulyaeva E. S., Buhaibeh R., Boundor M., Azouzi K., Willot J., Bastin S., Duhayon C., Lugan N., Filippov O. A., Sortais J.-B., Valyaev D. A., Canac Y.
Chemistry – A European Journal 2024, 30(22), e202304201/1-11.
https://doi.org/10.1002/chem.202304201
https://hal.science/hal-04522874
Manganese-mediated synthesis of NHC-phosphine ligand precursors
Willot J., Fatima S., Duhayon C., Lugan N., Canac Y., Valyaev D. A.
Helvetica Chimica Acta 2024, 107(4), e202400009/1-11.
https://doi.org/10.1002/hlca.202400009
https://hal.science/hal-04522796
Hydrogenation of carboxylic esters catalyzed by manganese catalysts supported by bidentate NHC-phosphine ligands
Azouzi K., Pointis R., Buhaibeh R., Fernández P. H., Pedussaut L., Boundor M., Bonfiglio A., Bruneau-Voisine A., Wei D., Roisnel T., Duhayon C., Casado M. Á., Valyaev D. A., Canac Y., Bastin S., Raynaud C., Sortais J.-B.
Journal of Catalysis 2024, 430, 115334/1-10.
https://doi.org/10.1016/j.jcat.2024.115334
https://hal.science/hal-04432103
Two active species from a single metal halide precursor: a case study of highly productive Mn-catalyzed dehydrogenation of amine-boranes via intermolecular bimetallic cooperation
Gulyaeva E. S., Osipova E. S., Kovalenko S. A., Filippov O. A., Belkova N. V., Vendier L., Canac Y., Shubina E. S., Valyaev D. A.
Chemical Science 2024, 15(4), 1409-1417.
http://dx.doi.org/10.1039/D3SC05356C
https://hal.science/hal-04428086
2023
An orbitally adapted push-pull template for N2 activation and reduction to diazene-diide
Specklin D., Boegli M.-C., Coffinet A., Escomel L., Vendier L., Grellier M., Simonneau A.
Chemical Science 2023, 14(48), 14262-14270.
http://dx.doi.org/10.1039/D3SC04390H
https://hal.science/hal-04299114
Two different compounds in one crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)
Sasaki I., Mallet-Ladeira S.
Journal of Chemical Crystallography 2023, 53, 293–298.
https://doi.org/10.1007/s10870-022-00970-0
https://hal.archives-ouvertes.fr/hal-03846487
Protonation behavior of a tetrahydrido molybdenum(IV) complex with organic and inorganic acids
Queyriaux N., Durvin N., Leon D., Boegli M.-C., Vendier L., Simonneau A.
European Journal of Inorganic Chemistry 2023, 26(33), e202300426/1-7.
https://doi.org/10.1002/ejic.202300426
https://hal.science/hal-04209769
NaLa(SO4)2,H2O thermal conversion and Na3La(SO4)3 crystal growth
Azeroual H., Vendier L., Geneste A., Granier D., Alvarez L., Hermet P., Cambon O.
Journal of Solid State Chemistry 2023, 317, 123570/1-7.
https://doi.org/10.1016/j.jssc.2022.123570
https://hal.science/hal-04818854
Phosphonium ylides vs iminophosphoranes: The role of the coordinating ylidic atom in cis-[phosphine-ylide Rh(CO)2] complexes
Popovici I., Barthes C., Tannoux T., Duhayon C., Casaretto N., Monari A., Auffrant A., Canac Y.
Inorganic Chemistry 2023, 62(5), 2376-2388.
https://doi.org/10.1021/acs.inorgchem.2c04151
https://hal.science/hal-03962127
Elastic properties of the iron(II)–triazole spin crossover complexes [Fe(Htrz)2trz]BF4 and [Fe(NH2trz)3]SO4
Paliwoda D., Vendier L., Getzner L., Alabarse F., Comboni D., Martin B., Alavi S. E., Piedrahita Bello M., Salmon L., Nicolazzi W., Molnár G., Bousseksou A.
Crystal Growth & Design 2023, 23(3), 1903-1914.
https://doi.org/10.1021/acs.cgd.2c01396
https://hal.science/hal-04008004
Iridium(i) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C–H silylation
Manguin R., Galiana-Cameo M., Kittikool T., Barthes C., Thongpaen J., Bancal E., Mallet-Ladeira S., Yotphan S., Castarlenas R., Mauduit M., Sortais J.-B., Baslé O.
Chemical Communications 2023, 59(28), 4193-4196.
http://dx.doi.org/10.1039/D2CC06865F
https://hal.science/hal-04061785
Syntheses of N2-bridged heterobimetallic complexes, their structural and qualitative bonding analyses
Le Dé Q., Orbay F., Vendier L., Simonneau A.
Journal of Organometallic Chemistry 2023, 986, 122604/1-7.
https://doi.org/10.1016/j.jorganchem.2022.122604
https://hal.science/hal-03955433
An experimental and computational investigation rules out direct nucleophilic addition on the N2 ligand in manganese dinitrogen complex [Cp(CO)2Mn(N2)]
Le Dé Q., Bouammali A., Bijani C., Vendier L., Del Rosal I., Valyaev D. A., Dinoi C., Simonneau A.
Angewandte Chemie, International Edition 2023, 62(40), e202305235/1-10.
https://doi.org/10.1002/anie.202305235
https://hal.science/hal-04159061
A Trojan horse approach for enhancing the cellular uptake of a ruthenium nitrosyl complex
Labra-Vázquez P., Rocha E., Xiao Y., Tassé M., Duhayon C., Farfán N., Santillan R., Gibot L., Lacroix P. G., Malfant I.
Dalton Transactions 2023, 52(48), 18177-18193.
http://dx.doi.org/10.1039/D3DT03480A
https://hal.science/hal-04346306
Acetylacetonate ruthenium nitrosyls: A gateway to nitric oxide release in water under near-infrared excitation by two-photon absorption
Labra-Vázquez P., Mudrak V., Tassé M., Mallet-Ladeira S., Sournia-Saquet A., Malval J.-P., Lacroix P. G., Malfant I.
Inorganic Chemistry 2023, 62(49), 20349-20363.
https://doi.org/10.1021/acs.inorgchem.3c03355
https://hal.science/hal-04284209
Mechanochemical studies on coupling of hydrazines and hydrazine amides with phenolic and furanyl aldehydes-hydrazones with antileishmanial and antibacterial activities
Kapusterynska A., Bijani C., Paliwoda D., Vendier L., Bourdon V., Imbert N., Cojean S., Loiseau P. M., Recchia D., Scoffone V. C., Degiacomi G., Akhir A., Saxena D., Chopra S., Lubenets V., Baltas M.
Molecules 2023, 28(13), 5284/1-26.
https://doi.org/10.3390/molecules28135284
https://hal.science/hal-04157067
Homochiral SCM built of tetrahedral and pentagonal bipyramidal Fe(II) units bridged by chlorine
Jubault V., Pradines B., Pichon C., Suaud N., Duhayon C., Guihéry N., Sutter J.-P.
Crystal Growth & Design 2023, 23(2), 1229-1237.
https://doi.org/10.1021/acs.cgd.2c01360
https://hal.science/hal-03981782
Pentagonal bipyramidal 3 d-metal complexes derived from a dimethylcarbamoyl-substituted pentadentate-[N3O2] ligand: Aiming for increased solubility
Jubault V., Genevois F., Pradines B., Cahier B., Jbeli W., Suaud N., Guihéry N., Duhayon C., Pichon C., Sutter J.-P.
ChemistrySelect 2023, 8(4), e202204935/1-10.
https://doi.org/10.1002/slct.202204935
https://hal.science/hal-03955461
Crystal structures and conformational effects in bis-fluorenyl based ligands and related ruthenium nitrosyl complexes
Juarez-Martinez Y., Labra-Vázquez P., Lacroix P. G., Tassé M., Bocé M., Mallet-Ladeira S., Malfant I.
Polyhedron 2023, 246, 116690/1-10.
https://doi.org/10.1016/j.poly.2023.116690
https://hal.science/hal-04283893
Towards (C,C)-cyclometalated N-(9-alkylfluorenyl)NHC ruthenium complexes for Z-selective olefin metathesis
Gajda K., Sytniczuk A., Vendier L., Trzaskowski B., Lugan N., Kajetanowicz A., Bastin S., Grela K., César V.
European Journal of Inorganic Chemistry 2023, 26(20), e202300169/1-15.
https://doi.org/10.1002/ejic.202300169
https://hal.science/hal-04155197
CO2 hydroboration: Impact of the boryl moieties on the reactivity of four bis(boryl)acetal compounds toward 2,6-diisopropylaniline
Desmons S., Zhou Y., Zhang D., Jarava-Barrera C., Coffinet A., Simonneau A., Vendier L., Luo G., Bontemps S.
European Journal of Organic Chemistry 2023, 26(30), e202300525/1-8.
https://doi.org/10.1002/ejoc.202300525
https://hal.science/hal-04169288
Structural determinations of homo and heterodi- or tetra-nuclear lanthanide complexes and their characterization by μ-Squid experiments
Costes J.-P., Duhayon C., Vendier L., Wernsdorfer W.
Polyhedron 2023, 246, 116699/1-8.
https://doi.org/10.1016/j.poly.2023.116699
https://hal.science/hal-04304533
Assessing combinations of B(C6F5)3 and N2-derived molybdenum nitrido complexes for heterolytic bond activation
Coffinet A., Specklin D., Le Dé Q., Bennaamane S., Muñoz L., Vendier L., Clot E., Mézailles N., Simonneau A.
Chemistry – A European Journal 2023, 29(26), e202203774/1-8.
https://doi.org/10.1002/chem.202203774
https://hal.science/hal-04007916
Mapping out the role of σ-silane complexes in the ruthenium-catalyzed hydrosilylation of nitriles
Chandran A., Ravel-Massol R., Vendier L., Slattery J. M., Lynam J. M., Grellier M.
Organometallics 2023, 42(21), 3153-3163.
https://doi.org/10.1021/acs.organomet.3c00397
https://hal.science/hal-04321916
Synthesis and coordination of a bisphosphine-[NHC-borane] compound: A ligand framework for bimetallic structure featuring a boron-bridging moiety
Camy A., Vendier L., Bijani C., Fernández I., Bontemps S.
Inorganic Chemistry 2023, 62(23), 9035-9043.
https://doi.org/10.1021/acs.inorgchem.3c00785
https://hal.science/hal-04169429
Hydrogenation of carboxylic esters catalyzed by phosphine-free bis-N-heterocyclic carbene manganese complexes
Azouzi K., Pedussaut L., Pointis R., Bonfiglio A., Kumari Riddhi R., Duhayon C., Bastin S., Sortais J.-B.
Organometallics 2023, 42(14), 1832-1838.
https://doi.org/10.1021/acs.organomet.3c00137
https://hal.science/hal-04174553
Combined B–H and Si–H bond activations at ruthenium
Ayyappan R., Saha K., Kaur U., Gayen S., Vendier L., Sabo-Etienne S., Ghosh S., Bontemps S.
Organometallics 2023, 42(9), 752-756.
https://doi.org/10.1021/acs.organomet.3c00109
https://hal.science/hal-04169506
Phosphine-NHC-phosphonium ylide pincer Ligand: Complexation with Pd(II) and unconventional P-coordination of the ylide moiety
Ameskal M., Taakili R., Gulyaeva E. S., Duhayon C., Willot J., Lugan N., Lepetit C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2023, 62(49), 20129-20141.
https://doi.org/10.1021/acs.inorgchem.3c03025
https://hal.science/hal-04284085
2022
Cu-Ln complexes involving non-symmetrical ligands able to introduce asymmetric centres in the vicinity of Ln ions
Zohra Chiboub Fellah F., Duhayon C., Mallet-Ladeira S., Vendier L., Costes J.-P.
Polyhedron 2022, 224, 116015/1-9.
https://doi.org/10.1016/j.poly.2022.116015
https://hal.archives-ouvertes.fr/hal-03813018
Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
Sutter J.-P., Béreau V., Jubault V., Bretosh K., Pichon C., Duhayon C.
Chemical Society Reviews 2022, 51(8), 3280-3313.
http://dx.doi.org/10.1039/D2CS00028H
https://hal.archives-ouvertes.fr/hal-03673750
Redox-switchable behavior of transition-metal complexes supported by amino-decorated N-heterocyclic carbenes
Ruamps M., Bastin S., Rechignat L., Sournia-Saquet A., Vendier L., Lugan N., Mouesca J.-M., Valyaev D. A., Maurel V., César V.
Molecules 2022, 27(12), 3776/1-17.
https://doi.org/10.3390/molecules27123776
https://hal.archives-ouvertes.fr/hal-03709012
Modulation of the sorption characteristics for an H-bonded porous architecture by varying the chemical functionalization of the channel walls
Roques N., Tovar-Molle A., Duhayon C., Brandès S., Spieß A., Janiak C., Sutter J.-P.
Chemistry – A European Journal 2022, 28(61), e202201935/1-10.
https://doi.org/10.1002/chem.202201935
https://hal.archives-ouvertes.fr/hal-03767128
Shvo-type metal–ligand cooperative catalysts: Tethered η5-oxocyclohexadienyl ruthenium complexes
Puig E., Verron R., Kechaou-Perrot M., Vendier L., Gornitzka H., Miqueu K., Sotiropoulos J.-M., Fischmeister C., Sutra P., Igau A.
Organometallics 2022, 41(11), 1391-1402.
https://doi.org/10.1021/acs.organomet.2c00123
https://hal.archives-ouvertes.fr/hal-03715383
Helical chiral N-heterocyclic carbene ligands in enantioselective gold catalysis
Pallova L., Abella L., Jean M., Vanthuyne N., Barthes C., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2022, 28(17), e202200166/1-5.
https://doi.org/10.1002/chem.202200166
https://hal.archives-ouvertes.fr/hal-03575284
Pressure tuning of coupled structural and spin state transitions in the molecular complex [Fe(H2B(pz)2)2(phen)]
Paliwoda D., Vendier L., Nicolazzi W., Molnár G., Bousseksou A.
Inorganic Chemistry 2022, 61(40), 15991-16002.
https://doi.org/10.1021/acs.inorgchem.2c02286
https://hal.archives-ouvertes.fr/hal-03790163
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-heterocyclic carbene bearing two N-cationic substituents
Padunnappattu A., Duhayon C., César V., Canac Y.
Organometallics 2022, 41(20), 2868-2878.
https://doi.org/10.1021/acs.organomet.2c00429
https://hal.archives-ouvertes.fr/hal-03818692
A masked form of an O-borylated Breslow intermediate for the diastereoselective FLP-type activation of aldehydes
Mejia Fajardo A., Queyriaux N., Camy A., Vendier L., Grellier M., Del Rosal I., Maron L., Bontemps S.
Chemistry – A European Journal 2022, 28(10), e202104122/1-5.
https://doi.org/10.1002/chem.202104122
https://hal.archives-ouvertes.fr/hal-03669849
X-Ray diffraction structure of Cu(II) and Zn(II) complexes of 8-aminoquinoline derivatives (TDMQ), related to the activity of these chelators as potential drugs against Alzheimer’s disease
Li Y., Nguyen M., Vendier L., Robert A., Liu Y., Meunier B.
Journal of Molecular Structure 2022, 1251, 132078/1-6.
https://doi.org/10.1016/j.molstruc.2021.132078
https://hal.archives-ouvertes.fr/hal-03509314
Design of anti-infectious agents from lawsone in a three-component reaction with aldehydes and isocyanides
Koumpoura C. L., Nguyen M., Bijani C., Vendier L., Salina E. G., Buroni S., Degiacomi G., Cojean S., Loiseau P. M., Benoit-Vical F., García-Sosa A. T., Robert A., Baltas M.
ACS Omega 2022, 7(40), 35635-35655.
https://doi.org/10.1021/acsomega.2c03421
https://hal.archives-ouvertes.fr/hal-03818601
Bimetallic ruthenium nitrosyl complexes with enhanced two-photon absorption properties for nitric oxide delivery
Juarez-Martinez Y., Labra-Vázquez P., Enríquez-Cabrera A., Leon-Rojas A. F., Martínez-Bourget D., Lacroix P. G., Tassé M., Mallet-Ladeira S., Farfán N., Santillan R., Ramos-Ortiz G., Malval J.-P., Malfant I.
Chemistry – A European Journal 2022, 28(62), e202201692/1-14.
https://doi.org/10.1002/chem.202201692
https://hal.archives-ouvertes.fr/hal-03796799
Diverse C-coordination modes of NHC-tricyclohexylphosphonium ylide ligands in palladium(II) complexes
El Kadiri M., Chihab A., Taakili R., Duhayon C., Valyaev D. A., Canac Y.
Organometallics 2022, 41(4), 456-466.
https://doi.org/10.1021/acs.organomet.1c00700
https://hal.archives-ouvertes.fr/hal-03579686
Characterisation by X-ray diffraction of bidentate and tridentate PCP and PCN NHC core pincer-type Mn(I) complexes
Duhayon C., Buhaibeh R., Valyaev D., Sortais J.-B., Canac Y.
Acta Crystallographica Section A 2022, 78(a2), e487.
https://doi.org/10.1107/S2053273322092610
https://hal.science/hal-04288540
Structural determinations and magnetic properties of a “chiral at metal” complex and its resulting [Cu–Ln]2 compounds
Costes J.-P., Duhayon C., Vendier L., Wernsdorfer W.
Dalton Transactions 2022, 51(7), 2805-2814.
http://dx.doi.org/10.1039/D1DT04249A
https://hal.archives-ouvertes.fr/hal-03592049
Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation
Bouammali A., Coffinet A., Vendier L., Simonneau A.
Dalton Transactions 2022, 51(28), 10697-10701.
http://dx.doi.org/10.1039/D1DT03905A
https://hal.archives-ouvertes.fr/hal-03474760
2021
Carbo-mer of barrelene: a rigid 3D-carbon-expanded molecular barrel
Zhu C., Poater A., Duhayon C., Kauffmann B., Saquet A., Rives A., Maraval V., Chauvin R.
Chemistry – A European Journal 2021, 27(36), 9286-9291.
https://doi.org/10.1002/chem.202100670
https://hal.archives-ouvertes.fr/hal-03228886v1
Quasilinear 3d-metal(i) complexes [KM(N(Dipp)SiR3)2] (M = Cr–Co) – structural diversity, solution state behaviour and reactivity
Weller R., Müller I., Duhayon C., Sabo-Etienne S., Bontemps S., Werncke C. G.
Dalton Transactions 2021, 50(14), 4890-4903.
http://dx.doi.org/10.1039/D1DT00121C
https://hal.archives-ouvertes.fr/hal-03219725
Dendrimers functionalized with palladium complexes of N-, N,N-, and N,N,N-ligands
Vanbellingen Q., Servin P., Coinaud A., Mallet-Ladeira S., Laurent R., Caminade A.-M.
Molecules 2021, 26(8), 2333/1-19.
https://doi.org/10.3390/molecules26082333
https://hal.archives-ouvertes.fr/hal-03275902
Direct access to palladium(II) complexes based on anionic C,C,C-phosphonium ylide core pincer ligand
Taakili R., Barthes C., Lepetit C., Duhayon C., Valyaev D. A., Canac Y.
Inorganic Chemistry 2021, 60(16), 12116-12128.
https://doi.org/10.1021/acs.inorgchem.1c01316
https://hal.archives-ouvertes.fr/hal-03357270
Synthesis, characterization, and comparative theoretical investigation of dinitrogen-bridged group 6-gold heterobimetallic complexes
Specklin D., Coffinet A., Vendier L., Del Rosal I., Dinoi C., Simonneau A.
Inorganic Chemistry 2021, 60(8), 5545–5562.
https://doi.org/10.1021/acs.inorgchem.0c03271
https://hal.archives-ouvertes.fr/hal-03176320
Electrochemical, spectroscopic, and computational investigation of a series of polypyridyl ruthenium(II) complexes: Characterization of reduced states
Queyriaux N., Esmieu C., Gupta A. K., Vendier L., Ott S., Orio M., Hammarström L.
European Journal of Inorganic Chemistry 2021, 2021(13), 1263-1270.
https://doi.org/10.1002/ejic.202001165
https://hal.archives-ouvertes.fr/hal-03202765
Trinuclear cyanido-bridged [Cr2Fe] complexes: To be or not to be a single-molecule magnet, a matter of straightness
Pichon C., Suaud N., Jubault V., Duhayon C., Guihéry N., Sutter J.-P.
Chemistry – A European Journal 2021, 27(62), 15484-15495.
https://doi.org/10.1002/chem.202102571
https://hal.archives-ouvertes.fr/hal-03424346
Discrete versus 1D compounds based on pentagonal bipyramid coordination geometries: A matter of solubility?
Pichon C., Duhayon C., Delahaye E., Sutter J.-P.
European Journal of Inorganic Chemistry 2021, 2021(48), 5112-5118.
https://doi.org/10.1002/ejic.202100834
https://hal.archives-ouvertes.fr/hal-03510193
Vanadium-catalyzed terpolymerization of α,ω-dienes with ethylene and cyclic olefins: Ready access to polar-functionalized polyolefins
Palucci B., Zanchin G., Ricci G., Vendier L., Lorber C., Leone G.
Macromolecules 2021, 54(23), 10700-10711.
https://doi.org/10.1021/acs.macromol.1c02142
https://hal.archives-ouvertes.fr/hal-03518735
Synthesis and properties of partially saturated fluorenyl-derived [n]helicenes featuring an overcrowded alkene
Pallova L., Gauthier E., Abella L., Jean M., Vanthuyne N., Dorcet V., Vendier L., Autschbach J., Crassous J., Bastin S., César V.
Chemistry – A European Journal 2021, 27(28), 7722-7730.
https://doi.org/10.1002/chem.202100150
https://hal.archives-ouvertes.fr/hal-03194360
Crystal structure of 1,1′-(pyridine-2,6-diyl)bis[N-(pyridin-2-ylmethyl)methanaminium] dichloride dihydrate
Merabet L., Tassé M., Mallet-Ladeira S., Kaboub L., Malfant I.
Acta Crystallographica Section E 2021, 77(12), 1296-1298.
https://doi.org/10.1107/S205698902101183X
https://hal.archives-ouvertes.fr/hal-03600453
Cyclooctadiene Rh(I) bis- and tris(pyrazolyl)aluminate complexes and their catalytic activity on the polymerization of phenylacetylene
Garcia O. J., Vendier L., Etienne M., Gwaltney S., Ressler A., Muñoz-Hernández M.-Á.
Inorganic Chemistry 2021, 60(14), 10757-10763.
https://doi.org/10.1021/acs.inorgchem.1c01434
https://hal.archives-ouvertes.fr/hal-03292668
Enantioselective reductive oligomerization of carbon dioxide into L-erythrulose via a chemoenzymatic catalysis
Desmons S., Grayson-Steel K., Nuñez-Dallos N., Vendier L., Hurtado J., Clapés P., Fauré R., Dumon C., Bontemps S.
Journal of the American Chemical Society 2021, 143(39), 16274–16283.
https://doi.org/10.1021/jacs.1c07872
https://hal.archives-ouvertes.fr/hal-03358019
Further insights into the oxidative pathway of thiocarbonyl-type antitubercular prodrugs: Ethionamide, thioacetazone, and isoxyl
de Freitas Paulo T., Duhayon C., de França Lopes L. G., Silva Sousa E. H., Chauvin R., Bernardes-Génisson V.
Chemical Research in Toxicology 2021, 34(8), 1879-1889.
https://doi.org/10.1021/acs.chemrestox.1c00164
https://hal.archives-ouvertes.fr/hal-03669331
Borane-catalysed dinitrogen borylation by 1,3-B–H bond addition
Coffinet A., Zhang D., Vendier L., Bontemps S., Simonneau A.
Dalton Transactions 2021, 50(16), 5582-5589.
https://dx.doi.org/10.1039/D1DT00317H
https://hal.archives-ouvertes.fr/hal-03176261
Oxidation-promoted synthesis of ferrocenyl planar chiral rhodium(III) complexes for C–H functionalization catalysis
Cabanes J., Odnoroh M., Duhayon C., Bijani C., Sournia-Saquet A., Polia R., Labande A.
Mendeleev Communications 2021, 31(5), 620-623.
https://doi.org/10.1016/j.mencom.2021.09.010
https://hal.archives-ouvertes.fr/hal-03412564
Cationic PCP and PCN NHC core pincer-type Mn(I) complexes: From synthesis to catalysis
Buhaibeh R., Duhayon C., Valyaev D. A., Sortais J.-B., Canac Y.
Organometallics 2021, 40(2), 231-241.
https://doi.org/10.1021/acs.organomet.0c00717
https://hal.archives-ouvertes.fr/hal-03128901
Solid-state and solution characterizations of [(TMPA)Cu(II)(SO3)] and [(TMPA)Cu(II)(S2O3)] complexes: Application to sulfite and thiosulfate fast detection
Berthonnaud L., Esmieu C., Mallet-Ladeira S., Hureau C.
Journal of Inorganic Biochemistry 2021, 225, 111601/1-9.
https://doi.org/10.1016/j.jinorgbio.2021.111601
https://hal.archives-ouvertes.fr/hal-03394471
An anionic, chelating C(sp3)/NHC ligand from the combination of an N-heterobicyclic carbene and barbituric heterocycle
Benaissa I., Gajda K., Vendier L., Lugan N., Kajetanowicz A., Grela K., Michelet V., César V., Bastin S.
Organometallics 2021, 40(18), 3223-3234.
https://doi.org/10.1021/acs.organomet.1c00458
https://hal.archives-ouvertes.fr/hal-03356487
Linear and nonlinear optical properties of a quadrupolar carbo-benzene and its benzenic parent: The carbo-merization effect
Barba-Barba R. M., Chammam M., Ramos-Ortiz G., Listunov D., Velusamy J., Rodriguez M., Carriles R., Silva C. G., Duhayon C., Kauffmann B., Maraval V., Chauvin R.
Dyes and Pigments 2021, 188, 109133/1-12.
https://doi.org/10.1016/j.dyepig.2021.109133
https://hal.archives-ouvertes.fr/hal-03202845v1
Impact of the alkali metal on the structural and dynamic properties of the anionic pentahydride ruthenium complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na, K)
Ayyappan R., Saha K., Grellier M., Clot E., Vendier L., Ghosh S., Sabo-Etienne S., Bontemps S.
Organometallics 2021, 40(17), 3024-3032.
https://doi.org/10.1021/acs.organomet.1c00384
https://hal.archives-ouvertes.fr/hal-03357901
Synthesis and reactivity of phosphine borohydride compounds
Ayyappan R., Coppel Y., Vendier L., Ghosh S., Sabo-Etienne S., Bontemps S.
Chemical Communications 2021, 57(3), 375-378.
http://dx.doi.org/10.1039/D0CC07072F
https://hal.archives-ouvertes.fr/hal-03149993
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