Molecular and Supramolecular Materials (Team S)

LCC

Overview

The research projects developed by the research group Molecular and Supramolecular Materials focus on the design of molecular organizations with workable chemical, physical and/or structural properties. Such features confer an identity to the chemical object that becomes material. Our approach towards supramolecular materials is based on the assembling of pre-formed molecular building blocks by the means of coordination chemistry or charge-assisted H-bonding.

At the interface between chemistry and physic, we take advantage of electronic properties (exchange interaction, magnetic anisotropy, luminescence) of transition or rare-earth ions coordination compounds to achieve magnetic materials such as Single Molecule Magnet (SMM) or Single Chain Magnet (SCM).

We explore also an original approach towards microporous solids using ionic hydrogen bonding as a cement for open 3D architectures.

Our works grow around three themes:

  1. Anisotropic magnetic materials (SMM, SCM),
  2. Multifunctional molecular magnets (multiferroic and magneto-optics),
  3. Porous supramolecular architectures.

    Members of the team

    All

    Research topics

    Anisotropic magnetic materials

    Multifunctional molecular magnets

    Supramolecular porous architectures

    Team news

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    Publications

    2023

    Pentagonal bipyramidal 3 d-metal complexes derived from a dimethylcarbamoyl-substituted pentadentate-[N3O2] ligand: Aiming for increased solubility
    Jubault V., Genevois F., Pradines B., Cahier B., Jbeli W., Suaud N., Guihéry N., Duhayon C., Pichon C., Sutter J.-P.
    ChemistrySelect 2023, 8(4), e202204935/1-10.
    https://doi.org/10.1002/slct.202204935
    https://hal.science/hal-03955461

    2022

    Blue-emitting ligand-mediated assembly of rare-earth MOFs toward white-light emission, sensing, magnetic, and catalytic studies
    Manna K., Sutter J.-P., Natarajan S.
    Inorganic Chemistry 2022, 61(42), 16770-16785.
    https://doi.org/10.1021/acs.inorgchem.2c02611
    https://hal.archives-ouvertes.fr/hal-03846612

    Cu-Ln complexes involving non-symmetrical ligands able to introduce asymmetric centres in the vicinity of Ln ions
    Zohra Chiboub Fellah F., Duhayon C., Mallet-Ladeira S., Vendier L., Costes J.-P.
    Polyhedron 2022, 224116015/1-9.
    https://doi.org/10.1016/j.poly.2022.116015
    https://hal.archives-ouvertes.fr/hal-03813018

    Perspective: Molecular transistors as substitutes for quantum information applications
    Dhingra A., Hu X. B., Borunda M. F., Johnson J. F., Binek C., Bird J., N’Diaye A. T., Sutter J.-P., Delahaye E., Switzer E. D., del Barco E., Rahman T. S., Dowben P. A.
    Journal of Physics: Condensed Matter 2022, 34(44), 441501/1-10.
    https://doi.org/10.1088/1361-648X/ac8c11
    https://hal.archives-ouvertes.fr/hal-03790224

    Modulation of the sorption characteristics for an H-bonded porous architecture by varying the chemical functionalization of the channel walls
    Roques N., Tovar-Molle A., Duhayon C., Brandès S., Spieß A., Janiak C., Sutter J.-P.
    Chemistry – A European Journal, 2022, 28(61), e202201935/1-10.
    https://doi.org/10.1002/chem.202201935
    https://hal.archives-ouvertes.fr/hal-03767128

    Rigid N3O2-pentadentate ligand-assisted octacoordinate mononuclear Ln(III) complexes: Syntheses, characterization, and slow magnetization relaxation
    Singh V., Das D., Anga S., Sutter J.-P., Chandrasekhar V., Bar A. K.
    ACS Omega 2022, 7(29), 25881-25890.
    https://doi.org/10.1021/acsomega.2c03631
    https://hal.archives-ouvertes.fr/hal-03746500

    A new nitronyl-nitroxide ligand for designing binuclear LnIII complexes: Syntheses, crystal structures, magnetic and EPR studies
    Răducă M., Martins D. O. T. A., Spinu C. A., Hillebrand M., Tuna F., Ionita G., Mădălan A. M., Lecourt C., Sutter J.-P., Andruh M.
    European Journal of Inorganic Chemistry 2022, 2022(16), e202200128/1-12.
    https://doi.org/10.1002/ejic.202200128
    https://hal.archives-ouvertes.fr/hal-03689254

    Supramolecular heptanuclear Ln–Cu complexes involving nitronyl nitroxide biradicals: structure and magnetic behavior
    Xi L., Jin C.-Y., Song H.-W., Wang X.-T., Li L.-C., Sutter J.-P.
    Dalton Transactions 2022, 51(22), 6955-6963.
    http://dx.doi.org/10.1039/D2DT00220E
    https://hal.archives-ouvertes.fr/hal-03673824

    Structural determinations and magnetic properties of a “chiral at metal” complex and its resulting [Cu–Ln]2 compounds
    Costes J.-P., Duhayon C., Vendier L., Wernsdorfer W.
    Dalton Transactions 2022, 51(7), 2805-2814.
    http://dx.doi.org/10.1039/D1DT04249A
    https://hal.archives-ouvertes.fr/hal-03592049

    Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
    Sutter J.-P., Béreau V., Jubault V., Bretosh K., Pichon C., Duhayon C.
    Chemical Society Reviews 2022, 51(8), 3280-3313.
    http://dx.doi.org/10.1039/D2CS00028H
    https://hal.archives-ouvertes.fr/hal-03673750

    Structurally characterised new twisted conformer for cyclen, controlled by metal ion complexation as seen in NiII and CuII complexes with halides and pseudohalides
    Verma A., Bhuvanesh N., Reibenspies J., Tayade S. B., Kumbhar A. S., Bretosh K., Sutter J.-P., Sunkari S. S.
    CrystEngComm 2022, 24(1), 119-131.
    http://dx.doi.org/10.1039/D1CE01096D
    https://hal.archives-ouvertes.fr/hal-03509672

    2021

    Discrete versus 1D compounds based on pentagonal bipyramid coordination geometries: A matter of solubility?
    Pichon C., Duhayon C., Delahaye E., Sutter J.-P.
    European Journal of Inorganic Chemistry 2021, 2021(48), 5112-5118.
    https://doi.org/10.1002/ejic.202100834
    https://hal.archives-ouvertes.fr/hal-03510193

    Trinuclear cyanido-bridged [Cr2Fe] complexes: To be or not to be a single-molecule magnet, a matter of straightness
    Pichon C., Suaud N., Jubault V., Duhayon C., Guihéry N., Sutter J.-P.
    Chemistry – A European Journal 2021, 27(62), 15484-15495.
    https://doi.org/10.1002/chem.202102571
    https://hal.archives-ouvertes.fr/hal-03424346

    A metal-radical hetero-tri-spin SCM with methyl–pyrazole–nitronyl nitroxide bridges
    Huang X., Wang K., Han J., Xie J., Li L., Sutter J.-P.
    Dalton Transactions 2021, 50(34), 11992-11998.
    http://dx.doi.org/10.1039/D1DT02006D
    https://hal.archives-ouvertes.fr/hal-03361525

    Octahedral hexachloro environment of Dy3+ with slow magnetic relaxation and luminescent properties
    Benamara N., Diop M., Leuvrey C., Lenertz M., Gilliot P., Gallart M., Bolvin H., Setifi F., Rogez G., Rabu P., Delahaye E.
    European Journal of Inorganic Chemistry 2021, 2021(22), 2099-2107.
    https://doi.org/10.1002/ejic.202100143
    https://hal.archives-ouvertes.fr/hal-03268319

    Synthesis, crystal structure, magnetic, spectroscopic, and theoretical investigations of two new nitronyl-nitroxide complexes
    Spinu C. A., Pichon C., Ionita G., Mocanu T., Calancea S., Raduca M., Sutter J.-P., Hillebrand M., Andruh M.
    Journal of Coordination Chemistry 2021, 74(1-3), 279-293.
    https://doi.org/10.1080/00958972.2021.1871900
    https://hal.archives-ouvertes.fr/hal-03188807

    Stuffed tridymite structures: Synthesis, structure, second harmonic generation, optical, and multiferroic properties
    Bhim A., Sutter J.-P., Gopalakrishnan J., Natarajan S.
    Chemistry – A European Journal 2021, 27(6), 1995-2008.
    https://doi.org/10.1002/chem.202004078
    https://hal.archives-ouvertes.fr/hal-03241518

    Accessing water processable cyanido bridged chiral heterobimetallic Co(II)–Fe(III) one dimensional network
    Choudhury A., Pichon C., Sutter J.-P., Pamu D., Sarma B., Mudoi P. P., Gogoi N.
    Chemical Communications 2021, 57(2), 207-210.
    http://dx.doi.org/10.1039/D0CC05356B
    https://hal.archives-ouvertes.fr/hal-03131086

    2020

    Concomitant emergence of circularly polarized luminescence and single-molecule magnet behavior in chiral-at-metal Dy complex
    El Rez B., Liu J., Béreau V., Duhayon C., Horino Y., Suzuki T., Coolen L., Sutter J.-P.
    Inorganic Chemistry Frontiers 2020, 7(22), 4527-4534.
    http://dx.doi.org/10.1039/D0QI00919A
    https://hal.archives-ouvertes.fr/hal-03035601

    Crystal structure and magnetic properties of Peacock–Weakley type polyoxometalates Na9[Ln(W5O18)2] (Ln = Tm, Yb): Rare Example of Tm(III) SMM
    Mariichak O. Y., Kaabel S., Karpichev Y. A., Rozantsev G. M., Radio S. V., Pichon C., Bolvin H., Sutter J.-P.
    Magnetochemistry 2020, 6(4), 53/1-14.
    https://doi.org/10.3390/magnetochemistry6040053
    https://hal.archives-ouvertes.fr/hal-02975464

    Molybdenum(III) thiocyanate- and selenocyanate-based one-dimensional heteronuclear polymers: Coordination affinity-controlled assemblage of mixed spin and mixed valence derivatives with Ni(II) and Co(II/III)
    Mousavi M., Duhayon C., Bretosh K., Béreau V., Sutter J. P.
    Inorganic Chemistry 2020, 59(11), 7603-7613.
    https://doi.org/10.1021/acs.inorgchem.0c00459
    https://hal.archives-ouvertes.fr/hal-02749318

    Single-chain magnet behavior in a 2p–3d–4f spin array with a nitronyl nitroxide biradical
    Sun J., Xie J., Li L., Sutter J. P.
    Inorganic Chemistry Frontiers 2020, 7(9), 1949-1956.
    http://dx.doi.org/10.1039/D0QI00098A
    https://hal.archives-ouvertes.fr/hal-02569569

    Pentagonal bipyramidal Ln(III) complexes containing an axial phosphine oxide ligand: Field-induced single-ion magnetism behavior of the Dy(III) analogues
    Kalita P., Ahmed N., Bar A. K., Dey S., Jana A., Rajaraman G., Sutter J. P., Chandrasekhar V.
    Inorganic Chemistry 2020, 59(9), 6603-6612.
    https://doi.org/10.1021/acs.inorgchem.0c00751
    https://hal.archives-ouvertes.fr/hal-02565216

    A ferromagnetic Ni(II)–Cr(III) single-chain magnet based on pentagonal bipyramidal building units
    Bretosh K., Béreau V., Duhayon K., Pichon C., Sutter J. P.
    Inorganic Chemistry Frontiers 2020, 71503-1511.
    https://doi.org/10.1039/C9QI01489F
    https://hal.archives-ouvertes.fr/hal-02533614

    Role of the main and auxiliary ligands in the nuclearity of Cu-Ln complexes
    Costes J.-P., Rodriguez Douton M.-J., Shova S., Vendier L.
    European Journal of Inorganic Chemistry 2020, 2020(4), 382-393.
    https://doi.org/10.1002/ejic.201901150
    https://hal.archives-ouvertes.fr/hal-02489672

    2019

    Mononuclear lanthanide complexes containing [O-O]-chelating sulfonylamidophosphate type ligands
    Prytula-Kurkunova A. Y., Pichon C., Duhayon C., Amirkhanov V. M., Sutter J. P.
    European Journal of Inorganic Chemistry 2019, (42), 4592-4596.
    https://doi.org/10.1002/ejic.201900976
    https://hal.archives-ouvertes.fr/hal-02367488

    Controlled growth of Ag nanocrystals in a H-bonded open framework
    Khodja W., Collière V., Kahn M. L., Roques N., Sutter J.-P.
    Chemistry – A European Journal 2019, 25(60), 13705-13708.
    https://doi.org/10.1002/chem.201903684
    https://hal.archives-ouvertes.fr/hal-02338823

    Contribution of 155Gd Mössbauer data to the study of the magnetic interaction in heterodinuclear 3d–Gd (3d = Cu, Ni) coordination complexes
    Ayabe T., Costes J.-P., Vendier L., Geist A., Takeda M., Takahashi M.
    Dalton Transactions 2019, 48(20), 6872-6878.
    http://dx.doi.org/10.1039/C9DT01336A
    https://hal.archives-ouvertes.fr/hal-02330528

    Effects of the exchange coupling on dynamic properties in a series of CoGdCo complexes
    Costes J.-P., Novitchi G., Vieru V., Chibotaru L. F., Duhayon C., Vendier L., Majoral J.-P., Wernsdorfer W.
    Inorganic Chemistry 2019, 58(1), 756-768.
    https://doi.org/10.1021/acs.inorgchem.8b02921
    https://hal.archives-ouvertes.fr/hal-01991167

    Improved single-chain-magnet behavior in a biradical-based nitronyl nitroxide-Cu–Dy chain
    Xie J., Li H.-D., Yang M., Sun J., Li L.-C., Sutter J.-P.
    Chemical Communications 2019, 55(23), 3398-3401.
    http://dx.doi.org/10.1039/C9CC00570F
    https://hal.archives-ouvertes.fr/hal-02140754

    Template directed synthesis of half condensed Schiff base complexes of Cu(II) and Co(III): Structural and magnetic studies
    Pandey P., Verma A., Bretosh K., Sutter J.-P., Sunkari S. S.
    Polyhedron 2019, 164, 80-89.
    https://doi.org/10.1016/j.poly.2019.02.037
    https://hal.archives-ouvertes.fr/hal-02140510

    Use of 155Gd, 151Eu, 166Er Mössbauer spectroscopy to characterize heterodinuclear Ln–Ln′ complexes
    Costes J.-P., Nicodème F., Ayabe T., Takeda M., Takahashi M.
    Polyhedron 2019, 174, 114154/1-6.
    https://doi.org/10.1016/j.poly.2019.114154
    https://hal.archives-ouvertes.fr/hal-02445240

    Influence of ancillary ligands and solvents on the nuclearity of Ni–Ln complexes
    Costes J.-P., Mallet-Ladeira S., Vendier L., Maurice R., Wernsdorfer W.
    Dalton Transactions 2019, 48(10), 3404-3414.
    http://dx.doi.org/10.1039/C9DT00370C
    https://hal.archives-ouvertes.fr/hal-02063674

    Alumnae

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    Permanent staff
    Maritie Garnier (2018-2019)
    Dr. Jean-Pierre Costes (2013)

    Post-docs and ATER
    Constance Lecourt (01/2021- 06/2021)
    Mathilde Boce (12/2018-05/2019)
    Raphaël Nougue (02/2018-01/2019)
    Arun Bar (2013-2015)
    Fatéma Chiboub (06/2010-08/2010 et 11/2010-12/2010)
    Nayan Gogoi (2009-2011)
    Nicolas Bréfuel (2006-2007)
    Venkatakrishnan Thengarai (2005-2007)
    Franck Thetiot (2005-2007)

    PhD students (year of PhD defensis)
    Valentin Jubault (2022)
    Kateryna Bretosh (2019)
    Walid Khodja (2019)
    Marion Gualino-Tamonino (2015)
    Bahjat El Rez (2015)
    Mahmoud Maksoud (2013)
    Georges Mouchaham (2012)
    Maliheh Mousavi (2011)
    Julie Milon (2008)

    M2 students
    Yuliia Oleski (2022)
    Femi Tharakan (2022)
    François Genevois (2022)
    Anthony Tovar-Molle (2019)
    Akane Okunage (2019)
    Andrii Zhluktar (2018)
    Dominique Stein (2016)
    Rana Hamze (2016)
    Mehrez Thlijeni (2012)
    Bahjat Elrez (2011)
    Georges Mouchaham (2009)
    Mohammad El Ezzi (2009)
    Cyril Tinguely (2005)

    M1 students
    Maxime Provost (2021)
    Samy Aïssou (2019)
    Anthony Tovar-Molle (2018)
    Karisma Patel (2017)
    Shinozuke Miyamoto (2017)
    Ayaka Sera (2013)
    Hamza Alkhazraji (2009)
    Sébastien Dehrs (2009)

    L1-L3 students
    Antonin Dufour (2022)
    Mary Tabut (2021)
    Sébastien Dehrs (2007 et 2008)
    Damien Villenave (2007)
    Elias Castel (2007)
    Mélanie Bousquet (2007)
    Komla Ako (2007)
    Mélanie Ferrié (2006)

    Visiting scholar
    Bohuslav Drahoš (2022)
    Wejden Jbebli (2020)
    Souhir Haddaoui (2020)
    Cristiab Spinu (2020)
    Mihai Raduca (2020)
    Djaafar Meziani (2016)
    Angelina Pritula (2014 et 2015)
    Monia Hamdouni (2011 et 2012)
    Traian Pasatoiu (2008 et 2009)
    Emi Evangelio (2006 et 2008)

    Address

    Laboratoire de chimie de coordination du CNRS

    205 route de Narbonne, BP 44099
    31077 Toulouse cedex 4
    France

    + 33 5 61 33 31 00